Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe<sup>3+</sup> by An Enhancement Pattern

Zhu-ye SHANG; Li SHU; Yue WANG; Qing-tao MENG; Hong-min JIA; Zhi-qiang ZHANG

doi:10.37188/CJL.20210386

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Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe³⁺ by An Enhancement Pattern

Luminescence Applications and Interdisciplinary Fields | 更新时间：2022-04-07

- Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe³⁺ by An Enhancement Pattern
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 3, Pages: 453-461(2022)
- 作者机构：
  
  辽宁科技大学　化学工程学院，辽宁　鞍山　114051
- 作者简介：
- 基金信息：
  
  Liaoning “BaiQianWan Talents Program”;Scientific Research Fund General Project of Liaoning Province Department of Education(LJKZ0277);Technological Project of Liaoning Provincial Department of Education(2019LNQN03;2019LNJC18)
- DOI：10.37188/CJL.20210386
  CLC： O482.31
- Received：08 December 2021，
  
  Revised：23 December 2021，
  
  Published：2022-03
- 稿件说明：
移动端阅览
Zhu-ye SHANG, Li SHU, Yue WANG, et al. Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe³⁺ by An Enhancement Pattern[J]. Chinese journal of luminescence, 2022, 43(3): 453-461.
DOI：

Zhu-ye SHANG, Li SHU, Yue WANG, et al. Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe³⁺ by An Enhancement Pattern[J]. Chinese journal of luminescence, 2022, 43(3): 453-461. DOI： 10.37188/CJL.20210386.

摘要

在人的许多生理过程中扮演着重要的角色，例如氧气运输、DNA合成、髓磷脂合成、线粒体呼吸、神经递质合成和代谢等。然而，过量的Fe

会诱导细胞产生·OH从而引起细胞损伤，并且还会诱导β-地中海贫血、帕金森病、癫痫和阿尔茨海默病等疾病的发生。因此，对Fe

的检测和监测具有非常重要的意义。本文设计并合成了一种以三苯胺为母体的增强型Fe

荧光探针

，并将其应用于实际水样中Fe

的识别。结果表明，探针

对Fe

的识别具有较高的灵敏度，其检测限低至0.165 μmol·L

-1

。同时，Fe

的加入会导致探针溶液的荧光颜色由蓝绿色变为黄色，能够达到“裸眼”识别的效果。通过高分辨率质谱证明了探针与Fe

为1∶1配位。利用密度泛函理论计算了识别Fe

前后轨道能级和电能的变化并解释了其荧光光谱现象。

Abstract

plays an important role in many physiological processes

such as oxygen transport

DNA synthesis

myelin synthesis

mitochondrial respiration

neurotransmitter synthesis and metabolism. However

excessive Fe

can induce cells to produce a large amount of ·OH and result in cell damage

which can also cause a variety of diseases

such as β-thalassemia

Parkinson‘s disease

epilepsy and Alzheimer‘s disease. Therefore

it is of great significance to detect and monitor Fe

. In this paper

a fluorescence enhanced Fe

probe

based on triphenylamine is designed and synthesized

and it is also applied to the recognition of Fe

in real water samples. The results show that the probe

has a high sensitivity for Fe

recognition

and the detection limit is as low as 0.165 μmol·L

-1

. At the same time

upon the addition of Fe

an obvious change in the colour of the

solution from turquoise to yellow is observed

allowing for colorimetric detection of Fe

by the "naked eye" . The 1∶1 coordination mode between

and Fe

is further proved by high resolution mass spectrometry. Density functional theory(DFT) is used to calculate the changes of energy level and energy of the orbital before and after coordination with Fe

and explain the phenomenon of its fluorescence spectrum.

关键词

Keywords

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Related Author

Zhi-qiang ZHANG

Zhu-ye SHANG

Li SHU

Yue WANG

Qing-tao MENG

Hong-min JIA

WU Hong-mei

GUO Yu

Related Institution

School of Chemical Engineering， University of Science and Technology Liaoning

School of Chemical and Environmental Engineering, Liaoning University of Technology

College of Mechanical Engineering and Automation, Liaoning University of Technology

Chemistry College, Dalian University of Technology

State Key Laboratory of Fine Chemicals, Dalian University of Technology

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⁰

Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe3+ by An Enhancement Pattern

DOI：10.37188/CJL.20210386

摘要

Abstract

关键词

Keywords

references

Synthesis and Performances of Triphenylamine Based Turn-on Fluorescent Probe for Fe³⁺ by An Enhancement Pattern