Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH3）4]2GeF6∶Mn4+ for Dual-mode Temperature Sensing

WANG Jing; LU Jitao; WU Yahong; SONG Mingjun

doi:10.37188/CJL.20220363

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Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing

Luminescence Applications and Interdisciplinary Fields | 更新时间：2023-06-15

- Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 5, Pages: 904-911(2023)
- 作者机构：
  
  潍坊学院化学化工与环境工程学院，山东潍坊　261061
- 作者简介：
- 基金信息：
  
  Doctoral Foundation of Weifang University(2021BS08)
- DOI：10.37188/CJL.20220363
  CLC： O482.31
- Published：05 May 2023，
  
  Received：12 October 2022，
  
  Revised：24 October 2022，
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王晶,逯纪涛,吴亚红等.零维有机⁃无机杂化荧光粉[N（CH₃）₄]₂GeF₆∶Mn⁴⁺的双模温度传感应用[J].发光学报,2023,44(05):904-911.

WANG Jing,LU Jitao,WU Yahong,et al.Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing[J].Chinese Journal of Luminescence,2023,44(05):904-911.
王晶,逯纪涛,吴亚红等.零维有机⁃无机杂化荧光粉[N（CH₃）₄]₂GeF₆∶Mn⁴⁺的双模温度传感应用[J].发光学报,2023,44(05):904-911. DOI： 10.37188/CJL.20220363.

WANG Jing,LU Jitao,WU Yahong,et al.Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing[J].Chinese Journal of Luminescence,2023,44(05):904-911. DOI： 10.37188/CJL.20220363.

摘要

新型低维有机⁃无机杂化荧光粉具有独特的光学性质和广泛的光电应用前景。本文报道了一种采用湿化学法合成的Mn

掺杂的有机⁃无机杂化［N（CH

）

］

GeF

荧光粉材料，并采用X射线粉末衍射（XRD）、热重差热分析（TG⁃DTA）、红外光谱（FTIR）、漫反射光谱（DRS）、激发（PL）与发射（PLE）光谱以及荧光寿命等手段对材料的晶体结构、热稳定性和发光性能进行了系统研究。研究结果表明，室温下，该荧光粉可产生高颜色纯度的窄红色发射峰，其峰值位于630 nm。在13~292 K的温度范围内，Mn

离子的Stokes和anti⁃Stokes边带发光强度表现出不同的温度响应。通过应用anti⁃Stokes和Stokes边带的发射强度比进行温度传感，获得的最大绝对灵敏度和相对灵敏度分别为0.002 1 K

-1

和2.11%·K

-1

。同时，Mn

离子的荧光寿命值也可以用于温度传感，最大相对灵敏度为0.44%·K

-1

，表明该荧光粉可以用于双模温度传感研究。

Abstract

Novel low-dimensional organic-inorganic hybrid phosphors have unique optical properties and wide optoelectronic applications. Zero-dimensional organic-inorganic hybrid phosphor ［N（CH

）

］

GeF

∶Mn

was synthesized by a wet chemical method. By using XRD， TG-DTA， FTIR， DRS， PL， PLE， and lifetime decay， the crystal structure， thermal stability， and optical properties were systemically investigated. The result shows that narrow red emission with high color purity can be observed even at room temperature， and the emission peak locates at 630 nm. In the temperature range of 13-292 K， anti-Stokes and Stokes sidebands of Mn

ions show different temperature responses. The emission intensity ratio of anti-Stokes

. Stokes sidebands can be used for temperature sensing， with a maximum absolute sensitivity of 0.002 1 K

-1

and relative sensitivity of 2.11%·K

-1

. Moreover， the lifetime of Mn

ions can also be used for temperature sensing with a maximum relative sensitivity of 0.44%·K

-1

， demonstrating its potential application in dual-mode optical thermometry.

关键词

零维发光材料Mn4+温度传感

Keywords

zero-dimensional luminescent materialMn4+temperature sensing

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王晶（1992-），女，山东潍坊人，博士，讲师，2020年于韩国釜庆大学获得博士学位，主要从事稀土与过渡金属离子发光材料的研究。. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

E⁃mail: jingwang9212@126.com. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

宋明君（1981-），男，山东济宁人，博士，教授，2009年于中国科学院福建物质结构研究所获得博士学位，主要从事激光晶体与稀土发光材料的研究。. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

E⁃mail: smj521209@126.com. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

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