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Down-conversion Luminescence Performance of Dy3+ Doped Lu2O3 and Y2O3 Single Crystal Fibers for Temperature Sensing
增强出版- Chinese Journal of Luminescence Vol. 43, Issue 2, Pages: 182-191(2022)
- 作者机构：
. 山东大学 晶体材料国家重点实验室，山东 济南 250100
- 作者简介：
- 基金信息：National Natural Science Foundation of China(62105181);Postdoctoral Applied Research in Qingdao
DOI：10.37188/CJL.20210345
CLC： O482.31Published：2022-02，
Received：04 November 2021，
Revised：22 November 2021，
- 稿件说明：
移动端阅览
NA ZHANG, YANG LI, YAN-RU YIN, et al. Down-conversion Luminescence Performance of Dy3+ Doped Lu2O3 and Y2O3 Single Crystal Fibers for Temperature Sensing. [J]. Chinese journal of luminescence, 2022, 43(2): 182-191.
NA ZHANG, YANG LI, YAN-RU YIN, et al. Down-conversion Luminescence Performance of Dy3+ Doped Lu2O3 and Y2O3 Single Crystal Fibers for Temperature Sensing. [J]. Chinese journal of luminescence, 2022, 43(2): 182-191. DOI： 10.37188/CJL.20210345.
摘要
稀土倍半氧化物单晶光纤材料凭借超高的熔点(~2 400 ℃)、稳定的物化性能以及灵活的结构被认为是极具潜力的高温传感介质。本文采用激光加热基座(LHPG)法，成功生长了透明无开裂Dy
3+
离子掺杂的倍半氧化物单晶光纤Lu
2
O
3
和Y
2
O
3
。依据Dy
3+
离子的
4
I
15/2
和
4
F
9/2
能级为一对热耦合能级对(TCLs)，测试得到了430~520 nm波长范围内的下转换荧光光谱。荧光强度比(FIR)结果显示，晶体在298~673 K温度范围内的荧光强度具有良好的温度相关性。其中Dy∶Lu
2
O
3
在该范围内的最大相对灵敏度和绝对灵敏度分别为0.97%·K
-1
(315 K)和1.62×10
-4
K
-1
(673 K)，展现出更为优异的温度传感性能。
Abstract
Rare earth sesquioxide single crystal fibers(SCFs) are considered to be potential high-temperature sensing media due to their ultra-high melting point(~2 400 ℃)
stable physical and chemical properties and flexible structure. The transparent and crack-free Dy
3+
doped Lu
2
O
3
and Y
2
O
3
single crystal fibers(SCFs) were successfully grown by laser heated pedestal growth(LHPG) method. According to the
4
I
15/2
and
4
F
9/2
energy levels of Dy
3+
ion as a pair of thermally coupled energy levels(TCLs)
the down-conversion luminescence in the wavelength range of 430-520 nm was obtained. The fluorescence intensity ratio(FIR) measurement technique shows that the Dy
3+
doped Lu
2
O
3
and Y
2
O
3
crystals have a good temperature dependence in the temperature range of 298-673 K. The maximum relative sensitivity and absolute sensitivity of Dy∶Lu
2
O
3
in this range are 0.97%·K
-1
(315 K) and 1.62×10
-4
K
-1
(673 K)
respectively
showing more excellent temperature sensing performance.
关键词
激光加热基座法倍半氧化物单晶光纤下转换荧光荧光强度比温度探测
Keywords
laser heated pedestal growth(LHPG) methodsesquioxide single crystal fibers(SCFs)down-conversion luminescencefluorescence intensity ratio(FIR)temperature sensing
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