Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr3Gd（BO3）3∶Dy3+/<italic style="font-style: italic">RE</italic>3+（<italic style="font-style: italic">RE</italic>=Tb, Eu） Crystals

FANG Gao-yang; WANG Yan; YOU Zhen-yu; LI Jian-fu; ZHU Zhao-jie; TU Chao-yang

doi:10.37188/CJL.20220094

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Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu） Crystals

Invited Paper | 更新时间：2022-12-08

- Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu） Crystals
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 11, Pages: 1721-1732(2022)
- 作者机构：
  
  1.中国科学院福建物质结构研究所光电子材料化学与物理重点实验室，福建福州　350002
  2.福州大学化学学院，福建福州　350108
  3.中国福建光电信息科学与技术创新实验室（闽都创新实验室），福建福州　350108
- 作者简介：
- 基金信息：
  
  National Nature Science Foundation of China(51872286);the Director Fund Project of Mindu Innovation Laboratory(2021ZR204);the Strategic Priority Research Programs of the Chinese Academy of Sciences(XDB20010200)
- DOI：10.37188/CJL.20220094
  CLC：
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方高阳,王燕,游振宇等.Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu）晶体的生长、发光性质及能量传递[J].发光学报,2022,43(11):1721-1732.

FANG Gao-yang,WANG Yan,YOU Zhen-yu,et al.Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu） Crystals[J].Chinese Journal of Luminescence,2022,43(11):1721-1732.
方高阳,王燕,游振宇等.Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu）晶体的生长、发光性质及能量传递[J].发光学报,2022,43(11):1721-1732. DOI： 10.37188/CJL.20220094.

FANG Gao-yang,WANG Yan,YOU Zhen-yu,et al.Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu） Crystals[J].Chinese Journal of Luminescence,2022,43(11):1721-1732. DOI： 10.37188/CJL.20220094.

摘要

黄光激光在医疗美容、原子冷却与捕获、激光雷达等领域具有潜在的应用前景，因此，黄光激光器的研究具有重要意义。Dy,3+,因其,4,F,9/2,→,6,H,13/2,辐射跃迁而成为黄光激光的最佳激活离子，但是其在可见光波段为自旋禁戒跃迁，导致其吸收截面和发射截面都很小，从而引起黄光激光输出困难。本文通过提拉法成功生长了Dy,3+,∶Sr,3,Gd（BO,3,）,3,（缩写Dy,3+,∶SGB）、Dy,3+,/Tb,3+,∶SGB和Dy,3+,/Eu,3+,∶SGB晶体，通过室温偏振吸收谱、发射谱、荧光衰减曲线以及Judd-Ofelt理论计算分析了其光谱性能和能量传递机制。研究表明，共掺Tb,3+,和Eu,3+,增大了Dy,3+,在黄光波段的发射截面和荧光量子效率，有利于Dy,3+,的黄光输出。此外，证明了Dy,3+,/Tb,3+,∶SGB晶体中发生了Dy,3+,和Tb,3+,之间相互能量传递过程，Dy,3+,/Eu,3+,∶SGB晶体中仅有Dy,3+,→Eu,3+,的能量传递过程。

Abstract

The yellow lasers are of great importance as they have potential applications in the areas such as medical aesthetics， atomic cooling and trapping， and radar. Dy,3+, is the best activating ion for yellow lasers due to its ,4,F,9/2,→,6,H,13/2, radiative transition， but its spin-forbidden transition in the visible wavelength leads to a small absorption and emission cross section， which causes difficulties in yellow laser output. In this paper， Dy,3+,∶Sr,3,Gd（BO,3,）,3,（abbreviation Dy,3+,∶SGB）， Dy,3+,/Tb,3+,∶SGB and Dy,3+,/Eu,3+,∶SGB crystals were successfully grown by the Czochralski method， and their spectral properties and energy transfer mechanisms were analyzed by room-temperature polarization absorption spectra， emission spectra， fluorescence decay curves and Judd-Ofelt theoretical calculations. It is shown that the co-dopant of Tb,3+, and Eu,3+, increases the emission cross section and fluorescence quantum efficiency of Dy,3+, in the yellow emission band， which is favorable to the yellow laser output of Dy,3+,. In addition， it is demonstrated that a mutual energy transfer process between Dy,3+, and Tb,3+ ,occurs in Dy,3+,/Tb,3+,∶SGB crystals and only Dy,3+,→Eu,3+, in Dy,3+,/Eu,3+,∶SGB crystals.

关键词

Sr3Gd（BO3）3Dy3+黄光光谱性能能量传递

Keywords

Sr3Gd（BO3）3Dy3+yellow emissionspectral propertiesenergy transfer

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Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr3Gd（BO3）3∶Dy3+/RE3+（RE=Tb, Eu） Crystals

DOI：10.37188/CJL.20220094

摘要

Abstract

关键词

Keywords

references

Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr₃Gd（BO₃）₃∶Dy³⁺/RE³⁺（RE=Tb, Eu） Crystals