Preparation of Copper/Silver Bimetallic Nanoclusters Stabilized by Penicillamine and Their Application in Silver Ion Detection

Jin-na BAI; Liang WANG; Ming-hui WANG; Ming CHEN; Quan LIN; Xu-dong YANG

doi:10.37188/CJL.20210341

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Preparation of Copper/Silver Bimetallic Nanoclusters Stabilized by Penicillamine and Their Application in Silver Ion Detection

Luminescence Applications and Interdisciplinary Fields | 更新时间：2022-02-25

- Preparation of Copper/Silver Bimetallic Nanoclusters Stabilized by Penicillamine and Their Application in Silver Ion Detection
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 2, Pages: 285-295(2022)
- 作者机构：
  
  1.长春工业大学　化学工程学院，　材料科学高等研究院，吉林　长春　130012
  2.吉林大学化学学院　超分子结构与材料国家重点实验室，吉林　长春　130012
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51603018);State key Laboratory of Supramolecular Structure and Materials of Jilin University(sklssm2021028)
- DOI：10.37188/CJL.20210341
  CLC： O614
- Published：2022-02，
  
  Received：02 November 2021，
  
  Revised：14 November 2021，
- 稿件说明：
移动端阅览
JIN-NA BAI, LIANG WANG, MING-HUI WANG, et al. Preparation of Copper/Silver Bimetallic Nanoclusters Stabilized by Penicillamine and Their Application in Silver Ion Detection. [J]. Chinese journal of luminescence, 2022, 43(2): 285-295.
DOI：

JIN-NA BAI, LIANG WANG, MING-HUI WANG, et al. Preparation of Copper/Silver Bimetallic Nanoclusters Stabilized by Penicillamine and Their Application in Silver Ion Detection. [J]. Chinese journal of luminescence, 2022, 43(2): 285-295. DOI： 10.37188/CJL.20210341.

摘要

以青霉胺(DPA)为还原剂和稳定剂，通过一锅法一步制备了青霉胺稳定的铜/银双金属纳米簇(DPA-Cu/Ag NCs)，并将其作为一种传感器用于检测水样中的银离子。该银离子传感器具有价格低廉、分析速度快速、选择性高等特点。采用透射电子显微镜(TEM)等方法表征了DPA-Cu/Ag NCs的结构及其化学组成，并通过荧光光谱和紫外-可见光谱法研究了DPA-Cu/Ag NCs的光学性质。结果表明，该DPA-Cu/Ag NCs在激发波长为300 nm时的最大发射波长为555 nm，其溶液在可见光照射下呈现乳白色，在紫外灯照射下则呈现出明亮的黄色荧光。在DPA-Cu/Ag NCs的制备条件达到最优化的情况下，可以将其作为探针，用来高选择性、高灵敏性地检测银离子。该探针检测银离子的检测限为0.3 μmol/L，线性范围为0~500 μmol/L。该DPA-Cu/Ag NCs探针还可应用于自然环境水样(湖水、瓶装矿泉水和实验室自来水)中银离子浓度的检测，其检测性能十分优异且具有良好的准确度和重现性，表明DPA-Cu/Ag NCs探针在环境检测方面有非常高的应用价值。

Abstract

Bimetallic copper-silver nanoclusters(DPA-Cu/Ag NCs) were prepared by one-pot method using penicillamine as reducing agent and stabilizer

and used as a sensor to detect silver ions in water samples. The Ag

sensor has the advantages of low price

quick analysis speed and high selectivity. The structure and chemical composition of bimetallic copper-silver nanoclusters were characterized by transmission electron microscopy(TEM). The results showed that the DPA-Cu/Ag NCs exhibited a maximum emission at 555 nm with an excitation wavelength of 300 nm. It is a milky white solution under visible light

and the solution shows bright yellow fluorescence under UV light. When the preparation conditions of DPA-Cu/Ag NCs are optimized

it can be used as a probe to detect silver ions with high selectivity and sensitivity. The detection limit of silver ion is 0.3 μmol/L and the linear range is 0-500 μmol/L. The DPA-Cu/Ag NCs probe can also be applied to the detection of silver ion concentration in natural environmental water samples(lake water

bottled mineral water and laboratory tap water

etc

and its detection performance is excellent with good percent of accuracy and reproducibility

indicating that the DPA-Cu/Ag NCs probe has extremely high application value in environmental monitoring.

关键词

金属纳米簇荧光双金属银离子检测

Keywords

metal nanoclusterfluorescencebi-metalsilver ion detection

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Related Author

Jin-na BAI

Liang WANG

Ming-hui WANG

Ming CHEN

Xu-dong YANG

Quan LIN

YANG Rui

LI Ziyue

Related Institution

State Key Laboratory of Supramolecular Structure and Materials， College of Chemistry， Jilin University

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State Key Laboratory of Integrated Optoelectronics， College of Electronic Science and Engineering， Jilin University

Department of Physics & Astronomy， Georgia Southern University， Statesboro

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