Design and Regulation of Near-infrared Emission Wavelength of Cr3+ in Isolated Lattice Sites: A Case Study of <italic style="font-style: italic">AM</italic>P2O7∶Cr3+

WU Jiayu; ZHANG Zhenzhen; LI Song; LIAN Shixun; YU Liping; QIU Zhongxian

doi:10.37188/CJL.20220320

您当前的位置：

首页 >

文章列表页 >

Design and Regulation of Near-infrared Emission Wavelength of Cr³⁺ in Isolated Lattice Sites: A Case Study of AMP₂O₇∶Cr³⁺

Synthesis and Properties of Materials | 更新时间：2023-03-13

- Design and Regulation of Near-infrared Emission Wavelength of Cr³⁺ in Isolated Lattice Sites: A Case Study of AMP₂O₇∶Cr³⁺
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 2, Pages: 246-258(2023)
- 作者机构：
  
  湖南师范大学化学化工学院光能转换材料湖南省高校重点实验室，湖南长沙　410081
- 作者简介：
- 基金信息：
  
  Natural Science Foundation of Hunan Province(2021JJ30438;2021JJ30440);Hunan Province Graduate Research and Innovation Project(QL20220130)
- DOI：10.37188/CJL.20220320
  CLC： O482.31
- Published：05 February 2023，
  
  Received：04 September 2022，
  
  Revised：18 September 2022，
- 稿件说明：
移动端阅览
吴家宇,张珍珍,李松等.孤立格位中的Cr³⁺近红外发射波长的设计与调控：以AMP₂O₇∶Cr³⁺为例[J].发光学报,2023,44(02):246-258.

WU Jiayu,ZHANG Zhenzhen,LI Song,et al.Design and Regulation of Near-infrared Emission Wavelength of Cr³⁺ in Isolated Lattice Sites: A Case Study of AMP₂O₇∶Cr³⁺[J].Chinese Journal of Luminescence,2023,44(02):246-258.
吴家宇,张珍珍,李松等.孤立格位中的Cr³⁺近红外发射波长的设计与调控：以AMP₂O₇∶Cr³⁺为例[J].发光学报,2023,44(02):246-258. DOI： 10.37188/CJL.20220320.

WU Jiayu,ZHANG Zhenzhen,LI Song,et al.Design and Regulation of Near-infrared Emission Wavelength of Cr³⁺ in Isolated Lattice Sites: A Case Study of AMP₂O₇∶Cr³⁺[J].Chinese Journal of Luminescence,2023,44(02):246-258. DOI： 10.37188/CJL.20220320.

摘要

近红外光谱调控对于开发新型近红外荧光粉至关重要。3d

电子构型的Cr

具有波长可调谐的宽带近红外发光性质，是一种理想的近红外激活剂离子。由于d轨道对晶体场敏感，Cr

离子发射波长强烈依赖于其配位晶体结构，明确配位结构与发光性质之间的构效关系是指导近红外荧光粉理性设计的理论基础。而实际上晶体结构复杂，影响局部配位结构性质的因素很多，难以形成明确的构效关系。

（

=Li，K；

=Ga， Sc，In）系列焦磷酸盐晶体中具有孤立的［

］八面体结构特征，可为Cr

提供孤立的配位环境，孤立格位大大减少了晶体结构的复杂性，为构效关系的建立提供了合理性保障。本文以

∶Cr

系列荧光粉为研究对象，Cr

取代在孤立的［

］八面体中心格位，具有波长可调谐的近红外发光性质，其发射波长随

和

组分变化而发生迁移，以Cr

发射波长对孤立配位结构特征的依赖关系初步构建［

］—Cr

近红外发射波长的构效关系，以期能为Cr

近红外发射材料理性设计提供一些依据和思路。

Abstract

Near-infrared （NIR） spectral modification is crucial for the development of NIR phosphors. With 3d

configuration， the Cr

ion shows wavelength-controllable wide-band NIR emissions， which is an ideal NIR activator ion. Due to the sensitivity of d orbitals to crystal field， the emission wavelength of Cr

strongly depends on its coordination structure. Clarifying the structure-function relationship between its coordination structure and luminescence properties is the theoretical basis to guide the rational design of NIR phosphors. In fact， limited by the complexity of the crystal structure， there are too many factors affecting the local coordination structure properties. A clarified structure-function relationship is still a serious challenge. A series of pyrophosphate crystals

（

Li， K；

=Ga， Sc， In） contain isolated ［

］ octahedron feature， which provides isolated coordination environment for Cr

. The isolated coordination greatly suppresses the effect of the next-closed coordination structures and guarantees the reasonability of the related structure-function relationship. This paper studies the series of

∶Cr

phosphors. The Cr

ions are introduced into the central site of the isolated ［

］ octahedra， which show wavelength-tunable NIR emissions depending on the composed

and

. We build a preliminary structure-function relationship of ［

］—NIR wavelength of Cr

based on the correlation of Cr

emissions and the isolated coordination structure features， which provides theoretical basis and ideas for rational design of Cr

NIR emitting materials.

关键词

近红外荧光粉Cr3+构效关系

Keywords

near-infrared（NIR）phosphorCr3+structure-function relationship

references

WEI Y， DANG P P， DAI Z， et al. Advances in near-infrared luminescent materials without Cr3+： crystal structure design， luminescence properties， and applications ［J］. Chem. Mater.， 2021， 33（14）： 5496-5526. doi: 10.1021/acs.chemmater.1c01325http://dx.doi.org/10.1021/acs.chemmater.1c01325

WANG Y Z， XIANG J Y， TANG Y， et al. A review of the application of near-infrared spectroscopy（NIRS） in forestry ［J］. Appl. Spectrosc. Rev.， 2022， 57（4）： 300-317. doi: 10.1080/05704928.2021.1875481http://dx.doi.org/10.1080/05704928.2021.1875481

FU X P， YING Y B. Food safety evaluation based on near infrared spectroscopy and imaging： a review ［J］. Crit. Rev. Food Sci. Nutr.， 2016， 56（11）： 1913-1924. doi: 10.1080/10408398.2013.807418http://dx.doi.org/10.1080/10408398.2013.807418

程丽娟，刘贵珊，万国玲，等. 可见/近红外高光谱成像技术对长枣中葡萄糖含量的无损检测［J］. 发光学报， 2019， 40（8）： 1055-1063. doi: 10.3788/fgxb20194008.1055http://dx.doi.org/10.3788/fgxb20194008.1055

CHENG L J， LIU G S， WAN G L， et al. Non-destructive detective of glucose contect in Lingwu jujube by Vis/NIR hyperspectral imaging technology ［J］. Chin. J. Lumin.， 2019， 40（8）： 1055-1063. （in Chinese）. doi: 10.3788/fgxb20194008.1055http://dx.doi.org/10.3788/fgxb20194008.1055

SAKUDO A. Near-infrared spectroscopy for medical applications： current status and future perspectives ［J］. Clin. Chim. Acta， 2016， 455： 181-188. doi: 10.1016/j.cca.2016.02.009http://dx.doi.org/10.1016/j.cca.2016.02.009

刘映雪，朱福荣. 近红外光的可视化及其应用［J］. 液晶与显示， 2021， 36（1）： 78-104. doi: 10.37188/CJLCD.2020-0287http://dx.doi.org/10.37188/CJLCD.2020-0287

LIU Y S， ZHU F R. Visualization of near-infrared light and applications ［J］. Chin. J. Liq. Cryst. Disp.， 2021， 36（1）： 78-104. （in English）. doi: 10.37188/CJLCD.2020-0287http://dx.doi.org/10.37188/CJLCD.2020-0287

SCHUBERT E F， KIM J K. Solid-state light sources getting smart ［J］. Science， 2005， 308（5726）： 1274-1278. doi: 10.1126/science.1108712http://dx.doi.org/10.1126/science.1108712

张亮亮，张家骅，郝振东，等. Cr3+掺杂的宽带近红外荧光粉及其研究进展［J］. 发光学报， 2019， 40（12）： 1449-1459. doi: 10.3788/fgxb20194012.1449http://dx.doi.org/10.3788/fgxb20194012.1449

ZHANG L L， ZHANG J H， HAO Z D， et al. Recent progress on Cr3+ doped broad band NIR phosphors ［J］. Chin. J. Lumin.， 2019， 40（12）： 1449-1459. （in Chinese）. doi: 10.3788/fgxb20194012.1449http://dx.doi.org/10.3788/fgxb20194012.1449

FILIPPO R， TARALLI E， RAJTERI M. LEDs： sources and intrinsically bandwidth-limited detectors ［J］. Sensors， 2017， 17（7）： 1673-1-12. doi: 10.3390/s17071673http://dx.doi.org/10.3390/s17071673

XIA Z G， LIU Q L. Progress in discovery and structural design of color conversion phosphors for LEDs ［J］. Prog. Mater. Sci.， 2016， 84： 59-117. doi: 10.1016/j.pmatsci.2016.09.007http://dx.doi.org/10.1016/j.pmatsci.2016.09.007

王长建，乔旭升，樊先平. 蓝光LED激发Cr3+掺杂宽带近红外荧光粉研究进展［J］. 发光学报， 2022， 43（12）： 1855-1870. doi: 10.37188/cjl.20220271http://dx.doi.org/10.37188/cjl.20220271

WANG C J， QIAO X S， FAN X P. Research progress on blue LED excited Cr3+ doped phosphors with broad-band near- infrared luminescence ［J］. Chin. J. Lumin.， 2022， 43（12）： 1855-1870. （in Chinese）. doi: 10.37188/cjl.20220271http://dx.doi.org/10.37188/cjl.20220271

CHEN X H， SONG E H， ZHOU Y Y， et al. Distorted octahedral site occupation-induced high-efficiency broadband near-infrared emission in LiScGe2O6∶Cr3+ phosphor ［J］. J. Mater. Chem. C， 2021， 9（39）： 13640-13646. doi: 10.1039/D1TC03057Dhttp://dx.doi.org/10.1039/D1TC03057D

XU X X， SHAO Q Y， YAO L Q， et al. Highly efficient and thermally stable Cr3+-activated silicate phosphors for broadband near-infrared LED applications ［J］. Chem. Eng. J.， 2020， 383： 123108-1-8. doi: 10.1016/j.cej.2019.123108http://dx.doi.org/10.1016/j.cej.2019.123108

DE GUZMAN G N A， RAJENDRAN V， BAO Z， et al. Multi-site cation control of ultra-broadband near-infrared phosphors for application in light-emitting diodes ［J］. Inorg. Chem.， 2020， 59（20）： 15101-15110. doi: 10.1021/acs.inorgchem.0c02055http://dx.doi.org/10.1021/acs.inorgchem.0c02055

SHAO Q Y， DING H， YAO L Q， et al. Photoluminescence properties of a ScBO3∶Cr3+ phosphor and its applications for broadband near-infrared LEDs ［J］. RSC Adv.， 2018， 8（22）： 12035-12042. doi: 10.1039/c8ra01084fhttp://dx.doi.org/10.1039/c8ra01084f

YAO L Q， SHAO Q Y， XU X X， et al. Broadband emission of single-phase Ca3Sc2Si3O12∶Cr3+/Ln3+（Ln=Nd， Yb， Ce） phosphors for novel solid-state light sources with visible to near-infrared light output ［J］. Ceram. Int.， 2019， 45（11）： 14249-14255. doi: 10.1016/j.ceramint.2019.04.133http://dx.doi.org/10.1016/j.ceramint.2019.04.133

ZHANG L L， ZHANG S， HAO Z D， et al. A high efficiency broad-band near-infrared Ca2LuZr2Al3O12∶Cr3+ garnet phosphor for blue LED chips ［J］. J. Mater. Chem. C， 2018， 6（18）： 4967-4976. doi: 10.1039/C8TC01216Dhttp://dx.doi.org/10.1039/C8TC01216D

ZHAO F Y， CAI H， SONG Z， et al. Structural confinement for Cr3+ activators toward efficient near-infrared phosphors with suppressed concentration quenching ［J］. Chem. Mater.， 2021， 33（10）： 3621-3630. doi: 10.1021/acs.chemmater.1c00441http://dx.doi.org/10.1021/acs.chemmater.1c00441

ZHANG Z C， MA C G， GAUTIER R， et al. Structural confinement toward giant enhancement of red emission in Mn2+-based phosphors ［J］. Adv. Funct. Mater.， 2018， 28（41）： 1804150-1-7. doi: 10.1002/adfm.201804150http://dx.doi.org/10.1002/adfm.201804150

YAO L Q， SHAO Q Y， HAN S Y， et al. Enhancing near-infrared photoluminescence intensity and spectral properties in Yb3+ codoped LiScP2O7∶Cr3+ ［J］. Chem. Mater.， 2020， 32（6）： 2430-2439. doi: 10.1021/acs.chemmater.9b04934http://dx.doi.org/10.1021/acs.chemmater.9b04934

YUAN C X， LI R Y， LIU Y F， et al. Efficient and broadband LiGaP2O7∶Cr3+ phosphors for smart near-infrared light-emitting diodes ［J］. Laser Photonics Rev.， 2021， 15（11）： 2100227-1-8. doi: 10.1002/lpor.202100227http://dx.doi.org/10.1002/lpor.202100227

ZHANG H S， ZHONG J Y， ZHANG X L， et al. Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7∶Cr3+，Yb3+ phosphor ［J］. J. Alloys Compd.， 2022， 894： 162386-1-8. doi: 10.1016/j.jallcom.2021.162386http://dx.doi.org/10.1016/j.jallcom.2021.162386

ZHONG J Y， LI C J， ZHAO W R， et al. Accessing high-power near-infrared spectroscopy using Cr3+-substituted metal phosphate phosphors ［J］. Chem. Mater.， 2022， 34（1）： 337-344. doi: 10.1021/acs.chemmater.1c03671http://dx.doi.org/10.1021/acs.chemmater.1c03671

ZHAO F Y， CAI H， ZHANG S Y， et al. Octahedron-dependent near-infrared luminescence in Cr3+-activated phosphors ［J］. Mater. Today Chem.， 2022， 23： 100704-1-8. doi: 10.1016/j.mtchem.2021.100704http://dx.doi.org/10.1016/j.mtchem.2021.100704

LIU T Y， CAI H， MAO N， et al. Efficient near-infrared pyroxene phosphor LiInGe2O6∶Cr3+ for NIR spectroscopy application ［J］. J. Am. Ceram. Soc.， 2021， 104（9）： 4577-4584. doi: 10.1111/jace.17856http://dx.doi.org/10.1111/jace.17856

ADACHI S. Spectroscopy of Cr3+ activator： Tanabe-Sugano diagram and Racah parameter analysis ［J］. J. Lumin.， 2021， 232： 117844-1-7. doi: 10.1016/j.jlumin.2020.117844http://dx.doi.org/10.1016/j.jlumin.2020.117844

ADACHI S. Luminescence spectroscopy of 3d3（Mn4+， Cr3+） ions in multiple octahedral-site phosphors ［J］. ECS J. Solid State Sci. Technol.， 2022， 11（4）： 046002-1-9. doi: 10.1149/2162-8777/ac63e4http://dx.doi.org/10.1149/2162-8777/ac63e4

ADACHI S. Luminescence spectroscopy of Cr3+ in an oxide： a strong or weak crystal-field phosphor？［J］. J. Lumin.， 2021， 234： 117965-1-4. doi: 10.1016/j.jlumin.2021.117965http://dx.doi.org/10.1016/j.jlumin.2021.117965

FANG M H， LEAÑO J L JR， LIU R S. Control of narrow-band emission in phosphor materials for application in light-emitting diodes ［J］. ACS Energy Lett.， 2018， 3（10）： 2573-2586. doi: 10.1021/acsenergylett.8b01408http://dx.doi.org/10.1021/acsenergylett.8b01408

ROBINSON K， GIBBS G V， RIBBE P H. Quadratic elongation： a quantitative measure of distortion in coordination polyhedra ［J］. Science， 1971， 172（3983）： 567-570. doi: 10.1126/science.172.3983.567http://dx.doi.org/10.1126/science.172.3983.567

MENG X Y， WANG Z J， QIU K L， et al. Design of a novel near-infrared phosphor by controlling the cationic coordination environment ［J］. Cryst. Growth Des.， 2018， 18（8）： 4691-4700. doi: 10.1021/acs.cgd.8b00672http://dx.doi.org/10.1021/acs.cgd.8b00672

GAO T Y， ZHUANG W D， LIU R H， et al. Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineering ［J］. J. Alloys Compd.， 2020， 848： 156557-1-9. doi: 10.1016/j.jallcom.2020.156557http://dx.doi.org/10.1016/j.jallcom.2020.156557

HE F Q， SONG E H， ZHOU Y Y， et al. A general ammonium salt assisted synthesis strategy for Cr3+‐doped hexafluorides with highly efficient near infrared emissions ［J］. Adv. Funct. Mater.， 2021， 31（36）： 2103743-1-11. doi: 10.1002/adfm.202103743http://dx.doi.org/10.1002/adfm.202103743

姬海鹏，张宗涛， XU Jian，等. Mn4+激活氧氟化物红光荧光粉的研究进展［J］. 无机材料学报， 2020， 35（8）： 847-856. doi: 10.15541/jim20190554http://dx.doi.org/10.15541/jim20190554

JI H P， ZHANG Z T， XU J， et al. Advance in red-emitting Mn4+-activated oxyfluoride phosphors ［J］. J. Inorg. Mater.， 2020， 35（8）： 847-856. （in Chinese）. doi: 10.15541/jim20190554http://dx.doi.org/10.15541/jim20190554

姬海鹏. 荧光粉中激活剂离子掺杂格位分析［J］. 发光学报， 2022， 43（1）： 26-41. doi: 10.37188/CJL.20210309http://dx.doi.org/10.37188/CJL.20210309

JI H P. Analysis of site-occupation of activator in phosphors ［J］. Chin. J. Lumin.， 2022， 43（1）： 26-41. （in Chinese）. doi: 10.37188/CJL.20210309http://dx.doi.org/10.37188/CJL.20210309

TRUEBA A， GARCÍA-LASTRA J M， GARCIA-FERNANDEZ P， et al. Cr3+-doped fluorides and oxides： role of internal fields and limitations of the Tanabe-Sugano approach ［J］. J. Phys. Chem. A， 2011， 115（46）： 13399-13406. doi: 10.1021/jp207249whttp://dx.doi.org/10.1021/jp207249w

ZHOU Y X， YI S P， FANG Z X， et al. Research on a new type of near-infrared phosphor Li2MgZrO4∶Cr3+- synthesis， crystal structure， photoluminescence and thermal stability ［J］. Opt. Mater.， 2021， 117： 111209-1-7. doi: 10.1016/j.optmat.2021.111209http://dx.doi.org/10.1016/j.optmat.2021.111209

Views

392

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Novel Far-red Phosphors (La,Gd,Y)₂MgTiO₆∶Cr³⁺ with Tunable Luminescence Spectra for Grow Light

Luminescence Properties and Application of Ce³⁺ Doped Ba₃Y₂（BO₃）₄ Phosphor

Methods for Evaluating Hydrolytic Degradation of Mn⁴⁺-activated Fluoride Phosphors

Related Author

Jia-yu WU

Zhen-zhen ZHANG

Song LI

Shi-xun LIAN

Li-ping YU

Zhong-xian QIU

Pei-xin GAO

Peng DONG

Related Institution

Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization

School of Chemistry and Materials Science, Hunan Agricultural University, Hunan Agricultural University

Hunan Optical Agriculture Engineering Technology Research Center, Hunan Agricultural University

Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS

Siberian Federal University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Design and Regulation of Near-infrared Emission Wavelength of Cr3+ in Isolated Lattice Sites: A Case Study of AMP2O7∶Cr3+

DOI：10.37188/CJL.20220320

摘要

Abstract

关键词

Keywords

references

Design and Regulation of Near-infrared Emission Wavelength of Cr³⁺ in Isolated Lattice Sites: A Case Study of AMP₂O₇∶Cr³⁺