Near-infrared Photoluminescence Properties of NaAlP2O7∶Cr3+ Phosphor

HE Xian-guo; HUANG De-cai; SONG Li-ping; LIANG Si-si; ZHU Hao-miao

doi:10.37188/CJL.20220180

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Near-infrared Photoluminescence Properties of NaAlP₂O₇∶Cr³⁺ Phosphor

Invited Paper | 更新时间：2023-02-13

- Near-infrared Photoluminescence Properties of NaAlP₂O₇∶Cr³⁺ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 9, Pages: 1380-1389(2022)
- 作者机构：
  
  1.福州大学化学学院，福建福州　350108
  2.中国科学院福建物质结构研究所中国科学院功能纳米结构设计与组装重点实验室，福建省纳米材料重点实验室，福建福州　350002
  3.厦门稀土材料研究所厦门市稀土光电功能材料重点实验室，福建厦门　361021
  4.中国科学院赣江创新研究院，江西赣州　341000
- 作者简介：
- 基金信息：
  
  National Key R&D Program of China(2021YFB3500400);National Natural Science Foundation of China(11904363);Key Research Program of The Chinese Academy of Sciences(ZDRW⁃CN⁃2021⁃3)
- DOI：10.37188/CJL.20220180
  CLC： O482.31
- Published：05 September 2022，
  
  Received：05 May 2022，
  
  Revised：17 May 2022，
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何献国,黄得财,宋丽平等.NaAlP₂O₇∶Cr³⁺荧光粉近红外发光特性[J].发光学报,2022,43(09):1380-1389.

HE Xian-guo,HUANG De-cai,SONG Li-ping,et al.Near-infrared Photoluminescence Properties of NaAlP₂O₇∶Cr³⁺ Phosphor[J].Chinese Journal of Luminescence,2022,43(09):1380-1389.
何献国,黄得财,宋丽平等.NaAlP₂O₇∶Cr³⁺荧光粉近红外发光特性[J].发光学报,2022,43(09):1380-1389. DOI： 10.37188/CJL.20220180.

HE Xian-guo,HUANG De-cai,SONG Li-ping,et al.Near-infrared Photoluminescence Properties of NaAlP₂O₇∶Cr³⁺ Phosphor[J].Chinese Journal of Luminescence,2022,43(09):1380-1389. DOI： 10.37188/CJL.20220180.

摘要

宽带近红外荧光粉转换型LED光源在医学成像、食品检测以及传感等领域展现出了巨大的应用前景，该类光源的光谱和效率与所用近红外荧光粉的性能紧密相关，Cr

离子激活的近红外发光材料具有可被蓝光有效激发、发射光谱可调等优点，因此得到了重点关注。本文采用高温固相法制备了NaAlP

∶Cr

宽带近红外发光荧光粉，该材料在450 nm蓝光激发下，发射出650~1 000 nm的近红外光，峰值位于780 nm，半高宽为 1 580 cm

-1

；其在423 K下的发光强度能够维持室温下的71%，表现出良好的发光热稳定性。对材料的晶体结构和变温光谱（8~503 K）进行了系统的分析，计算得到了Cr

离子在NaAlP

基质中的晶体场强度等参数；利用8 K低温光谱，并结合计算，分析了Cr

各能级零声子线；基于高温变温光谱，讨论了材料的电⁃声子耦合效应及荧光热猝灭机理。

Abstract

Near-infrared phosphor-converted light-emitting diode（NIR pc-LED） light source has a great application prospect in medical imaging， food detection， sensing and other aspects. The spectral characteristic and photoelectric conversion efficiency of the pc-LEDs are highly dependent on the performance of NIR phosphors. Currently， the development of inexpensive， efficient， and thermally stable broadband NIR phosphors remains a great challenge. Among the potential broadband NIR phosphors， the Cr

activated NIR materials have attracted serious attentions due to their advantages of being able to be excited efficiently by blue light and tunable emission band. In this study， a broadband NIR phosphor NaAlP

∶Cr

was successfully synthesized by high temperature solid-state method. Under 450 nm blue light excitation， the phosphor shows a broadband emission covering 650-1 000 nm with a peak centered at ~780 nm and a full width at half-maximum（FWHM） of 1 580 cm

-1

. Particularly， at 423 K， the NaAlP

∶4%Cr

sample retained ~71% of the photoluminescence（PL） intensity at room temperature， exhibiting good PL thermal stability. Furthermore， the crystallographic site occupation and crystal field strength parameter of Cr

ions in NaAlP

host were investigated based on the structural analysis and temperature-dependent（8-503 K） spectra of the phosphor. The zero-phonon lines of Cr

energy levels were determined by low temperature spectroscopy at 8 K and theoretical calculation. The PL thermal quenching mechanism of Cr

was discussed in combination with high temperature dependent spectra. In summary，

this work presents a new broadband NIR phosphor for application in NIR pc-LEDs， and highlights some strategies to explore this class of materials.

关键词

近红外荧光粉宽带发射热猝灭电-声子耦合

Keywords

near-infrared phosphorbroadband emissionphotoluminescence thermal quenchingelectron-phonon coupling

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