Up-conversion Luminescence and Temperature Sensing Properties of La<sub>2</sub><italic style="font-style: italic">A</italic>TiO<sub>6</sub>（<italic style="font-style: italic">A</italic>=Mg, Zn） Phosphor

WEN Yi-nuo; ZHOU Liu-yan; CHEN Yan-ling; LIN Jian-hua; FU Jie; CHEN Shu-yang; HAN Ming-xiao; LI Jie; DENG De-gang; CHEN Liang

doi:10.37188/CJL.20220099

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Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor

Synthesis and Properties of Materials | 更新时间：2023-10-27

- Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 10, Pages: 1552-1563(2022)
- 作者机构：
  
  中国计量大学光电材料与器件研究所，浙江杭州　310018
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(52172164);the Fundamental Research Funds for the Provincial Universities of Zhejiang(2020YW21;2020YW23;2019YW03;2020YW31)
- DOI：10.37188/CJL.20220099
  CLC： O482.31
- Published：05 October 2022，
  
  Received：23 March 2022，
  
  Revised：11 April 2022，
- 稿件说明：
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温一诺,周柳艳,陈彦伶等.La₂ATiO₆（A=Mg，Zn）∶Er³⁺荧光材料的上转换发光特性及温度传感特性调控[J].发光学报,2022,43(10):1552-156310.37188/CJL.20220099.

WEN Yi-nuo,ZHOU Liu-yan,CHEN Yan-ling,et al.Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor[J].Chinese Journal of Luminescence,2022,43(10):1552-156310.37188/CJL.20220099.
温一诺,周柳艳,陈彦伶等.La₂ATiO₆（A=Mg，Zn）∶Er³⁺荧光材料的上转换发光特性及温度传感特性调控[J].发光学报,2022,43(10):1552-156310.37188/CJL.20220099. DOI：

WEN Yi-nuo,ZHOU Liu-yan,CHEN Yan-ling,et al.Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor[J].Chinese Journal of Luminescence,2022,43(10):1552-156310.37188/CJL.20220099. DOI：

摘要

的上转换性能强烈依赖局部位置对称畸变。在本研究中，采用高温固相法制备了La

（1-

）

TiO

∶

（

=0，0.02，0.04，0.06，0.08，0.10；

0，0.3，0.5，0.7，1.0）系列荧光粉。基于XRD精修，Zn

的掺杂改变了La

MgTiO

晶体的配位环境，晶相由

Pbnm

转变为

。在980 nm激光激发下，样品上转换荧光强度随Er

离子浓度改变，当Er

离子浓度为

=0.06时样品的上转换荧光强度最强。基于荧光强度比技术研究了样品La

（1-

）

TiO

∶

（

=0.06；

=0，0.3，0.5，0.7，1.0）在303～583 K温度范围内的上转换荧光温度传感特性。实验结果表明，灵敏度随着Mg

和Zn

掺杂浓度比例的改变而改变，在

=1.0时达到最大绝对灵敏度0.90%·K

-1

，说明Zn

的掺杂提高了La

MgTiO

的灵敏度。

Abstract

The up-conversion performance of Er

strongly depends on local position symmetry distortion. In this study， the series of La

2（1-

）

（1

-w

）

TiO

∶

（

=0.06；

=0， 0.3， 0.5， 0.7， 1.0） were prepared by solid state reaction at high temperature. According to XRD refinement， the coordination environment of La

MgTiO

crystal was changed by Zn

doping， and the crystal phase changed from

Pbnm

. Besides， the up-conversion fluorescence intensity of the sample changed with the change of Er

ion concentration excited by a 980 nm laser， and the concentration of Er

was

=0.06 when the up-conversion fluorescence intensity was the highest. Based on the fluorescence intensity ratio technique， the temperature sensing properties of the samples La

2（1-

）

（1

-w

）

TiO

∶

（

=0.06；

=0， 0.3， 0.5， 0.7， 1.0） were studied from 303 K to 583 K. The results show that the sensitivity changes with the concentration ratio of Mg

and Zn

and reaches the maximum absolute sensitivity of 0.90%·K

-1

when

=1.0， which indicates that the doping of Zn

increases the sensitivity of La

MgTiO

关键词

Er3+掺杂荧光粉荧光性能温度传感

Keywords

Er3+ dopingfluorescent powderfluorescence propertiestemperature sensing

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Related Author

Yi-nuo WEN

Liu-yan ZHOU

Yan-ling CHEN

LIN-Jian-hua

Jie FU

Shu-yang CHEN

Ming-xiao HAN

Jie Li

Related Institution

China University of Metrology， Institute of Optoelectronic Materials and Devices

University of Chinese Academy of Sciences

Key Laboratory of Optoelectronic Materials Chemistry and Physics， Fujian Institute of Research on the Structure of Matter， Chinese Academy of Sciences

College of Science， Dalian Maritime University

Institute of Laser Engineering， Faculty of Materials and Manufacturing， Beijing University of Technology

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⁰

Up-conversion Luminescence and Temperature Sensing Properties of La2ATiO6（A=Mg, Zn） Phosphor

DOI：10.37188/CJL.20220099

摘要

Abstract

关键词

Keywords

references

Up-conversion Luminescence and Temperature Sensing Properties of La₂ATiO₆（A=Mg, Zn） Phosphor