Preparation and Tunable Broadband Emission of α/β-Zn2SiO4∶Mn2+ Dual-phase Nanocrystals Embedded in Glass Ceramics

YU Man; LIU Xueyun; GUO Hai; XIAO Fen

doi:10.37188/CJL.20220431

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Preparation and Tunable Broadband Emission of α/β-Zn₂SiO₄∶Mn²⁺ Dual-phase Nanocrystals Embedded in Glass Ceramics

Synthesis and Properties of Materials | 更新时间：2023-06-15

- Preparation and Tunable Broadband Emission of α/β-Zn₂SiO₄∶Mn²⁺ Dual-phase Nanocrystals Embedded in Glass Ceramics
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 5, Pages: 852-862(2023)
- 作者机构：
  
  1.宁波大学高等技术研究院，浙江宁波　315211
  2.宁波海洋研究院，浙江宁波　315832
  3.浙江师范大学物理系，浙江金华　321004
  4.井冈山大学机电工程学院，江西吉安　343009
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(51702172);Natural Science Foundation of Zhejiang Province(LY20A040002)
- DOI：10.37188/CJL.20220431
  CLC： O482.31
- Published：05 May 2023，
  
  Received：26 December 2022，
  
  Revised：12 January 2023，
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于曼,刘雪云,郭海等.α/β⁃Zn₂SiO₄∶Mn²⁺双相玻璃陶瓷制备与宽带可调控发光[J].发光学报,2023,44(05):852-862.

YU Man,LIU Xueyun,GUO Hai,et al.Preparation and Tunable Broadband Emission of α/β-Zn₂SiO₄∶Mn²⁺ Dual-phase Nanocrystals Embedded in Glass Ceramics[J].Chinese Journal of Luminescence,2023,44(05):852-862.
于曼,刘雪云,郭海等.α/β⁃Zn₂SiO₄∶Mn²⁺双相玻璃陶瓷制备与宽带可调控发光[J].发光学报,2023,44(05):852-862. DOI： 10.37188/CJL.20220431.

YU Man,LIU Xueyun,GUO Hai,et al.Preparation and Tunable Broadband Emission of α/β-Zn₂SiO₄∶Mn²⁺ Dual-phase Nanocrystals Embedded in Glass Ceramics[J].Chinese Journal of Luminescence,2023,44(05):852-862. DOI： 10.37188/CJL.20220431.

摘要

含单相纳米晶体的玻璃陶瓷尽管能够为激活离子提供良好的发光环境，然而因其晶体场环境较为单一，在构造多色、多模式以及超宽带发光的光功能材料时受到了一定限制。基于此，研发双相纳米晶复合玻璃陶瓷对拓展该类功能材料的应用领域具有重要的研究意义。本文采用熔融淬火法在硅铝酸盐玻璃体系中成功析出了α

⁃

SiO

和β

⁃

SiO

纳米晶，通过调控Al

含量、热处理温度可以实现β

⁃

SiO

单相纳米晶向α/β

⁃

SiO

双相纳米晶共存的转变。进一步引入Mn

，在285 nm激发下，制得的玻璃陶瓷呈现可调谐的单带（~580 nm）和连续双模（~530/580 nm）发射，并且双宽带发光强度随Mn

浓度和热处理温度而可调变化，对应样品的发光颜色逐渐由橘黄色变为黄绿色。结合纳米晶体结构和光谱数据对Mn

可调控发光机理进行了解释。本研究结果对过渡金属离子掺杂双相玻璃陶瓷制备与可调宽带发光的基础研究及应用探索具有一定参考价值。

Abstract

Glass ceramics embedded with only one kind of nanocrystals are usually cannot meet the requirements of multi-color， multi-mode and ultra-wideband luminescence applications due to the limitation of single crystal field environment. It is thus of significance to develop dual-phase nanocrystal-based glass ceramics for expanding the application field of this kind of functional materials. In this paper， an aluminosilicate glass ceramic containing α-Zn

SiO

and β-Zn

SiO

nanocrystals was successfully prepared by a melt quenching technique. The transition from single-phase to dual-phase nanocrystals can be achieved by varying Al

content and heat treatment temperature. The obtained glass ceramics exhibit tunable single-band （~580 nm） and continuous dual-mode （~530/580 nm） emission under the excitation of 285 nm， and the luminescence intensity varies with the concentration of Mn

and heat treatment temperature， resulting in a tunable emissive color from orange to yellowish. The related luminescence mechanism was explained by combining with the structure of nanocrystals and spectral data. This research may be of reference value for the preparation of dual-phase glass ceramics and exploration of broadband light source.

关键词

微晶玻璃双相纳米晶锰离子宽带发光

Keywords

glass-ceramicsdual-phase nanocrystalsMn2+ ionsbroadband luminescence

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