Basic Knowledge for Understanding Spectroscopic Property of Mn<sup>4+</sup> Ion

JI Hai-peng

doi:10.37188/CJL.20220102

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Basic Knowledge for Understanding Spectroscopic Property of Mn⁴⁺ Ion

Views on Basic Knowledge of Luminescence | 更新时间：2022-10-19

- Basic Knowledge for Understanding Spectroscopic Property of Mn⁴⁺ Ion
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 8, Pages: 1175-1187(2022)
- 作者机构：
  
  1.郑州大学材料科学与工程学院郑州市先进能源催化功能材料制备技术重点实验室，河南郑州　450001
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51902291);China Postdoctoral Science Foundation(2019M662524);Postdoctoral Research Sponsorship in Henan Province(19030025);Key R & D and promotion projects in Henan Province(212102210180);Hebei Key Laboratory of Dielectric and Electrolyte Functional Material, Northeastern University at Qinhuangdao(HKDEFM2021301);Young Talents Lifting Project from Henan Association for Science and Technology(2022HYTP016)
- DOI：10.37188/CJL.20220102
  CLC：
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JI Hai-peng. Basic Knowledge for Understanding Spectroscopic Property of Mn⁴⁺ Ion. [J]. Chinese Journal of Luminescence 43(8):1175-1187(2022)
DOI：

JI Hai-peng. Basic Knowledge for Understanding Spectroscopic Property of Mn⁴⁺ Ion. [J]. Chinese Journal of Luminescence 43(8):1175-1187(2022) DOI： 10.37188/CJL.20220102.

摘要

介绍了Mn,4+,离子发光光谱学的一些基础知识，包括如何确定Mn,4+,自由离子的光谱项和如何确定Mn,4+,离子各光谱项在八面体晶体场中的劈裂等。最后就如何理解Mn,4+,激活荧光粉的荧光光谱（比如如何确定各跃迁的零声子线位置、如何调节发射光子能量等）进行了讨论。

Abstract

By introducing the related basic knowledge， this paper provided a tutorial for understanding the optical property of Mn,4+, ion， including how to determine the LS term of a free Mn,4+, ion， and how to determine the splitting of these LS terms in an ,O,h, point group， ,etc,. Finally， this paper discussed how to analyze the photoluminescence spectra of Mn,4+,-doped phosphors， including how to determine the zero phonon line energy of each involved transitions， how to adjust the energy of the emitting photons， ,etc,.

关键词

Mn4+发光光谱学

Keywords

Mn4+optical spectroscopy

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Key Laboratory of Advanced Energy Catalytic and Functional Material Preparation of Zhengzhou City， School of Materials;Science and Engineering， Zhengzhou University

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Basic Knowledge for Understanding Spectroscopic Property of Mn4+ Ion

DOI：10.37188/CJL.20220102

摘要

Abstract

关键词

Keywords

references

Basic Knowledge for Understanding Spectroscopic Property of Mn⁴⁺ Ion