Local Electronic Structure of Lithium Nitrogen Codoped ZnO Films Revealed by X-ray Absorption Fine Structure Spectroscopy

He SHEN; Yan-yan WANG; Ming GAO; Dong-fei LI

doi:10.37188/CJL.20210365

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Local Electronic Structure of Lithium Nitrogen Codoped ZnO Films Revealed by X-ray Absorption Fine Structure Spectroscopy

Synthesis and Properties of Materials | 更新时间：2022-02-25

- Local Electronic Structure of Lithium Nitrogen Codoped ZnO Films Revealed by X-ray Absorption Fine Structure Spectroscopy
  增强出版
- 发光学报 Vol. 43, Issue 2, Pages: 218-225(2022)
- 作者机构：
  
  1.吉林师范大学功能材料物理与化学教育部重点实验室, 吉林长春 130103
  2.吉林师范大学物理学院, 吉林四平 136000
  3.吉林师范大学环境友好材料制备与应用教育部重点实验室, 吉林长春 130103
  4.吉林师范大学化学学院, 吉林四平 136000
- 作者简介：
  
  [ "申赫(1986-)，男，辽宁铁岭人，博士，实验师，2014年于中国科学院长春光学精密机械与物理研究所获得博士学位，主要从事半导体光电材料与器件的研究。E-mail: shenhe861206@163.com" ]
  [ "王岩岩(1985-)，女，吉林长春人，博士，高级实验师，2014年于中国科学院长春光学精密机械与物理研究所获得博士学位，主要从事纳米光学材料的研究。E-mail: wangyanyan.24@163.com" ]
- 基金信息：
  
  国家自然科学基金(61704065;61705078;11904130)
- DOI：10.37188/CJL.20210365
  CLC： O484.4
- Published：2022-02，
  
  Received：17 November 2021，
  
  Revised：07 December 2021，
- 稿件说明：
移动端阅览
HE SHEN, YAN-YAN WANG, MING GAO, et al. Local Electronic Structure of Lithium Nitrogen Codoped ZnO Films Revealed by X-ray Absorption Fine Structure Spectroscopy. [J]. 发光学报, 2022, 43(2): 218-225.
DOI：

HE SHEN, YAN-YAN WANG, MING GAO, et al. Local Electronic Structure of Lithium Nitrogen Codoped ZnO Films Revealed by X-ray Absorption Fine Structure Spectroscopy. [J]. 发光学报, 2022, 43(2): 218-225. DOI： 10.37188/CJL.20210365.

摘要

为了实现对Li—N共掺杂p型ZnO薄膜的形成机制以及其稳定p型导电原因的揭示，利用X射线光电子谱及基于同步辐射光源的X射线吸收精细结构谱测试对薄膜的局域电子结构进行了测算分析. 获得了Li—N成键及Li—N复合型受主形成的信号，利用光致发光测量计算其受主能级为122 mV. 证实了薄膜中Li—N复合型受主的形成，而Li—N共掺杂p型ZnO良好的稳定性则归因于Li—N共掺杂在p型ZnO薄膜中实现了Li和N的成键.

Abstract

It is to reveal the formation mechanism of Li and N codoped p-ZnO films and the cause for the stable p-type conductivity. The films has been studied by investigating their local electronic structures using X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy based on synchrotron radiation source. The signals of Li—N bond and Li—N complex acceptors in the p-ZnO films have been collected

and the acceptor level estimated from photoluminescence spectroscopy is about 122 meV. The formation of Li—N complex acceptors has been confirmed

and the realization of Li—N bond has been attributed to the origin of the good stability of the p-type ZnO films obtained by Li

N codoping method.

关键词

氧化锌p型掺杂形成机制稳定性X射线吸收精细结构谱

Keywords

zinc oxidep-type dopingformation mechanismstabilityX-ray absorption fine structure spectroscopy

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He SHEN

Yan-yan WANG

Ming GAO

Dong-fei LI

Related Institution

Key Laboratory of Functional Materials Physics and Chemistry， Chinese Ministry of Education， Jilin Normal University

College of Physics， Jilin Normal University

Key Laboratory of Preparation and Application of Environmentally Friendly Materials， Chinese Ministry of Education， Jilin Normal University

College of Chemistry， Jilin Normal University

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