Two-photon Luminescence of CsPbBr<sub>3</sub> Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method

YANG Min; YUE Peng; LIAN Lan-qi; LIU Shao-ding

doi:10.37188/CJL.20220113

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Two-photon Luminescence of CsPbBr₃ Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method

Synthesis and Properties of Materials | 更新时间：2022-10-19

- Two-photon Luminescence of CsPbBr₃ Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 8, Pages: 1207-1216(2022)
- 作者机构：
  
  1.太原理工大学新型传感器与智能控制教育部与山西省重点实验室，山西太原　030024
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11874276;11574228);Key Research and Development Program of Shanxi Province(201903D121131)
- DOI：10.37188/CJL.20220113
  CLC：
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YANG Min, YUE Peng, LIAN Lan-qi, et al. Two-photon Luminescence of CsPbBr₃ Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method. [J]. Chinese Journal of Luminescence 43(8):1207-1216(2022)
DOI：

YANG Min, YUE Peng, LIAN Lan-qi, et al. Two-photon Luminescence of CsPbBr₃ Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method. [J]. Chinese Journal of Luminescence 43(8):1207-1216(2022) DOI： 10.37188/CJL.20220113.

摘要

全无机金属卤化物钙钛矿材料的非线性光学效应对构建新型微纳光子器件具有重要意义。本文重点研究了微米尺度CsPbBr,3,钙钛矿单晶颗粒的双光子发射特性，实验中基于声化学合成法制备了不同尺寸的CsPbBr,3,微晶颗粒，通过对激发光能量密度、波长、偏振的调整，研究了其对双光子发光特性的影响。实验结果表明在室温下CsPbBr,3,微晶即具有较强的双光子发光。波长相关的光致发光光谱表明，同一吸收带隙下，其发光峰位相对于单光子发射变化不大，且随着激发波长的增大双光子发射强度逐渐降低。此外，CsPbBr,3,微晶颗粒双光子发射具有偏振依赖性行为，偏振角度在0°~360°范围内呈现四重对称性。上述CsPbBr,3,微晶的双光子发光特性使其有望用于非线性集成器件。

Abstract

The nonlinear optical effect of all-inorganic metal halide perovskite materials is important for the design of novel micro- and nano-photonic devices. In this paper， the two-photon luminescence of micro-scale CsPbBr,3, perovskite single crystal particles is investigated. In the experiment， CsPbBr,3, microcrystals with different sizes were prepared based on the sonochemistry synthesis method， and the variations of the two-photon luminescence were studied by adjusting the energy density， wavelength and polarization of the pump laser beam. The experimental results demonstrate that the CsPbBr,3, microcrystals possess strong two-photon luminescence at room temperature. The wavelength-dependent two-photon luminescence spectrum shows that under the same absorption band gap， the luminescence peak position does not change much compared with the single-photon emission， and the two-photon emission intensity gradually decreases with the increase of excitation wavelength. In addition， the two-photon emission of CsPbBr,3, microcrystals reveals polarization-dependent behavior and the polarization angle presents quadruple symmetry in the range of 0°-360°. The two-photon luminescence responses of the CsPbBr,3, microcrystals make them promising for nonlinear integrated devices.

关键词

CsPbBr3钙钛矿微晶光致发光双光子发光非线性效应

Keywords

CsPbBr3 perovskite microcrystalsphotoluminescencetwo-photon luminescencenonlinear effect

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Two-photon Luminescence of CsPbBr3 Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method

DOI：10.37188/CJL.20220113

摘要

Abstract

关键词

Keywords

references

Two-photon Luminescence of CsPbBr₃ Perovskite Microcrystals Fabricated with Sonochemistry Synthesis Method