Up-conversion Luminescence and Temperature Sensing Properties of La<sub>2</sub><italic style="font-style: italic">A</italic>TiO<sub>6</sub>（<italic style="font-style: italic">A</italic>=Mg, Zn） Phosphor

WEN Yi-nuo; ZHOU Liu-yan; CHEN Yan-ling; LIN Jian-hua; FU Jie; CHEN Shu-yang; HAN Ming-xiao; LI Jie; DENG De-gang; CHEN Liang

doi:10.37188/CJL.20220099

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Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor

Synthesis and Properties of Materials | 更新时间：2022-11-04

- Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 10, Pages: 1552-1563(2022)
- 作者机构：
  
  1.中国计量大学光电材料与器件研究所，浙江杭州　310018
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(52172164);the Fundamental Research Funds for the Provincial Universities of Zhejiang(2020YW21;2020YW23;2019YW03;2020YW31)
- DOI：10.37188/CJL.20220099
  CLC：
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WEN Yi-nuo, ZHOU Liu-yan, CHEN Yan-ling, et al. Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor. [J]. Chinese Journal of Luminescence 43(10):1552-1563(2022)
DOI：

WEN Yi-nuo, ZHOU Liu-yan, CHEN Yan-ling, et al. Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor. [J]. Chinese Journal of Luminescence 43(10):1552-1563(2022) DOI： 10.37188/CJL.20220099.

摘要

Er,3+,的上转换性能强烈依赖局部位置对称畸变。在本研究中，采用高温固相法制备了La,2,Mg,（1-,w,）,Zn,w,TiO,6,∶,x,Er,3+,（,x,=0，0.02，0.04，0.06，0.08，0.10；,w=,0，0.3，0.5，0.7，1.0）系列荧光粉。基于XRD精修，Zn,2+,的掺杂改变了La,2,MgTiO,6,晶体的配位环境，晶相由,Pbnm,转变为,P,2,1/,n,。在980 nm激光激发下，样品上转换荧光强度随Er,3+,离子浓度改变，当Er,3+,离子浓度为,x,=0.06时样品的上转换荧光强度最强。基于荧光强度比技术研究了样品La,2,Mg,（1-,w,）,Zn,w,TiO,6,∶,x,Er,3+,（,x,=0.06；,w,=0，0.3，0.5，0.7，1.0）在303～583 K温度范围内的上转换荧光温度传感特性。实验结果表明，灵敏度随着Mg,2+,和Zn,2+,掺杂浓度比例的改变而改变，在,w,=1.0时达到最大绝对灵敏度0.90%·K,-1,，说明Zn,2+,的掺杂提高了La,2,MgTiO,6,的灵敏度。

Abstract

The up-conversion performance of Er,3+, strongly depends on local position symmetry distortion. In this study， the series of La,2（1-,x,）,Zn,w,Mg,（1,-w,）,TiO,6,∶,x,Er,3+,（,x,=0.06； ,w,=0， 0.3， 0.5， 0.7， 1.0） were prepared by solid state reaction at high temperature. According to XRD refinement， the coordination environment of La,2,MgTiO,6, crystal was changed by Zn,2+, doping， and the crystal phase changed from ,Pbnm, to ,P,2,1/,n,. Besides， the up-conversion fluorescence intensity of the sample changed with the change of Er,3+, ion concentration excited by a 980 nm laser， and the concentration of Er,3+, was ,x,=0.06 when the up-conversion fluorescence intensity was the highest. Based on the fluorescence intensity ratio technique， the temperature sensing properties of the samples La,2（1-,x,）,Zn,w,Mg,（1,-w,）,TiO,6,∶,x,Er,3+,（,x,=0.06； ,w,=0， 0.3， 0.5， 0.7， 1.0） were studied from 303 K to 583 K. The results show that the sensitivity changes with the concentration ratio of Mg,2+, and Zn,2+, and reaches the maximum absolute sensitivity of 0.90%·K,-1, when ,w,=1.0， which indicates that the doping of Zn,2+, increases the sensitivity of La,2,MgTiO,6,.

关键词

Er3+掺杂荧光粉荧光性能温度传感

Keywords

Er3+ dopingfluorescent powderfluorescence propertiestemperature sensing

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Up-conversion Luminescence and Temperature Sensing Properties of La2ATiO6（A=Mg, Zn） Phosphor

DOI：10.37188/CJL.20220099

摘要

Abstract

关键词

Keywords

references

Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor