Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials

Xue BAI; Zan XU; Ying-zhu ZI; Dai-wen XIAO; Li-xiang FU; Yan-ni HE; He-ping ZHAO; Zhao-shuo YANG; You-yan SONG; Asif Ali HAIDER; Fei-fei XIANG; Zhi-guo SONG; Yang-ke CUN; Jian-bei QIU; Zheng-wen YANG

doi:10.37188/CJL.20210326

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Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials

Cover Story | 更新时间：2022-04-20

- Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials
  封面论文增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 4, Pages: 463-477(2022)
- 作者机构：
  
  昆明理工大学　材料科学与工程学院，云南　昆明　650093
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51762029);Applied Basic Research Key Program of Yunnan Province(2018FA026);Key project of National Natural Science Foundation of China - Yunnan Joint Fund(U2102215)
- DOI：10.37188/CJL.20210326
  CLC： O482.31
- Published：01 April 2022，
  
  Received：14 October 2021，
  
  Revised：30 October 2021，
- 稿件说明：
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XUE BAI, ZAN XU, YING-ZHU ZI, et al. Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials. [J]. Chinese journal of luminescence, 2022, 43(4): 463-477.
DOI：

XUE BAI, ZAN XU, YING-ZHU ZI, et al. Reversible Fluorescence Modulation and Applications Based on Chromic Effect in Inorganic Rare-earth Luminescent Materials. [J]. Chinese journal of luminescence, 2022, 43(4): 463-477. DOI： 10.37188/CJL.20210326.

摘要

无机稀土发光材料在照明、显示、激光和生物医学等领域有着极其广泛的应用。对荧光性能的调控有利于拓展其在温度传感、防伪识别、光开关、光存储等领域的应用。传统的荧光调控方式包括设计核壳结构、改变材料成分控制晶体场、改变稀土离子的掺杂类型或浓度从而控制能量传递等。然而，这些调控方式难以实现荧光性能的可逆调控，限制了其实际应用。对比传统的调控方式，材料在电场、热场或光场等外场刺激下可产生变色效应，通过变色效应可以实现对其荧光性能的可逆调控从而扩展其应用。本文主要综述了在电场、热场和光场刺激下，无机稀土发光材料的变色效应对其荧光性能的可逆调控及应用。

Abstract

Inorganic rare-earth luminescent materials are widely used in lighting

display

laser and biomedicine. The fluorescence modulation is beneficial to expand the applications in temperature sensing

anti-counterfeiting

optical switch

optical storage

et al

. However

the traditional fluorescence modulation methods such as designing the core and shell structure

changing the material composition to control the crystal field

and changing the doping type or concentration of rare earth ions to control the energy transfer are difficult to achieve reversible modulation of fluorescence properties

limiting their practical applications. Compared with these traditional methods

the color of materials can change under external stimulation

such as electric field

thermal field and light field. The reversible fluorescence modulation based on the chromic effect could expand the applications. In this paper

the reversible modulation based on chromic effect under electric field

thermal field or light field stimulation in inorganic rare-earth luminescent materials and their applications were mainly reviewed.

关键词

无机稀土发光材料荧光调控电致变色热致变色光致变色

Keywords

inorganic rare-earth luminescent materialsfluorescence modulationelectrochromicthermochromicphotochromic

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Guangzhou Research and Development Center of Optics-Mechanics-Electricity Engineering, Guangdong Public Laboratory of Modern Control and Optics-M echanics-Electricity Technology, Guangzhou, 510635, China

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