Fabrication and Characterization of Dy,Tb∶LuAG Transparent Ceramics for Yellow Lasers

LIU Qiang; WU Long-fei; LI Xiao-ying; LIU Zi-yu; CHEN Peng-hui; TIAN Feng; XIE Teng-fei; PIRRI Angela; TOCI Guido; LI Jiang

doi:10.37188/CJL.20220153

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Fabrication and Characterization of Dy,Tb∶LuAG Transparent Ceramics for Yellow Lasers

Invited Paper | 更新时间：2022-12-08

- Fabrication and Characterization of Dy,Tb∶LuAG Transparent Ceramics for Yellow Lasers
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 11, Pages: 1733-1740(2022)
- 作者机构：
  
  1.江苏大学材料科学与工程学院，江苏镇江　212013
  2.中国科学院上海硅酸盐研究所透明光功能无机材料重点实验室，上海　201899
  3.中国科学院大学材料与光电研究中心，北京　100049
  4.Istituto di Fisica Applicata “N. Carrara”， Consiglio Nazionale delle Ricerche， CNR⁃IFAC， Via Madonna del Piano 10C， 50019 Sesto Fiorentino（Fi）， Italy
  5.Istituto Nazionale di Ottica， Consiglio Nazionale delle Ricerche， CNR‑INO， Via Madonna del Piano 10C， 50019 Sesto Fiorentino（Fi）， Italy
- 作者简介：
- 基金信息：
  
  中国科学院国际伙伴计划(121631KYSB20200039);上海市科委国际合作项目(20520750200)
- DOI：10.37188/CJL.20220153
  CLC： O482.31
- Published：05 November 2022，
  
  Received：23 April 2022，
  
  Revised：11 May 2022，
- 稿件说明：
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刘强,武龙飞,李晓英等.黄光激光用Dy,Tb∶LuAG透明陶瓷的制备与性能研究[J].发光学报,2022,43(11):1733-1740.

LIU Qiang,WU Long-fei,LI Xiao-ying,et al.Fabrication and Characterization of Dy,Tb∶LuAG Transparent Ceramics for Yellow Lasers[J].Chinese Journal of Luminescence,2022,43(11):1733-1740.
刘强,武龙飞,李晓英等.黄光激光用Dy,Tb∶LuAG透明陶瓷的制备与性能研究[J].发光学报,2022,43(11):1733-1740. DOI： 10.37188/CJL.20220153.

LIU Qiang,WU Long-fei,LI Xiao-ying,et al.Fabrication and Characterization of Dy,Tb∶LuAG Transparent Ceramics for Yellow Lasers[J].Chinese Journal of Luminescence,2022,43(11):1733-1740. DOI： 10.37188/CJL.20220153.

摘要

以NH

HCO

为沉淀剂，通过共沉淀法合成了分散性良好的Dy，Tb∶LuAG纳米粉体，并研究了前驱体的热分解行为、粉体的物相及显微形貌。在不添加任何烧结助剂的情况下，采用真空预烧结合热等静压烧结技术首次制备出高透明的Dy，Tb∶LuAG陶瓷，并研究了预烧温度对陶瓷显微形貌及光学质量的影响。当预烧温度为1 600 ℃时，退火后的Dy，Tb∶LuAG陶瓷（厚度为1.5 mm）在578 nm处的直线透过率达到83.6%，平均晶粒尺寸为0.9 μm。此外，退火后的3%Dy，1%Tb∶LuAG透明陶瓷在447 nm的吸收截面积为1.3×10

-21

，半高宽为3.0 nm，与商用GaN蓝色激光二极管具有良好的匹配性。研究表明，Dy，Tb∶LuAG透明陶瓷在黄光激光领域具有潜在的应用价值。

Abstract

3%Dy，1%Tb∶LuAG（Dy，Tb∶LuAG） nanopowders with good dispersibility were synthesized by the co-precipitation method using NH

HCO

as a precipitant. The thermal decomposition behavior of the precursor， and the phase and microstructure of powders were studied. Dy，Tb∶LuAG ceramics with high transparency were fabricated by vacuum pre-sintering and hot isostatic pressing（HIP） post-treatment without any sintering additives for the first time. The influences of pre-sintering temperature on the microstructure and the optical quality of the ceramics were investigated. When the pre-sintering temperature is 1 600 ℃， the in-line transmittance of the annealed Dy，Tb∶LuAG ceramics（1.5 mm in thickness） reaches 83.6% at 578 nm， and the average grain size of the annealed ceramics is 0.9 μm. In addition， the absorption cross section of the 3%Dy，1%Tb∶LuAG ceramics at 447 nm is calculated to be 1.3×10

-21

， with a full width at half maximum（FWHM） of 3.0 nm， which matches that of commercial GaN blue laser diodes. This study shows that Dy，Tb∶LuAG transparent ceramics have potential application value in the yellow lasers.

关键词

Dy，Tb∶LuAG透明陶瓷共沉淀法热等静压烧结

Keywords

Dy，Tb∶LuAGtransparent ceramicsco-precipitation methodhot isostatic pressing

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