Influence of Zn Doped SnO<sub>2</sub> Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

Cui-ling YU; Rui-bin ZHU; Shan LIN; Feng WU; Da-kun WU; Hai-fa ZHAO; Liang CHANG

doi:10.37188/CJL.20210285

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Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

Device Fabrication and Physics | 更新时间：2021-12-17

- Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 12, Pages: 1936-1943(2021)
- 作者机构：
  
  1.哈尔滨工业大学　物理学院，黑龙江　哈尔滨　150001
  2.长春希达电子科技有限公司，吉林　长春　130103
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51502056);Fundamental Research Funds for the Central Universities(HIT. NSRIF. 2020100)
- DOI：10.37188/CJL.20210285
  CLC： O482.31;TM914
- Received：27 August 2021，
  
  Revised：10 September 2021，
  
  Published：2021-12
- 稿件说明：
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Cui-ling YU, Rui-bin ZHU, Shan LIN, et al. Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells[J]. Chinese journal of luminescence, 2021, 42(12): 1936-1943.
DOI：

Cui-ling YU, Rui-bin ZHU, Shan LIN, et al. Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells[J]. Chinese journal of luminescence, 2021, 42(12): 1936-1943. DOI： 10.37188/CJL.20210285.

摘要

利用水热法合成不同Zn掺杂含量的SnO

(SnO

∶Zn)纳米晶，并通过丝网印刷技术制备了SnO

∶Zn纳米晶光阳极，研究不同含量Zn掺杂SnO

纳米晶光阳极对染料敏化太阳能电池光电性能的影响。实验结果表明，Zn掺杂含量增加能够引起SnO

光阳极的平带电位负向偏移和等电点增加。与未掺杂SnO

染料敏化太阳能电池相比，当Zn掺杂量为2% 时，SnO

∶Zn基染料敏化太阳能电池的功率转换效率(PCE)最高，为4.2%，这归因于Zn掺杂能够增加染料在SnO

光阳极的担载量和提高染料敏化太阳能电池的光生电子寿命(

)。此外，2% Zn掺杂SnO

光阳极进一步经过TiCl

处理，其电池功率转换效率可提高到7.7%。

Abstract

Zn-doped SnO

nanocrystals under hydrothermal conditions were synthesized and subsequently the photoanodes were prepared

via

the screen printing technology for dye-sensitized solar cells. The effect of Zn-doped SnO

on the performance of dye-sensitized solar cells was investigated. It is found that Zn doping into SnO

can induce a negative shift in the flat-band potential and enhance the isoelectric point. As a result

the power conversion efficiency(PCE) of 4.2% was achieved for 2% Zn-doped SnO

based dye-sensitized solar cell compared with undoped SnO

based dye-sensitized solar cell. The enhancement in performance was ascribed to improve photogenerated electron lifetime(

) and dye-uptake capabilities. Moreover

after the TiCl

treatment of the photoanode

the 2% Zn-doped SnO

based dye-sensitized solar cell exhibited an impressive power conversion efficiency of 7.7%.

关键词

Keywords

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Liang CHANG

Hai-fa ZHAO

Da-kun WU

Feng WU

Shan LIN

Rui-bin ZHU

Cui-ling YU

WANG Li-dan

Related Institution

School of Physics， Harbin Institute of Technology

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Fujian Key Laboratory for Advanced Micro-nano Photonics Technology and Devices， College of Physics and Information Engineering， Quanzhou Normal University

College of Chemical Engineering and Material， Quanzhou Normal University

Department of Physics, Harbin Institute of Technology

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⁰

Influence of Zn Doped SnO2 Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells

DOI：10.37188/CJL.20210285

摘要

Abstract

关键词

Keywords

references

Influence of Zn Doped SnO₂ Nanocrystals as Photoanode Materials on Photoelectric Performance of Dye-sensitized Solar Cells