Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH3）4]2GeF6∶Mn4+ for Dual-mode Temperature Sensing

WANG Jing; LU Jitao; WU Yahong; SONG Mingjun

doi:10.37188/CJL.20220363

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Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing

Luminescence Applications and Interdisciplinary Fields | 更新时间：2023-06-15

- Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 5, Pages: 904-911(2023)
- 作者机构：
  
  潍坊学院化学化工与环境工程学院，山东潍坊　261061
- 作者简介：
- 基金信息：
  
  Doctoral Foundation of Weifang University(2021BS08)
- DOI：10.37188/CJL.20220363
  CLC： O482.31
- Published：05 May 2023，
  
  Received：12 October 2022，
  
  Revised：24 October 2022，
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王晶,逯纪涛,吴亚红等.零维有机⁃无机杂化荧光粉[N（CH₃）₄]₂GeF₆∶Mn⁴⁺的双模温度传感应用[J].发光学报,2023,44(05):904-911.

WANG Jing,LU Jitao,WU Yahong,et al.Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing[J].Chinese Journal of Luminescence,2023,44(05):904-911.
王晶,逯纪涛,吴亚红等.零维有机⁃无机杂化荧光粉[N（CH₃）₄]₂GeF₆∶Mn⁴⁺的双模温度传感应用[J].发光学报,2023,44(05):904-911. DOI： 10.37188/CJL.20220363.

WANG Jing,LU Jitao,WU Yahong,et al.Luminescence of Zero-dimensional Organic-inorganic Hybrid Phosphor [N（CH₃）₄]₂GeF₆∶Mn⁴⁺ for Dual-mode Temperature Sensing[J].Chinese Journal of Luminescence,2023,44(05):904-911. DOI： 10.37188/CJL.20220363.

摘要

新型低维有机⁃无机杂化荧光粉具有独特的光学性质和广泛的光电应用前景。本文报道了一种采用湿化学法合成的Mn

掺杂的有机⁃无机杂化［N（CH

）

］

GeF

荧光粉材料，并采用X射线粉末衍射（XRD）、热重差热分析（TG⁃DTA）、红外光谱（FTIR）、漫反射光谱（DRS）、激发（PL）与发射（PLE）光谱以及荧光寿命等手段对材料的晶体结构、热稳定性和发光性能进行了系统研究。研究结果表明，室温下，该荧光粉可产生高颜色纯度的窄红色发射峰，其峰值位于630 nm。在13~292 K的温度范围内，Mn

离子的Stokes和anti⁃Stokes边带发光强度表现出不同的温度响应。通过应用anti⁃Stokes和Stokes边带的发射强度比进行温度传感，获得的最大绝对灵敏度和相对灵敏度分别为0.002 1 K

-1

和2.11%·K

-1

。同时，Mn

离子的荧光寿命值也可以用于温度传感，最大相对灵敏度为0.44%·K

-1

，表明该荧光粉可以用于双模温度传感研究。

Abstract

Novel low-dimensional organic-inorganic hybrid phosphors have unique optical properties and wide optoelectronic applications. Zero-dimensional organic-inorganic hybrid phosphor ［N（CH

）

］

GeF

∶Mn

was synthesized by a wet chemical method. By using XRD， TG-DTA， FTIR， DRS， PL， PLE， and lifetime decay， the crystal structure， thermal stability， and optical properties were systemically investigated. The result shows that narrow red emission with high color purity can be observed even at room temperature， and the emission peak locates at 630 nm. In the temperature range of 13-292 K， anti-Stokes and Stokes sidebands of Mn

ions show different temperature responses. The emission intensity ratio of anti-Stokes

. Stokes sidebands can be used for temperature sensing， with a maximum absolute sensitivity of 0.002 1 K

-1

and relative sensitivity of 2.11%·K

-1

. Moreover， the lifetime of Mn

ions can also be used for temperature sensing with a maximum relative sensitivity of 0.44%·K

-1

， demonstrating its potential application in dual-mode optical thermometry.

关键词

零维发光材料Mn4+温度传感

Keywords

zero-dimensional luminescent materialMn4+temperature sensing

references

ADACHI S. Review-Mn4+-activated red and deep red-emitting phosphors ［J］. ECS J. Solid State Sci. Technol.， 2019， 9（1）： 016001. doi: 10.1149/2.0022001jsshttp://dx.doi.org/10.1149/2.0022001jss

CAO R P， LV X Y， RAN Y Q， et al. Rare-earth-free Li5La3Ta2O12∶Mn4+ deep-red-emitting phosphor： synthesis and photoluminescence properties ［J］. J. Am. Ceram. Soc.， 2019， 102（10）： 5910-5918. doi: 10.1111/jace.16447http://dx.doi.org/10.1111/jace.16447

XUE J P， NOH H M， CHOI B C， et al. Dual-functional of non-contact thermometry and field emission displays via efficient Bi3+ → Eu3+ energy transfer in emitting-color tunable GdNbO4 phosphors ［J］. Chem. Eng. J.， 2020， 382： 122861-1-11. doi: 10.1016/j.cej.2019.122861http://dx.doi.org/10.1016/j.cej.2019.122861

ZHOU Y Y， SONG E H， DENG T T， et al. Surface passivation toward highly stable Mn4+-activated red-emitting fluoride phosphors and enhanced photostability for white LEDs ［J］. Adv. Mater. Interfaces， 2019， 6（9）： 1802006-1-15. doi: 10.1002/admi.201802006http://dx.doi.org/10.1002/admi.201802006

QIN L， BI S L， CAI P Q， et al. Preparation， characterization and luminescent properties of red-emitting phosphor： LiLa2NbO6 doped with Mn4+ ions ［J］. J. Alloys Compd.， 2018， 755： 61-66. doi: 10.1016/j.jallcom.2018.04.295http://dx.doi.org/10.1016/j.jallcom.2018.04.295

MING H， LIU L L， HE S G， et al. An ultra-high yield of spherical K2NaScF6∶Mn4+ red phosphor and its application in ultra-wide color gamut liquid crystal displays ［J］. J. Mater. Chem. C， 2019， 7（24）： 7237-7248. doi: 10.1039/c9tc02295chttp://dx.doi.org/10.1039/c9tc02295c

ZHOU Y Y， SONG E H， DENG T T， et al. Waterproof narrow-band fluoride red phosphor K2TiF6∶Mn4+ via facile superhydrophobic surface modification ［J］. ACS Appl. Mater. Interfaces， 2018， 10（1）： 880-889. doi: 10.1021/acsami.7b15503http://dx.doi.org/10.1021/acsami.7b15503

CAI P Q， WANG X F， SEO H J， et al. Bluish-white-light-emitting diodes based on two-dimensional lead halide perovskite （C6H5C2H4NH3）2PbCl2Br2 ［J］. Appl. Phys. Lett.， 2018， 112（15）： 153901-1-5. doi: 10.1063/1.5023797http://dx.doi.org/10.1063/1.5023797

SONG E H， WANG J Q， SHI J H， et al. Highly efficient and thermally stable K3AlF6∶Mn4+ as a red phosphor for ultra-high-performance warm white light-emitting diodes ［J］. ACS Appl. Mater. Interfaces， 2017， 9（10）： 8805-8812. doi: 10.1021/acsami.7b00749http://dx.doi.org/10.1021/acsami.7b00749

WU W L， FANG M H， ZHOU W L， et al. High color rendering index of Rb2GeF6∶Mn4+ for light-emitting diodes ［J］. Chem. Mater.， 2017， 29（3）： 935-939.

MING H， ZHAO Y F， ZHOU Y Y， et al. Shining Mn4+ in 0D organometallic fluoride hosts towards highly efficient photoluminescence ［J］. Adv. Opt. Mater.， 2022， 10（7）： 2102141-1-10. doi: 10.1002/adom.202102141http://dx.doi.org/10.1002/adom.202102141

XUE J P， YU Z K， NOH H M， et al. Designing multi-mode optical thermometers via the thermochromic LaNbO4∶Bi3+/Ln3+ （Ln = Eu， Tb， Dy， Sm） phosphors ［J］. Chem. Eng. J.， 2021， 415： 128977-1-14. doi: 10.1016/j.cej.2021.128977http://dx.doi.org/10.1016/j.cej.2021.128977

XUE J， LI F， LIU F， et al. Designing ultra-highly efficient Mn2+-activated Zn2GeO4 green-emitting persistent phosphors toward versatile applications ［J］. Mater. Today Chem.， 2022， 23： 100693. doi: 10.1016/j.mtchem.2021.100693http://dx.doi.org/10.1016/j.mtchem.2021.100693

XUE J P， NOH H M， PARK S H， et al. NUV light induced visible emission in Er3+-activated NaSrLa（MoO4）O3 phosphors for green LEDs and thermometer ［J］. J. Am. Ceram. Soc.， 2020， 103（2）： 1174-1186. doi: 10.1111/jace.16797http://dx.doi.org/10.1111/jace.16797

WANG X F， LIU Q， BU Y Y， et al. Optical temperature sensing of rare-earth ion doped phosphors ［J］. RSC Adv.， 2015， 5（105）： 86219-86236. doi: 10.1039/c5ra16986khttp://dx.doi.org/10.1039/c5ra16986k

BAUR F， BÖHNISCH D， JÜSTEL T. Luminescence of Mn4+ in a hexafluorogermanate with the complex organic cation guanidinium ［C（NH2）3］2GeF6∶Mn4+ ［J］. ECS J. Solid State Sci. Technol.， 2020， 9（4）： 046003-1-6. doi: 10.1149/2162-8777/ab8788http://dx.doi.org/10.1149/2162-8777/ab8788

CAI P Q， WANG S， XU T M， et al. Mn4+ doped zero-dimensional organic-inorganic hybrid material with narrow-red emission ［J］. J. Lumin.， 2020， 228： 117661-1-7. doi: 10.1016/j.jlumin.2020.117661http://dx.doi.org/10.1016/j.jlumin.2020.117661

KIM E A， LEE D W， OK K M. Centrosymmetric ［N（CH3）4］2TiF6 vs. noncentrosymmetric polar ［C（NH2）3］2TiF6：a hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra ［J］. J. Solid State Chem.， 2012， 195： 149-154. doi: 10.1016/j.jssc.2011.11.027http://dx.doi.org/10.1016/j.jssc.2011.11.027

YOUNG C W， KOEHLER J S， MCKINNEY D S. Infrared absorption spectra of tetramethyl compounds ［J］. J. Am. Chem. Soc.， 1947， 69（6）： 1410-1415. doi: 10.1021/ja01198a050http://dx.doi.org/10.1021/ja01198a050

VOIT E I， DAVIDOVICH R L， UDOVENKO A A， et al. The structure and vibrational spectra of gallium（Ⅲ） fluoride dimeric complex with tetramethylammonium cation ［J］. Opt. Spectrosc.， 2019， 127（6）： 984-990. doi: 10.1134/s0030400x19120300http://dx.doi.org/10.1134/s0030400x19120300

JIN Y， FANG M H， GRINBERG M， et al. Narrow red emission band fluoride phosphor KNaSiF6∶Mn4+ for warm white light-emitting diodes ［J］. ACS Appl. Mater. Interfaces， 2016， 8（18）： 11194-11203. doi: 10.1021/acsami.6b01905http://dx.doi.org/10.1021/acsami.6b01905

姬海鹏. Mn4+离子光谱学基础［J］. 发光学报， 2022， 43（8）： 1175-1187. doi: 10.37188/cjl.20220102http://dx.doi.org/10.37188/cjl.20220102

JI H P. Basic knowledge for understanding spectroscopic property of Mn4+ ion ［J］. Chin. J. Lumin.， 2022， 43（8）： 1175-1187. （in Chinese）. doi: 10.37188/cjl.20220102http://dx.doi.org/10.37188/cjl.20220102

OK K M. Toward the rational design of novel noncentrosymmetric materials： factors influencing the framework structures ［J］. Acc. Chem. Res.， 2016， 49（12）： 2774-2785. doi: 10.1021/acs.accounts.6b00452http://dx.doi.org/10.1021/acs.accounts.6b00452

ZHONG J S， CHEN D Q， CHEN X， et al. Efficient rare-earth free red-emitting Ca2YSbO6∶Mn4+， M（M = Li+， Na+， K+， Mg2+） phosphors for white light-emitting diodes ［J］. Dalton Trans.， 2018， 47（18）： 6528-6537. doi: 10.1039/c8dt00992ahttp://dx.doi.org/10.1039/c8dt00992a

WANG X F， WANG Y， MARQUES-HUESO J， et al. Improving optical temperature sensing performance of Er3+ doped Y2O3 microtubes via Co-doping and controlling excitation power ［J］. Sci. Rep.， 2017， 7（1）： 758-1-13. doi: 10.1038/s41598-017-00838-whttp://dx.doi.org/10.1038/s41598-017-00838-w

FAN H， LU Z Z， MENG Y B， et al. Optical temperature sensor with superior sensitivity based on Ca2LaSbO6∶Mn4+， Eu3+ phosphor ［J］. Opt. Laser Technol.， 2022， 14： 107804-1-5. doi: 10.1016/j.optlastec.2021.107804http://dx.doi.org/10.1016/j.optlastec.2021.107804

FANG Y Y， ZHANG Y P， ZHANG Y P， et al. Achieving high thermal sensitivity from ratiometric CaGdAlO4∶Mn4+， Tb3+ thermometers ［J］. Dalton Trans.， 2021， 50（38）： 13447-13458. doi: 10.1039/d1dt02185khttp://dx.doi.org/10.1039/d1dt02185k

SENDEN T， VAN DIJK-MOES R J A， MEIJERINK A. Quenching of the red Mn4+ luminescence in Mn4+-doped fluoride LED phosphors ［J］. Light： Sci. Appl.， 2018， 7： 8-1-13. doi: 10.1038/s41377-018-0013-1http://dx.doi.org/10.1038/s41377-018-0013-1

CAO R P， ZHANG W J， CHEN T， et al. Perovskite tungstate Ba2La2ZnW2O12∶Mn4+ phosphor： synthesis， energy transfer and tunable emission ［J］. Mater. Res. Bull.， 2021， 137： 111200-1-7. doi: 10.1016/j.materresbull.2020.111200http://dx.doi.org/10.1016/j.materresbull.2020.111200

CAI P Q， QIN L， CHEN C L， et al. Optical thermometry based on vibration sidebands in Y2MgTiO6∶Mn4+ double perovskite ［J］. Inorg. Chem.， 2018， 57（6）： 3073-3081. doi: 10.1021/acs.inorgchem.7b02938http://dx.doi.org/10.1021/acs.inorgchem.7b02938

YANG Z B， WANG Z J， ZHENG M J， et al. Excitation selective thermal characteristics of Mg28Ge7.55-xGaxO32F15.04∶Mn4+ and application in single/dual-mode optical thermometry ［J］. Mater. Today Commun.， 2021， 28： 102660. doi: 10.1016/j.mtcomm.2021.102660http://dx.doi.org/10.1016/j.mtcomm.2021.102660

CAI P Q， WANG X F， SEO H J. Excitation power dependent optical temperature behaviors in Mn4+ doped oxyfluoride Na2WO2F4 ［J］. Phys. Chem. Chem. Phys.， 2018， 20（3）： 2028-2035. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

王晶（1992-），女，山东潍坊人，博士，讲师，2020年于韩国釜庆大学获得博士学位，主要从事稀土与过渡金属离子发光材料的研究。. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

E⁃mail: jingwang9212@126.com. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

宋明君（1981-），男，山东济宁人，博士，教授，2009年于中国科学院福建物质结构研究所获得博士学位，主要从事激光晶体与稀土发光材料的研究。. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

E⁃mail: smj521209@126.com. doi: 10.1039/c7cp07123jhttp://dx.doi.org/10.1039/c7cp07123j

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