Upconversion Luminescence and Temperature Sensing Characteristics of Lu2O3∶Er3+/Yb3+ Phosphor

Hui-li ZHOU; Feng WU; Zhi-hong ZHANG; Yan ZHANG; Lin-hua YE

doi:10.37188/CJL.20210363

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Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor

Synthesis and Properties of Materials | 更新时间：2022-02-25

- Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 2, Pages: 192-200(2022)
- 作者机构：
  
  1.浙江大学　物理系，浙江　杭州　310027
  2.中国航发四川燃气涡轮研究院，四川　成都　610500
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11674284);Advanced Jet Propulsion Innovation Center,AEAC(HKCX2019-01-017)
- DOI：10.37188/CJL.20210363
  CLC： O482.31
- Published：2022-02，
  
  Received：16 November 2021，
  
  Revised：30 November 2021，
- 稿件说明：
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HUI-LI ZHOU, FENG WU, ZHI-HONG ZHANG, et al. Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor. [J]. Chinese journal of luminescence, 2022, 43(2): 192-200.
DOI：

HUI-LI ZHOU, FENG WU, ZHI-HONG ZHANG, et al. Upconversion Luminescence and Temperature Sensing Characteristics of Lu₂O₃∶Er³⁺/Yb³⁺ Phosphor. [J]. Chinese journal of luminescence, 2022, 43(2): 192-200. DOI： 10.37188/CJL.20210363.

摘要

采用CO

激光区熔法制备了Lu

∶0.5%Er

%Yb

(

5)上转换荧光材料。X射线衍射结果表明，所制备的Lu

∶Er

/Yb

荧光材料具有纯Lu

晶相。在980 nm激光激发下，样品发出明亮的上转换荧光。光谱测试结果表明，样品上转换荧光强度和荧光中绿光与红光比例随Yb

离子浓度改变，当Er

和Yb

离子浓度分别为0.5%和3%时，样品上转换荧光强度最强。通过荧光强度比(FIR)技术研究了样品Lu

∶0.5%Er

/3%Yb

在298~873 K温度范围内上转换荧光温度传感特性，在532.8 K时最大绝对灵敏度为0.006 0 K

-1

，在298 K时最大相对灵敏度为0.009 0 K

-1

。结果表明，Lu

∶Er

/Yb

荧光材料非常适合用于宽温度范围荧光温度传感。

Abstract

∶0.5%Er

%Yb

(

5) phosphors were prepared by CO

laser zone melting method. X-ray diffraction results showed that all the prepared Lu

∶Er

/Yb

phosphors have a pure Lu

crystal phase. Under the excitation of a 980 nm laser diode

the samples emit bright up-conversion luminescence(UCL). The luminescence intensity and the ratio of green band to red band in luminescence spectra change with Yb

concentration. Besides

the UCL intensity reaches its maximum value when the doping concentrations of Er

and Yb

ions are 0.5% and 3%

respectively. The temperature sensing characteristics of Lu

∶0.5%Er

/3%Yb

were investigated using fluorescence intensity ratio(FIR) technique from 298 K to 873 K. The maximum absolute sensitivity is 0.006 0 K

-1

at 532.8 K

and the maximum relative sensitivity is 0.009 0 K

-1

at 298 K. The above results indicate that the Lu

∶Er

/Yb

phosphor is very suitable for wide-range temperature sensing.

关键词

Lu2O3∶Er3+/Yb3+；上转换发光荧光强度比(FIR)荧光温度传感CO2激光区熔法

Keywords

Lu2O3∶Er3+/Yb3+upconversion luminescencefluorescence intensity ratio(FIR)fluorescence temperature sensingCO2 laser zone melting method

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