Synthesis and Optical Properties of Barium Doped CsPbBr<sub>3</sub> Blue Luminescence Quantum Dots

Fan-ju ZENG; Yong-qian TAN; Wei HU; Xiao-sheng TANG; Tao JING; Hai-feng YIN

doi:10.37188/CJL.20210323

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Synthesis and Optical Properties of Barium Doped CsPbBr₃ Blue Luminescence Quantum Dots

Synthesis and Properties of Materials | 更新时间：2022-01-14

- Synthesis and Optical Properties of Barium Doped CsPbBr₃ Blue Luminescence Quantum Dots
  增强出版
- Chinese Journal of Luminescence Vol. 43, Issue 1, Pages: 69-76(2022)
- 作者机构：
  
  1.凯里学院　大数据工程学院，贵州　凯里　556011
  2.重庆大学　光电工程学院，重庆　400044
  3.重庆邮电大学　光电学院，重庆　400065
- 作者简介：
- 基金信息：
  
  Science and Technology Foundation of Guizhou Province(ZK [2021] 245);National Natural Science Foundation of China(61975023);Special doctoral project of Kaili University(BS202004;BS201301);Academic Cultivation and Innovation Exploration Project of Kaili University(黔科合平台人才[2019]01-4);Major Research Projects of Innovative Groups in Education Department of Guizhou Province(黔教合KY 字[2018]035)
- DOI：10.37188/CJL.20210323
  CLC： O482.31
- Published：2022-01，
  
  Received：12 October 2021，
  
  Revised：27 October 2021，
- 稿件说明：
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FAN-JU ZENG, YONG-QIAN TAN, WEI HU, et al. Synthesis and Optical Properties of Barium Doped CsPbBr₃ Blue Luminescence Quantum Dots. [J]. Chinese journal of luminescence, 2022, 43(1): 69-76.
DOI：

FAN-JU ZENG, YONG-QIAN TAN, WEI HU, et al. Synthesis and Optical Properties of Barium Doped CsPbBr₃ Blue Luminescence Quantum Dots. [J]. Chinese journal of luminescence, 2022, 43(1): 69-76. DOI： 10.37188/CJL.20210323.

摘要

近年来，全无机卤素钙钛矿CsPb

(

=Cl

I)因其荧光带宽窄、带隙可调、合成工艺简单以及荧光量子产率(Photoluminescence quantum yield

PLQY)高等优点而被应用于光电器件领域。但相比于PLQY接近于100%的红光与绿光CsPb

量子点，PLQY低于10%的蓝光量子点光学性能仍需要提高。本文通过调节前驱体BaBr

与PbBr

的量比，常温下合成了Ba

离子掺杂CsPbBr

量子点，并对合成量子点的晶体结构、形貌及其光学性能进行了研究。研究结果显示，随着Ba/Pb量比的增加，由于Ba

离子半径小于Pb

离子半径，导致合成量子点粒径由未掺杂的11.37 nm减小到Ba/Pb为1.0时的10.36 nm；此外，Ba

离子的引入拓展了带宽，吸收光谱和荧光光谱均发生蓝移，荧光光谱由未掺杂的510 nm的绿光蓝移至Ba/Pb量比为1.0 时的461 nm的蓝光。当前驱液中Ba/Pb量比为0.5时，在461 nm处具有最强的蓝光发射，PLQY为39%。研究证明适量引入BaBr

合成Ba/Pb混合金属钙钛矿量子点可有效提高其光学性能。

Abstract

In recent years

all-inorganic halide perovskite CsPb

(

=Cl

I) has attracted tremendous attention owning to its narrow emission full width at half maximum

tunable bandgap

low production cost

and high photoluminescence quantum yield (PLQY). However

the blue luminescence perovskite quantum dots(QDs) is still lag behind their red and green luminescence counterparts. Herein

the Ba

ion doped CsPbBr

QDs was obtained by adjusting the molar ratio of BaBr

and PbBr

in precursor solution. The crystal structure

morphology

and optical property of as-prepared QDs were studied. The results exhibited that the decrease of particle size and blue shift in absorption and photoluminescence spectra as the increase of the Ba/Pb molar ratio. It is mainly contributed that the ionic radius of Ba

is smaller than Pb

ion

and the bandgap of as-prepared quantum dots is enlarged by partially replacement Pb

ion with Ba

ion. The particle size is decreases from 11.37 nm(undoped) to 10.36 nm(Ba/Pb molar ratio of 1.0). The photoluminescence is blue shift from 510 nm(undoped) to 461 nm(Ba

ion doped). Most interesting

the Ba

doped CsPbBr

quantum dot with the Ba/Pb molar ratio of 0.5 demonstrated the super blue luminescence at 461 nm with PLQY of 39%. It is certified that the optical property could be effectively improved by introducing appropriate amount Ba

ion to partially replacement of Pb

ion.

关键词

Ba2+离子掺杂CsPbBr3蓝光量子点合成光学性能

Keywords

Ba2+ ion doped CsPbBr3blue luminescence quantum dotssynthesisoptical property

references

AKKERMAN Q A, D'INNOCENZO V, ACCORNERO S, et al. Tuning the optical properties of cesium lead halide perovskite nanocrystals by anion exchange reactions[J]. J. Am. Chem. Soc., 2015, 137(32): 10276-10281.

NEDELCU G, PROTESESCU L, YAKUNIN S, et al. Fast anion-exchange in highly luminescent nanocrystals of cesium lead halide perovskites(CsPbX3,X=Cl,Br,I)[J]. Nano Lett., 2015, 15(8): 5635-5640.

HUANG H, BODNARCHUK M I, KERSHAW S V, et al. Lead halide perovskite nanocrystals in the research spotlight: stability and defect tolerance[J]. ACS Energy Lett., 2017, 2(9): 2071-2083.

CHEN W W, HAO J Y, HU W, et al. Enhanced stability and tunable photoluminescence in perovskite CsPbX3/ZnS quantum dot heterostructure[J]. Small, 2017, 13(21): 1604085-1-8.

PROTESESCU L, YAKUNIN S, BODNARCHUK M I, et al. Nanocrystals of cesium lead halide perovskites (CsPbX3,X=Cl,Br,and I): novel optoelectronic materials showing bright emission with wide color gamut[J]. Nano Lett., 2015, 15(6): 3692-3696.

DING J, ZHAO Y Y, DUAN J L, et al. Alloy-controlled work function for enhanced charge extraction in all-inorganic CsPbBr3 perovskite solar cells[J]. ChemSusChem, 2018, 11(9): 1432-1437.

WANG J X, ZHANG Y Z, CHEN J, et al. Strong polarized photoluminescence CsPbBr3 nanowire composite films for UV spectral conversion polarization photodetector enhancement[J]. ACS Appl. Mater. Interfaces, 2021, 13(30): 36147-36156.

ZHANG Y, ZHU H O, ZHENG J L, et al. Performance enhancement of all-inorganic perovskite quantum dots(CsPbX3) by UV-NIR laser irradiation[J]. J. Phys. Chem. C, 2019, 123(7): 4502-4511.

SHARMA D K, HIRATA S, BIJU V, et al. Stark effect and environment-induced modulation of emission in single halide perovskite nanocrystals[J]. ACS Nano, 2019, 13(1): 624-632.

XIE Y J, YU Y, GONG J Y, et al. Encapsulated room-temperature synthesized CsPbX3 perovskite quantum dots with high stability and wide color gamut for display[J]. Opt. Mater. Express, 2018, 8(11): 3494-3505.

林继栋, 王志斌, 张瑞丹, 等. CsPbX3(X=Cl,Br,I)钙钛矿量子点玻璃制备及其应用研究进展[J]. 发光学报, 2021, 42(9): 1331-1344.

LIN J D, WANG Z B, ZHANG R D, et al. Research progresses in preparation and applications of CsPbX3 (X=Cl,Br,I) perovskite quantum dots-embedded glass[J]. Chin. J. Lumin., 2021, 42(9): 1331-1344. (in Chinese)

XU W D, HU Q, BAI S, et al. Rational molecular passivation for high-performance perovskite light-emitting diodes[J]. Nat. Photonics, 2019, 13(6): 418-424.

皮慧慧, 李国辉, 周博林, 等. 高效率钙钛矿量子点发光二极管研究进展[J]. 发光学报, 2021, 42(5): 650-667.

PI H H, LI G H, ZHOU B L, et al. Progress of high-efficiency perovskite quantum dot light-emitting diodes[J]. Chin. J. Lumin., 2021, 42(5): 650-667. (in Chinese)

王志斌, 朱晓东, 贾浩然, 等. 蓝光钙钛矿发光二极管:从材料制备到器件优化[J]. 发光学报, 2020, 41(8): 879-898.

WANG Z B, ZHU X D, JIA H R, et al. Blue perovskite light-emitting diodes: from material preparation to device optimization[J]. Chin. J. Lumin., 2020, 41(8): 879-898. (in Chinese)

ZHU X, GE L, WANG Y, et al. Recent advances in enhancing and enriching the optical properties of Cl-based CsPbX3 nanocrystals[J]. Adv. Opt. Mater., 2021, 9(16): 2100058-1-17.

KUMAWAT N K, LIU X K, KABRA D, et al. Blue perovskite light-emitting diodes: progress, challenges and future directions[J]. Nanoscale, 2019, 11(5): 2109-2120.

尹勇明, 孟鸿. 量子点、钙钛矿色转换全彩显示应用研究进展[J]. 发光学报, 2021, 42(4): 419-447.

YIN Y M, MENG H. Progress of quantum dots and perovskite as color conversion materials for full-color display[J]. Chin. J. Lumin., 2021, 42(4): 419-447. (in Chinese)

段聪聪, 程露, 殷垚, 等. 蓝光钙钛矿发光二极管:机遇与挑战[J]. 物理学报, 2019, 68(15): 158503-1-8.

DUAN C C, CHENG L, YIN Y, et al. Blue perovskite light-emitting diodes: opportunities and challenges[J]. Acta Phys. Sinica, 2019, 68(15): 158503-1-8. (in Chinese)

REN Z W, WANG K, SUN X W, et al. Strategies toward efficient blue perovskite light-emitting diodes[J]. Adv. Funct. Mater., 2021, 31(30): 2100516-1-22.

PRODANOV M F, VASHCHENKO V V, SRIVASTAVA A K. Progress toward blue-emitting(460-475 nm) nanomaterials in display applications[J]. Nanophotonics, 2021, 10(7): 1801-1836.

ZHANG X L, CAO W Y, WANG W G, et al. Efficient light-emitting diodes based on green perovskite nanocrystals with mixed-metal cations[J]. Nano Energy, 2016, 30: 511-516.

BI C H, WANG S X, LI Q, et al. Thermally stable copper(Ⅱ)-doped cesium lead halide perovskite quantum dots with strong blue emission[J]. J. Phys. Chem. Lett., 2019, 10(5): 943-952.

LI S, SHI Z F, ZHANG F, et al. Sodium doping-enhanced emission efficiency and stability of cspbbr3 nanocrystals for white light-emitting devices[J]. Chem. Mater., 2019, 31(11): 3917-3928.

LIU H W, WU Z N, SHAO J R, et al. CsPbxMn1-xCl3 perovskite quantum dots with high mn substitution ratio[J]. ACS Nano, 2017, 11(2): 2239-2247.

LIU M, ZHONG G H, YIN Y M, et al. Aluminum-doped cesium lead bromide perovskite nanocrystals with stable blue photoluminescence used for display backlight[J]. Adv. Sci., 2017, 4(11): 1700335-1-8.

PAN G C, BAI X, XU W, et al. Bright blue light emission of Ni2+ ion-doped CsPbClxBr3-x perovskite quantum dots enabling efficient light-emitting devices[J]. ACS Appl. Mater. Interfaces, 2020, 12(12): 14195-14202.

王坤华, 姚纪松, 杨俊楠, 等. 金属卤化物钙钛矿纳米晶高效发光二极管的制备与器件性能优化[J]. 高等学校化学学报, 2021, 42(5): 1464-1479.

WANG K H, YAO J S, YANG J N, et al. Synthesis and device optimization of highly efficient metal halide perovskite light-emitting diodes[J]. Chem. J. Chin. Univ., 2021, 42(5): 1464-1479. (in Chinese)

TARASOVA N, GALISHEVA A, ANIMITSA I. Ba2+/Ti4+-co-doped layered perovskite BаLaInO4: the structure and ionic (O2-,H+) conductivity[J]. Int. J. Hydrogen Energy, 2021, 46(32): 16868-16877.

ZHANG H B, SHANG M H, ZHENG X Y, et al. Ba2+ doped CH3NH3PbI3 to tune the energy state and improve the performance of perovskite solar cells[J]. Electrochim. Acta, 2017, 254: 165-171.

LI X M, WU Y, ZHANG S L, et al. CsPbX3 quantum dots for lighting and displays: room-temperature synthesis, photoluminescence superiorities, underlying origins and white light-emitting diodes[J]. Adv. Funct. Mater., 2016, 26(15): 2435-2445.

HUANG H, SUSHA A S, KERSHAW S V, et al. Control of emission color of high quantum yield CH3NH3PbBr3 perovskite quantum dots by precipitation temperature[J]. Adv. Sci., 2015, 2(9): 1500194-1-5.

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Related Author

Fan-ju ZENG

Yong-qian TAN

HU-Wei

Xiao-sheng TANG

Tao JIN

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Related Institution

College of Optoelectronic Engineering， Chongqing University of Posts and Telecommunications

School of Big Data Engineering， Kaili University， Kaili

College of Optoelectronic Engineering， Chongqing University

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University

School of Chemistry and Chemical Engineering, Anhui University

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Synthesis and Optical Properties of Barium Doped CsPbBr3 Blue Luminescence Quantum Dots

DOI：10.37188/CJL.20210323

摘要

Abstract

关键词

Keywords

references

Synthesis and Optical Properties of Barium Doped CsPbBr₃ Blue Luminescence Quantum Dots