Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules

XIE Guangqi; MA Mengen; YANG Danni; YANG Huidong; ZENG Yilin; MA Yujiao; WU Shaohang; LIU Chong; MAI Yaohua

doi:10.37188/CJL.20220414

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Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules

Device Fabrication and Physics | 更新时间：2023-10-27

- Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 6, Pages: 1023-1031(2023)
- 作者机构：
  
  1.暨南大学信息科学技术学院，新能源技术研究院，广东广州　510632
  2.五邑大学智能制造学部，广东江门　529020
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(62104082;62005099);Guangdong Basic and Applied Basic Research Foundation(2022A1515010746;2022A1515011228);The Science and Technology Program of Guangzhou(202201010458;202201010542)
- DOI：10.37188/CJL.20220414
  CLC： TM914.4
- Published：05 June 2023，
  
  Received：14 December 2022，
  
  Revised：29 December 2022，
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谢光起,马梦恩,杨丹妮等.双自组装单分子层修饰氧化镍制备高效率钙钛矿太阳电池及组件[J].发光学报,2023,44(06):1023-1031.

XIE Guangqi,MA Mengen,YANG Danni,et al.Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules[J].Chinese Journal of Luminescence,2023,44(06):1023-1031.
谢光起,马梦恩,杨丹妮等.双自组装单分子层修饰氧化镍制备高效率钙钛矿太阳电池及组件[J].发光学报,2023,44(06):1023-1031. DOI： 10.37188/CJL.20220414.

XIE Guangqi,MA Mengen,YANG Danni,et al.Co-assembled Monolayers Modified Nickel Oxide for High Efficient Perovskite Solar Cells and Modules[J].Chinese Journal of Luminescence,2023,44(06):1023-1031. DOI： 10.37188/CJL.20220414.

摘要

氧化镍（NiO

）作为无机p型半导体，常用于倒置钙钛矿太阳能电池（PSCs）中的空穴传输层（HTL），但本身存在的高缺陷密度和与钙钛矿不相匹配的能级排布限制了PSCs的能量转换效率。本文通过引入双自组装单分子层修饰氧化镍界面，钝化氧化镍材料自身缺陷，改善能级匹配，促进了界面处光生载流子的提取和传输，提高了PSCs的开路电压（

）和填充因子（FF），最终将刮涂氧化镍基PSCs的效率提升到20.38%，而且未封装的器件在氮气氛围中用85 ℃老化1 000 h后仍维持原始效率的96%。更重要的是，我们以此制备了孔径面积为60.84 cm

、由13节子电池串联而成的钙钛矿组件，效率达到了17.04%。

Abstract

Nickel oxide （NiO

）， an inorganic p-type semiconductor， is commonly used as the hole transporting layer （HTL） for inverted perovskite solar cells （PSCs）. However， the high defect density of NiO

and mismatched energy levels with the perovskite layer strongly limit the efficiency of PSCs. In this work， the co-assembled monolayer is introduced to modify the interface of NiO

， which was demonstrated to passivate the defects and improve the energy level alignment， leading to the enhancement of charge extraction and transmission at the interface. Finally， the blade-coated PSCs yield a power conversion efficiency of 20.38% due to the improvement on open circuit voltage （

） and filling factor （FF）. Moreover， the device without encapsulation can maintain 96% of the initial efficiency after aging at 85 ℃ for 1 000 h in nitrogen atmosphere. More importantly， we have fabricated a perovskite solar module with an aperture area of 60.84 cm

， which is composed of 13 sub cells in series， and the efficiency has reached 17.04%.

关键词

钙钛矿太阳电池组件能级匹配电荷抽取高效率

Keywords

perovskite solar cellsmodulebandgap alignmentcharge extractionhigh efficiency

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Related Institution

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School of Optoelectronic Engineering, Changchun University of Science and Technology

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