Growth and Luminescence Properties of Tb<sup>3+</sup> Ions Doped CaF<sub>2</sub> Crystals

LIU Jian; WANG Wu-di; SONG Qing-song; DONG Jian-shu; XUE Yan-yan; WANG Qing-guo; XU Xiao-dong; SU Liang-bi; XU Jun

doi:10.37188/CJL.20220229

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Growth and Luminescence Properties of Tb³⁺ Ions Doped CaF₂ Crystals

Invited Paper | 更新时间：2022-12-08

- Growth and Luminescence Properties of Tb³⁺ Ions Doped CaF₂ Crystals
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 11, Pages: 1750-1757(2022)
- 作者机构：
  
  1.同济大学物理科学与工程学院，高等研究院，上海　200092
  2.江苏师范大学物理电子与工程学院江苏省先进激光材料与器件重点实验室，江苏徐州　221116
  3.中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室，上海　201899
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(61621001;62075166)
- DOI：10.37188/CJL.20220229
  CLC： O482.31
- Published：05 November 2022，
  
  Received：06 June 2022，
  
  Revised：19 June 2022，
- 稿件说明：
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刘坚,王无敌,宋青松等.Tb³⁺离子掺杂CaF₂晶体的生长和发光性能[J].发光学报,2022,43(11):1750-1757.

LIU Jian,WANG Wu-di,SONG Qing-song,et al.Growth and Luminescence Properties of Tb³⁺ Ions Doped CaF₂ Crystals[J].Chinese Journal of Luminescence,2022,43(11):1750-1757.
刘坚,王无敌,宋青松等.Tb³⁺离子掺杂CaF₂晶体的生长和发光性能[J].发光学报,2022,43(11):1750-1757. DOI： 10.37188/CJL.20220229.

LIU Jian,WANG Wu-di,SONG Qing-song,et al.Growth and Luminescence Properties of Tb³⁺ Ions Doped CaF₂ Crystals[J].Chinese Journal of Luminescence,2022,43(11):1750-1757. DOI： 10.37188/CJL.20220229.

摘要

使用温梯法生长了10%Tb，

%Y∶CaF

（

= 0，3，5，10）系列晶体。通过X射线衍射分析了晶体结构，结果表明高浓度的稀土离子掺杂使得晶胞参数增大，但是仍然保持CaF

的萤石立方结构。采用吸收光谱、发射光谱及荧光衰减曲线等测试数据对其发光性能进行了研究。通过J⁃O理论计算，共掺Y

离子后，光谱品质因子

由0.75增加到0.80。F‑L公式计算得到10%Tb∶CaF

绿光545 nm处和黄光583 nm处的发射截面分别为0.89×10

-21

和0.082×10

-21

，10%Tb，10%Y∶CaF

在绿光545 nm处和黄光583 nm处的发射截面分别为0.89×10

-21

和0.077×10

-21

。并且Tb

离子

能级的荧光寿命都在5 ms以上，并不存在高浓度掺杂导致的荧光寿命降低现象，长荧光寿命意味着Tb

离子绝佳的储能能力。实验结果表明，Tb∶CaF

及Tb，Y∶CaF

晶体是有极大潜力实现可见激光输出的激光增益介质。

Abstract

A series of 10%Tb∶

%Y∶CaF

（

= 0， 3， 5， 10） crystals have been successfully grown by the temperature gradient technique（TGT）. The crystal structure was analyzed by X-ray diffraction， and the results showed that the high concentration of rare earth ion doping increased the unit cell parameters， but still maintained the fluorite cubic structure of CaF

. The absorption spectra， fluorescence spectra， and fluorescence decay curves were measured and analyzed at room temperature. By co-doping Y

ions， the spectral quality factor

increased from 0.75 to 0.80. Using F-L formula， the emission cross sections of 10%Tb∶CaF

were calculated to be 0.89×10

-21

and 0.082×10

-21

for the 545 nm and 587 nm， respectively， and the emission cross sections of 10% Tb，10%Y∶CaF

were calculated to be 0.89×10

-21

and 0.077×10

-21

for the 545 nm and 587 nm. The fluorescence lifetime of

level is more than 5 ms， and there is no fluorescence lifetime quenching phenomenon caused by high concentration doping. The long fluorescence lifetime means that Tb

ion has excellent energy storage capacity. The experimental results show that Tb∶CaF

and Tb，Y∶CaF

crystals are gain mediums with great potential to realize visible laser output.

关键词

Tb∶CaF2可见激光光谱性能J-O 理论

Keywords

Tb∶CaF2visible laserspectral propertiesJ-O theory

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Related Institution

School of Physics Science and Engineering， Institute for Advanced Study， Tongji University

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Key Laboratory of Optoelectronic Materials Chemistry and Physics， Fujian Institute of Research on The Structure of Matter， Chinese Academy of Sciences

College of Chemistry， Fuzhou University

Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China （Mindu Innovation Laboratory）

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⁰

Growth and Luminescence Properties of Tb3+ Ions Doped CaF2 Crystals

DOI：10.37188/CJL.20220229

摘要

Abstract

关键词

Keywords

references

Growth and Luminescence Properties of Tb³⁺ Ions Doped CaF₂ Crystals