Influence of Zn Doped SnO<sub>2</sub> Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

Cui-ling YU; Rui-bin ZHU; Shan LIN; Feng WU; Da-kun WU; Hai-fa ZHAO; Liang CHANG

doi:10.37188/CJL.20210285

您当前的位置：

首页 >

文章列表页 >

Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

Device Fabrication and Physics | 更新时间：2021-12-17

- Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 12, Pages: 1936-1943(2021)
- 作者机构：
  
  1.哈尔滨工业大学　物理学院，黑龙江　哈尔滨　150001
  2.长春希达电子科技有限公司，吉林　长春　130103
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51502056);Fundamental Research Funds for the Central Universities(HIT. NSRIF. 2020100)
- DOI：10.37188/CJL.20210285
  CLC： O482.31;TM914
- Received：27 August 2021，
  
  Revised：2021-09-10，
  
  Published：2021-12
- 稿件说明：
移动端阅览
Cui-ling YU, Rui-bin ZHU, Shan LIN, et al. Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells[J]. Chinese Journal of Luminescence, 2021, 42(12): 1936-1943.
DOI：

Cui-ling YU, Rui-bin ZHU, Shan LIN, et al. Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells[J]. Chinese Journal of Luminescence, 2021, 42(12): 1936-1943. DOI： 10.37188/CJL.20210285.

摘要

利用水热法合成不同Zn掺杂含量的SnO

(SnO

∶Zn)纳米晶，并通过丝网印刷技术制备了SnO

∶Zn纳米晶光阳极，研究不同含量Zn掺杂SnO

纳米晶光阳极对染料敏化太阳能电池光电性能的影响。实验结果表明，Zn掺杂含量增加能够引起SnO

光阳极的平带电位负向偏移和等电点增加。与未掺杂SnO

染料敏化太阳能电池相比，当Zn掺杂量为2% 时，SnO

∶Zn基染料敏化太阳能电池的功率转换效率(PCE)最高，为4.2%，这归因于Zn掺杂能够增加染料在SnO

光阳极的担载量和提高染料敏化太阳能电池的光生电子寿命(

)。此外，2% Zn掺杂SnO

光阳极进一步经过TiCl

处理，其电池功率转换效率可提高到7.7%。

Abstract

Zn-doped SnO

nanocrystals under hydrothermal conditions were synthesized and subsequently the photoanodes were prepared

via

the screen printing technology for dye-sensitized solar cells. The effect of Zn-doped SnO

on the performance of dye-sensitized solar cells was investigated. It is found that Zn doping into SnO

can induce a negative shift in the flat-band potential and enhance the isoelectric point. As a result

the power conversion efficiency(PCE) of 4.2% was achieved for 2% Zn-doped SnO

based dye-sensitized solar cell compared with undoped SnO

based dye-sensitized solar cell. The enhancement in performance was ascribed to improve photogenerated electron lifetime(

) and dye-uptake capabilities. Moreover

after the TiCl

treatment of the photoanode

the 2% Zn-doped SnO

based dye-sensitized solar cell exhibited an impressive power conversion efficiency of 7.7%.

关键词

Keywords

references

O'REGAN B , GRÄTZEL M . A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films [J]. Nature , 1991 , 353 ( 6346 ): 737 - 740 .

CHUNG I , LEE B , HE J Q , et al . All-solid-state dye-sensitized solar cells with high efficiency [J]. Nature , 2012 , 485 ( 7399 ): 486 - 489 .

DEVADIGA D , SELVAKUMAR M , SHETTY P , et al . Recent progress in dye sensitized solar cell materials and photo-supercapacitors:a review [J]. J. Power Sources , 2021 , 493 : 229698 .

KOKKONEN M , TALEBI P , ZHOU J , et al . Advanced research trends in dye-sensitized solar cells [J]. J. Mater. Chem. A , 2021 , 9 ( 17 ): 10527 - 10545 .

YEOH M E , CHAN K Y . A review on semitransparent solar cells for real-life applications based on dye-sensitized technology [J]. IEEE J. Photovolt. , 2021 , 11 ( 2 ): 354 - 361 .

YU Q J , WANG Y H , YI Z H , et al . High-efficiency dye-sensitized solar cells:the influence of lithium ions on exciton dissociation,charge recombination,and surface states [J]. ACS Nano , 2010 , 4 ( 10 ): 6032 - 6038 .

REN Y M , SUN D Y , CAO Y M , et al . A stable blue photosensitizer for color palette of dye-sensitized solar cells reaching 12.6% efficiency [J]. J. Am. Chem. Soc. , 2018 , 140 ( 7 ): 2405 - 2408 .

ZENG K W , CHEN Y Y , ZHU W H , et al . Efficient solar cells based on concerted companion dyes containing two complementary components:an alternative approach for cosensitization [J]. J. Am. Chem. Soc. , 2020 , 142 ( 11 ): 5154 - 5161 .

JI J M , ZHOU H R , EOM Y K , et al . 14.2% Efficiency dye-sensitized solar cells by co-sensitizing novel thieno[3,2-b]indole-based organic dyes with a promising porphyrin sensitizer [J]. Adv. Energy Mater. , 2020 , 10 ( 15 ): 2000124-1-12 .

KUMAR V , GUPTA R , BANSAL A . Hydrothermal growth of ZnO nanorods for use in dye-sensitized solar cells [J]. ACS Appl. Nano Mater. , 2021 , 4 ( 6 ): 6212 - 6222 .

RINGLEB A , RUESS R , HOFEDITZ N , et al . Influence of Mg-doping on the characteristics of ZnO photoanodes in dye-sensitized solar cells [J]. Phys. Chem. Chem. Phys. , 2021 , 23 ( 14 ): 8393 - 8402 .

SOUZA A P S , OLIVEIRA F G S , NUNES V F , et al . High performance SnO2 pure photoelectrode in dye-sensitized solar cells achieved via electrophoretic technique [J]. Solar Energy , 2020 , 221 : 312 - 323 .

PHAM B , WILLINGER D , MCMILLAN N K , et al . Tin(Ⅳ) oxide nanoparticulate films for aqueous dye-sensitized solar cells [J]. Solar Energy , 2021 , 224 : 984 - 991 .

MOHITE N , SHINDE M , GUPTA A K , et al . Facile synthesis of hollow urchin-like Nb2O5 nanostructures and their performance in dye-sensitized solar cells [J]. J. Solid State Electrochem. , 2020 , 24 ( 2 ): 273 - 281 .

ARNOLD M S , AVOURIS P , PAN Z W , et al . Field-effect transistors based on single semiconducting oxide nanobelts [J]. J. Phys. Chem. B , 2003 , 107 ( 3 ): 659 - 663 .

SENEVIRATHNA M K I , PITIGALA P K D D P , PREMALAL E V A , et al . Stability of the SnO2/MgO dye-sensitized photoelectrochemical solar cell [J]. Solar Energy Mater. Solar Cells , 2007 , 91 ( 6 ): 544 - 547 .

GREEN A N M , PALOMARES E , HAQUE S A , et al . Charge transport versus recombination in dye-sensitized solar cells employing nanocrystalline TiO2 and SnO2 films [J]. J. Phys. Chem. B , 2005 , 109 ( 25 ): 12525 - 12533 .

KAY A , GRÄTZEL M . Dye-sensitized core-shell nanocrystals:improved efficiency of mesoporous tin oxide electrodes coated with a thin layer of an insulating oxide [J]. Chem. Mater. , 2002 , 14 ( 7 ): 2930 - 2935 .

WANG Y F , LI K N , LIANG C L , et al . Synthesis of hierarchical SnO2 octahedra with tailorable size and application in dye-sensitized solar cells with enhanced power conversion efficiency [J]. J. Mater. Chem. , 2012 , 22 ( 40 ): 21495 - 21501 .

RAMASAMY E , LEE J . Ordered mesoporous Zn-doped SnO2 synthesized by exotemplating for efficient dye-sensitized solar cells [J]. Energy Environ. Sci. , 2011 , 4 ( 7 ): 2529 - 2536 .

DOU X C , SABBA D , MATHEWS N , et al . Hydrothermal synthesis of high electron mobility Zn-doped SnO2 nanoflowers as photoanode material for efficient dye-sensitized solar cells [J]. Chem. Mater. , 2011 , 23 ( 17 ): 3938 - 3945 .

MAO W T , LI Z D , BAO K Y , et al . Nanowire-based zinc-doped tin oxide microtubes for enhanced solar energy utilization efficiency [J]. Ceram. Int. , 2017 , 43 ( 9 ): 6822 - 6830 .

DUAN J H , ZOU S B , YANG C M , et al . Full SnO2 double-layer dye-sensitized solar cells:slowly increasing phenomenon of power conversion efficiency [J]. Solar Energy , 2020 , 196 : 99 - 106 .

WANG P , ZAKEERUDDIN S M , COMTE P , et al . Enhance the performance of dye-sensitized solar cells by Co-grafting amphiphilic sensitizer and hexadecylmalonic acid on TiO2 nanocrystals [J]. J. Phys. Chem. B , 2003 , 107 ( 51 ): 14336 - 14341 .

ITO S , MURAKAMI T N , COMTE P , et al . Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% [J]. Thin Solid Films , 2008 , 516 ( 14 ): 4613 - 4619 .

BILGIN V , KOSE S , ATAY F , et al . The effect of Zn concentration on some physical properties of tin oxide films obtained by ultrasonic spray pyrolysis [J]. Mater. Lett. , 2004 , 58 ( 29 ): 3686 - 3693 .

LIU X F , IQBAL J , WU Z B , et al . Structure and room-temperature ferromagnetism of Zn-Doped SnO2 nanorods prepared by solvothermal method [J]. J. Phys. Chem. C , 2010 , 114 ( 11 ): 4790 - 4796 .

LI Z , ZHOU Y , YU T , et al . Unique Zn-doped SnO2 nano-echinus with excellent electron transport and light harvesting properties as photoanode materials for high performance dye-sensitized solar cell [J]. CrystEngComm , 2012 , 14 ( 20 ): 6462 - 6468 .

XIANG P , LI X , WANG H , et al . Mesoporous nitrogen-doped TiO2 sphere applied for quasi-solid-state dye-sensitized solar cell [J]. Nanoscale Res. Lett. , 2011 , 6 ( 1 ): 606-1-5 .

VAN DE KROL R , GOOSSENS A , SCHOONMAN J . Mott-Schottky analysis of nanometer-scale thin-film anatase TiO2 [J]. J. Electrochem. Soc. , 1997 , 144 ( 5 ): 1723 - 1727 .

FENG X J , SHANKAR K , PAULOSE M , et al . Tantalum-doped titanium dioxide nanowire arrays for dye-sensitized solar cells with high open-circuit voltage [J]. Angew. Chem. Int. Ed. , 2009 , 48 ( 43 ): 8095 - 8098 .

SNAITH H J , DUCATI C . SnO2-based dye-sensitized hybrid solar cells exhibiting near unity absorbed photon-to-electron conversion efficiency [J]. Nano Lett. , 2010 , 10 ( 4 ): 1259 - 1265 .

GRINIS L , KOTLYAR S , RÜHLE S , et al . Conformal nano-sized inorganic coatings on mesoporous TiO2 films for low-temperature dye-sensitized solar cell fabrication [J]. Adv. Funct. Mater. , 2010 , 20 ( 2 ): 282 - 228 .

BASU K , BENETTI D , ZHAO H G , et al . Enhanced photovoltaic properties in dye sensitized solar cells by surface treatment of SnO2 photoanodes [J]. Sci. Rep. , 2016 , 6 : 23312-1-10 .

Views

255

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Photodetectors Based on A 2D/3D Hybrid Tin Perovskite/SnO₂Heterojunction

Effect of Surface Decoration of CH₃NH₃PbBr₃ on Performance of SnO₂-based Photodetector

Sr-F Codoped SnO₂ Transparent Conductive Film

Effects of Experimental Conditions on The Morphology and Photocurrent Density of TiO₂ Nanorods

Related Author

Liang CHANG

Hai-fa ZHAO

Da-kun WU

Feng WU

Shan LIN

Rui-bin ZHU

Cui-ling YU

WANG Li-dan

Related Institution

School of Physics， Harbin Institute of Technology

Changchun Cedar Electronics Technology Co.， Ltd.

Fujian Key Laboratory for Advanced Micro-nano Photonics Technology and Devices， College of Physics and Information Engineering， Quanzhou Normal University

College of Chemical Engineering and Material， Quanzhou Normal University

Department of Physics, Harbin Institute of Technology

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Influence of Zn Doped SnO2 Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

DOI：10.37188/CJL.20210285

摘要

Abstract

关键词

Keywords

references

Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells