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1.中国科学院西安光学精密机械研究所 瞬态光学与光子技术国家重点实验室, 陕西 西安 710119
2.中国科学院大学, 北京 100049
E-mail: guoht_001@opt.ac.cn
Published:05 June 2022,
Received:15 March 2022,
Revised:27 March 2022,
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许晨煜,崔健,许彦涛等.用于中红外光纤激光器的高Pr3+掺杂硒化物硫系玻璃和光纤制备及其光谱特性[J].发光学报,2022,43(06):851-8611.
XU Chen-yu,CUI Jian,XU Yan-tao,et al.Fabrication and Spectroscopic Properties of Heavily Pr3+ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser[J].Chinese Journal of Luminescence,2022,43(06):851-861.
许晨煜,崔健,许彦涛等.用于中红外光纤激光器的高Pr3+掺杂硒化物硫系玻璃和光纤制备及其光谱特性[J].发光学报,2022,43(06):851-8611. DOI: 10.37188/CJL.20220088.
XU Chen-yu,CUI Jian,XU Yan-tao,et al.Fabrication and Spectroscopic Properties of Heavily Pr3+ Doped Selenide Chalcogenide Glass and Fiber for Mid-infrared Fiber Laser[J].Chinese Journal of Luminescence,2022,43(06):851-861. DOI: 10.37188/CJL.20220088.
为了研发用于3~5 μm波段光纤激光器的增益介质,制备了重量百分比为0~0.4%不同浓度Pr
3+
离子掺杂的Ge
12
As
20.8
Ga
4
Se
63.2
硒化物硫系玻璃。通过多级棒管法,重量百分比为0.2%的Pr
3+
离子掺杂玻璃被成功拉制成阶跃型双包层光纤,损耗最低为2.95 dB/m(位于6.58 μm处)。采用电子探针显微分析(EPMA)、X射线衍射(XRD)、差示扫描量热(DSC)、场发射透射电子显微镜(FE⁃TEM)、透射光谱和中红外荧光光谱分析了玻璃中Pr
3+
离子的分散性、杂质含量以及Pr
3+
离子引入引起的热、光学性质变化。通过玻璃的吸收和发射光谱并结合Judd-Ofelt理论,计算了Judd-Ofelt强度参数、辐射跃迁几率、荧光寿命、荧光分支比和受激发射截面。这种硒化硫系玻璃具有较高的Pr
3+
离子溶解度和中红外发光特性、良好的热稳定性和成纤性能,表明其具有作为中红外激光工作介质的潜力。
In order to develop a high gain medium for fiber lasers operating at 3-5 μm waveband, 0-0.4%(in weight) Pr
3+
ions doped Ge
12
As
20.8
Ga
4
Se
63.2
selenide chalcogenide glasses were prepared and the 0.2%(in weight) Pr
3+
ions doped one was successfully drawn into step-index double-cladding fiber with the lowest loss of 2.95 dB/m@6.58 μm by a multistage rod-in-tube method. The electron-probe measure microanalysis(EPMA), X-ray diffraction(XRD), differential scanning calorimeter(DSC), field emission transmission electron microscope(FE-TEM), transmission and mid-infrared fluorescence spectra were carried out to analyze the dispersion of Pr
3+
ions in glass, the impurity contents,thermal and optical changes caused by the Pr
3+
ions’ introduction. By analyzing the absorption and emission measurements of the serial glasses with the Judd-Ofelt theory, the Judd-Ofelt strength parameters, transition probabilities, exited state lifetime, branching ratios, and emission cross-sections were also calculated. This selenide chalcogenide glass has high Pr
3+
ions’ solubility and emission characteristic, good thermal stability and fiber forming performance, indicating that it has potential to be used as mid-infrared laser working medium.
硫系玻璃稀土离子光谱学中红外荧光红外光纤
chalcogenide glassrare-earth ionsspectroscopymid-infrared fluorescenceinfrared fiber
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