Elaboration and Mid-infrared Emission of KYb3F10∶Er3+ Nanocrystals Embedded in Glass Ceramics

Peng ZHAO; Chong-yang YE; Man YU; Chao LIU; Xue-yun LIU; Hai GUO

doi:10.37188/CJL.20210349

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Elaboration and Mid-infrared Emission of KYb₃F₁₀∶Er³⁺ Nanocrystals Embedded in Glass Ceramics

Synthesis and Properties of Materials | 更新时间：2022-02-25

- Elaboration and Mid-infrared Emission of KYb₃F₁₀∶Er³⁺ Nanocrystals Embedded in Glass Ceramics
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 2, Pages: 174-181(2022)
- 作者机构：
  
  1.宁波大学　高等技术研究院，浙江　宁波　315211
  2.宁波海洋研究院，浙江　宁波　315832
  3.浙江师范大学　物理系，浙江　金华　321004
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(51702172);Natural Science Foundation of Zhejiang Province(LY20A040002)
- DOI：10.37188/CJL.20210349
  CLC： O482.31
- Published：2022-02，
  
  Received：05 November 2021，
  
  Revised：17 November 2021，
- 稿件说明：
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PENG ZHAO, CHONG-YANG YE, MAN YU, et al. Elaboration and Mid-infrared Emission of KYb₃F₁₀∶Er³⁺ Nanocrystals Embedded in Glass Ceramics. [J]. Chinese journal of luminescence, 2022, 43(2): 174-181.
DOI：

PENG ZHAO, CHONG-YANG YE, MAN YU, et al. Elaboration and Mid-infrared Emission of KYb₃F₁₀∶Er³⁺ Nanocrystals Embedded in Glass Ceramics. [J]. Chinese journal of luminescence, 2022, 43(2): 174-181. DOI： 10.37188/CJL.20210349.

摘要

由于在军事和民生领域重要的应用潜力，~3 μm激光光源的开发一直以来受到了极大关注。传统中红外激光玻璃因其较高的声子能量会极大削弱发光离子的辐射跃迁几率，导致无法获得有效激光输出。因此，寻找高效且稳定的中红外~3 μm激光增益材料具有重要价值和研究意义。本文报道了在氟硅酸盐玻璃中SiO

-ZnF

-KF-YbF

-ErF

原位析出KYb

∶Er

纳米晶，获得的微晶玻璃样品可保持80%以上的透过率。利用X射线衍射仪(XRD)和透射电子显微镜(TEM)表征了玻璃中纳米晶体种类和元素分布。在980 nm激光二极管(LD)激发下，热处理后的样品中Er

位于2.7 μm处的发射带强度获得极大增强(相比于未经热处理的样品增强了约19倍)，进一步结合吸收光谱和稳态光谱结果对其发光增强机理进行了解释。研究结果可为开发~3 μm激光增益材料提供相关数据和研究思路。

Abstract

Mid-infrared lasers operating at around 3 μm have been paid much attention due to their significant potential at civil and military field. Traditional mid-infrared laser glass matrix presents high phonon energy

which causes the radiative transition probability of luminescent ions being greatly weakened

and thus leads to the inability to obtain effective laser output. Therefore

it is of great value to explore efficient and stable gain materials for 3 μm laser. In this paper

we report the

in-situ

precipitation of KYb

∶Er

nanocrystals from SiO

-ZnF

-KF-YbF

-ErF

fluorosilicate glass matrix. The obtained glass ceramic can maintain more than 80% transmittance. The nanocrystal species and elemental distribution in the glass were characterized by X-ray diffractometry(XRD) and transmission electron microscopy(TEM) technology. Under 980 nm laser diode(LD) excitation

the mid-infrared emission at 2.7 μm of Er

for the heat-treated sample is greatly enhanced

which is about 19 times stronger than that of the precursor sample. The related mechanism for the luminescence enhancement is further explained by the results of absorption spectra and steady state fluorescence spectra. The present results may provide reference data and research ideas for the development of ~3 μm laser gain materials.

关键词

微晶玻璃氟化物纳米晶铒离子中红外荧光

Keywords

glass ceramicsfluoride nanocrystalsEr3+ ionsmid-infrared emission

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Related Author

Peng ZHAO

Chongyang YE

Man YU

Chao LIU

Xueyun LIU

Hai GUO

HUANG Lihui

LI Bo

Related Institution

Department of Physics， Zhejiang Normal University

The Research Institute of Advanced Technology， Ningbo University

Key Laboratory of Rare Earth Optoelectronic Materials and Deices of Zhejiang Province， Institute of Optoelectronic Materials and Devices， College of Optical and Electronic Technology， China Jiliang University

School of Physics and Electronic Engineering， Taishan University， Taishan

College of Physics and Optoelectronic Engineering， Harbin Engineering University

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