Upconversion Luminescence and Temperature Sensing Characteristics of Lu2O3∶Er3+/Yb3+ Phosphor

Hui-li ZHOU; Feng WU; Zhi-hong ZHANG; Yan ZHANG; Lin-hua YE

doi:10.37188/CJL.20210363

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Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor

Synthesis and Properties of Materials | 更新时间：2022-02-25

- Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 2, Pages: 192-200(2022)
- 作者机构：
  
  1.浙江大学　物理系，浙江　杭州　310027
  2.中国航发四川燃气涡轮研究院，四川　成都　610500
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11674284);Advanced Jet Propulsion Innovation Center,AEAC(HKCX2019-01-017)
- DOI：10.37188/CJL.20210363
  CLC：
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Hui-li ZHOU, Feng WU, Zhi-hong ZHANG, et al. Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor. [J]. Chinese Journal of Luminescence 43(2):192-200(2022)
DOI：

Hui-li ZHOU, Feng WU, Zhi-hong ZHANG, et al. Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor. [J]. Chinese Journal of Luminescence 43(2):192-200(2022) DOI： 10.37188/CJL.20210363.

摘要

采用CO,2,激光区熔法制备了Lu,2,O,3,∶0.5%Er,3+,/,x,%Yb,3+,(,x,=1,3,5)上转换荧光材料。X射线衍射结果表明，所制备的Lu,2,O,3,∶Er,3+,/Yb,3+,荧光材料具有纯Lu,2,O,3,晶相。在980 nm激光激发下，样品发出明亮的上转换荧光。光谱测试结果表明，样品上转换荧光强度和荧光中绿光与红光比例随Yb,3+,离子浓度改变，当Er,3+,和Yb,3+,离子浓度分别为0.5%和3%时，样品上转换荧光强度最强。通过荧光强度比(FIR)技术研究了样品Lu,2,O,3,∶0.5%Er,3+,/3%Yb,3+,在298~873 K温度范围内上转换荧光温度传感特性，在532.8 K时最大绝对灵敏度为0.006 0 K,-1,，在298 K时最大相对灵敏度为0.009 0 K,-1,。结果表明，Lu,2,O,3,∶Er,3+,/Yb,3+,荧光材料非常适合用于宽温度范围荧光温度传感。

Abstract

Lu,2,O,3,∶0.5%Er,3+,/,x,%Yb,3+,(,x,=1, 3, 5) phosphors were prepared by CO,2, laser zone melting method. X-ray diffraction results showed that all the prepared Lu,2,O,3,∶Er,3+,/Yb,3+, phosphors have a pure Lu,2,O,3, crystal phase. Under the excitation of a 980 nm laser diode, the samples emit bright up-conversion luminescence(UCL). The luminescence intensity and the ratio of green band to red band in luminescence spectra change with Yb,3+, concentration. Besides, the UCL intensity reaches its maximum value when the doping concentrations of Er,3+, and Yb,3+, ions are 0.5% and 3%, respectively. The temperature sensing characteristics of Lu,2,O,3,∶0.5%Er,3+,/3%Yb,3+, were investigated using fluorescence intensity ratio(FIR) technique from 298 K to 873 K. The maximum absolute sensitivity is 0.006 0 K,-1, at 532.8 K, and the maximum relative sensitivity is 0.009 0 K,-1, at 298 K. The above results indicate that the Lu,2,O,3,∶Er,3+,/Yb,3+, phosphor is very suitable for wide-range temperature sensing.

关键词

Lu2O3∶Er3+/Yb3+；上转换发光荧光强度比(FIR)荧光温度传感CO2激光区熔法

Keywords

Lu2O3∶Er3+/Yb3+upconversion luminescencefluorescence intensity ratio(FIR)fluorescence temperature sensingCO2 laser zone melting method

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