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Available Manganese-containing Chemicals and Synthesis Methods for Mn4+-activated Phosphors
增强出版- Chinese Journal of Luminescence Vol. 43, Issue 5, Pages: 662-675(2022)
- 作者机构：
1.郑州大学材料科学与工程学院 郑州市先进能源催化功能材料制备技术重点实验室，河南 郑州 450001
2.中国地质科学院 郑州矿产综合利用研究所，河南 郑州 450006
3.东北大学秦皇岛分校 河北省电介质与电解质功能材料重点实验室，河北 秦皇岛 066004
- 作者简介：
- 基金信息：National Natural Science Foundation of China(51902291);China Postdoctoral Science Foundation(2019M662524);Postdoctoral Research Sponsorship in Henan Province(19030025);Key R & D and promotion projects in Henan Province(212102210180);Hebei Key Laboratory of Dielectric and Electrolyte Functional Material, Northeastern University at Qinhuangdao(HKDEFM2021301);Young Talents Lifting Project from Henan Association for Science and Technology(2022HYTP016)
DOI：10.37188/CJL.20210412
CLC： O482.31;TP394.1;TP691.9Published：2022-05，
Received：27 December 2021，
Revised：12 January 2022，
扫 描 看 全 文
Zhao-wu WANG, Qiao QU, Hai-peng JI, et al. Available Manganese-containing Chemicals and Synthesis Methods for Mn4+-activated Phosphors. [J]. Chinese Journal of Luminescence 43(5):662-675(2022)
Zhao-wu WANG, Qiao QU, Hai-peng JI, et al. Available Manganese-containing Chemicals and Synthesis Methods for Mn4+-activated Phosphors. [J]. Chinese Journal of Luminescence 43(5):662-675(2022) DOI： 10.37188/CJL.20210412.
摘要
Mn
4+
激活荧光粉可在蓝光激发下发射波长可调的红光，是当前白光发光二极管用荧光粉的研究热点之一。在制备Mn
4+
激活红光荧光粉时，有多种锰源可供选择，如K
2
MnF
6
、KMnO
4
、Mn（HPO
4
）
2
、MnCO
3
、MnO
2
、MnO、Mn（NO
3
）
2
、Mn（CH
3
COO）
2
等。本文综述了文献中在制备Mn
4+
激活氟化物、氟氧化物和氧化物基质红光荧光粉时采用的锰源，列举了相应的制备方法，并总结了采取不同锰源和制备方法对所合成荧光粉的荧光性质（如量子效率）等方面的影响。最后就如何控制Mn
4+
激活荧光粉中锰离子价态等进行了展望。
Abstract
The Mn
4+
activated phosphors can emit wavelength-tunable red luminescence under blue light excitation
which is one of the hotspots in the field of red phosphor for white light-emitting diodes. There are several manganese-containing chemicals that were used as manganese source
including K
2
MnF
6
KMnO
4
Mn(HPO
4
)
2
MnCO
3
MnO
2
MnO
Mn(NO
3
)
2
and Mn(CH
3
COO)
2
. This mini-review summarized the types of these chemicals that have been chosen in literatures as the manganese source for the synthesis of Mn
4+
-doped fluoride
oxyfluoride
and oxide phosphors
via
different synthesis methods. The influences of choosing different manganese sources and synthesis methods on the photoluminescence properties(for example
the quantum efficiency) of the as-prepared phosphors were summarized. Finally
the methods for controlling the valence state of manganese ions in the as-synthesized phosphors were prospected.
关键词
荧光粉锰离子锰源
Keywords
phosphormanganese ionmanganese-containing chemical
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