Structure-property Correlation and Phenomenological Theory in Ce<sup>3+</sup>/Eu<sup>2+</sup>-doped Inorganic Luminescent Materials

WANG Shu-xin; SONG Zhen; LIU Quan-lin

doi:10.37188/CJL.20220191

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Structure-property Correlation and Phenomenological Theory in Ce³⁺/Eu²⁺-doped Inorganic Luminescent Materials

Invited Paper | 更新时间：2023-02-13

- Structure-property Correlation and Phenomenological Theory in Ce³⁺/Eu²⁺-doped Inorganic Luminescent Materials
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 9, Pages: 1319-1339(2022)
- 作者机构：
  
  1.北京科技大学材料科学与工程学院，北京　100083
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51832005;51672027)
- DOI：10.37188/CJL.20220191
  CLC：
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WANG Shu-xin, SONG Zhen, LIU Quan-lin. Structure-property Correlation and Phenomenological Theory in Ce³⁺/Eu²⁺-doped Inorganic Luminescent Materials. [J]. Chinese Journal of Luminescence 43(9):1319-1339(2022)
DOI：

WANG Shu-xin, SONG Zhen, LIU Quan-lin. Structure-property Correlation and Phenomenological Theory in Ce³⁺/Eu²⁺-doped Inorganic Luminescent Materials. [J]. Chinese Journal of Luminescence 43(9):1319-1339(2022) DOI： 10.37188/CJL.20220191.

摘要

Ce,3+,/Eu,2+,掺杂无机发光材料在照明、显示、监测、示踪、防伪以及信息存储等领域具有重要应用。Ce,3+,/Eu,2+,的5d电子与基质材料中近邻阴离子配体之间存在强交互作用，共价键效应、晶体场劈裂和电声子耦合作用可以有效调控其激发光谱和发射光谱，从而赋予Ce,3+,/Eu,2+,掺杂无机固体高效可调的优异性能。近年来，研究人员研发出了许多Ce,3+,/Eu,2+,掺杂的无机发光材料，并深入研究了其成分、结构与性能之间的关系。本文系统综述了Ce,3+,/Eu,2+,掺杂无机发光材料的构效关系与唯象理论研究进展，详细总结了基质材料组分、晶体结构、局域结构和电子结构对发光性能的影响规律，并对未来发展提出了展望。

Abstract

Ce,3+,/Eu,2+,-doped inorganic luminescence materials have been well developed as an indispensable component in fields of lighting， display， monitoring， tracing， anti-counterfeiting， and information storage. The f-d transitions from isolated luminescent centers Ce,3+,/Eu,2+, are strongly influenced by the coordinated crystalline environment， under which energy levels of Ce,3+,/Eu,2+, may be split and shifted due to covalency effect， crystal field splitting， and electron-phonon coupling， resulting in their highly tunable luminescence properties. To date， researchers have developed many high-performance Ce,3+,/Eu,2+,-doped luminescent materials， and a series of sound theories have been established to gain insight into the composition-structure-property correlations. Herein， we review the current progress in Ce,3+,/Eu,2+,-doped phosphors， focusing on composition-structure-property correlation and phenomenological theory. Particular attention is devoted to overviewing the effect of the local structure and electronic structure on the luminescence property. Finally， an outlook toward potential theory developments is proposed.

关键词

Ce3+/Eu2+无机发光材料构效关系唯象理论局域结构电子结构

Keywords

Ce3+/Eu2+inorganic luminescence materialsstructure-property correlationphenomenological theorylocal structureelectronic structure

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Structure-property Correlation and Phenomenological Theory in Ce3+/Eu2+-doped Inorganic Luminescent Materials

DOI：10.37188/CJL.20220191

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Structure-property Correlation and Phenomenological Theory in Ce³⁺/Eu²⁺-doped Inorganic Luminescent Materials