Temperature Sensing Characteristics of Up-conversion Luminescence in Tm3+/Yb3+ Co-doped LuYO3 Phosphor

Zhi-hong ZHANG; Hui-li ZHOU; Feng WU; Yan ZHANG; Lin-hua YE

doi:10.37188/CJL.20210276

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Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor

Synthesis and Properties of Materials | 更新时间：2021-12-17

- Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 12, Pages: 1872-1881(2021)
- 作者机构：
  
  1.中国航发四川燃气涡轮研究院，四川　成都　610500
  2.浙江大学　物理系，浙江　杭州　310027
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11674284);Advanced Jet Propulsion Innovation Center,AEAC(HKCX2019-01-017)
- DOI：10.37188/CJL.20210276
  CLC： O433.1
- Published：2021-12，
  
  Received：20 August 2021，
  
  Revised：07 September 2021，
- 稿件说明：
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ZHI-HONG ZHANG, HUI-LI ZHOU, FENG WU, et al. Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor. [J]. Chinese journal of luminescence, 2021, 42(12): 1872-1881.
DOI：

ZHI-HONG ZHANG, HUI-LI ZHOU, FENG WU, et al. Temperature Sensing Characteristics of Up-conversion Luminescence in Tm³⁺/Yb³⁺ Co-doped LuYO₃ Phosphor. [J]. Chinese journal of luminescence, 2021, 42(12): 1872-1881. DOI： 10.37188/CJL.20210276.

摘要

采用CO

激光区熔法制备了LuYO

∶Tm

(0.3%)-Yb

(5%)荧光材料。在980 nm激光激发下测量了样品在可见光波段的上转换(UC)荧光光谱，其中

→

跃迁产生的蓝色上转换荧光发生明显的Stark劈裂。利用荧光强度比(FIR)方法对样品的Stark劈裂能级

4(a)

与

4(b)

和

与

两对热耦合能级的荧光温度传感特性进行研究。结果表明，两对热耦合能级的测温范围为223~723 K。

4(a)

与

4(b)

能级在低温下灵敏度较高，在223 K处有最大绝对灵敏度5.62×10

-3

-1

和最大相对灵敏度28.2×10

-3

-1

;

与

能级比较适合高温下的温度传感，最大绝对灵敏度为1.44×10

-3

-1

(723 K)，最大相对灵敏度为4.61×10

-3

-1

(516.3 K)，表明所制备荧光材料非常适合用于荧光温度传感。

Abstract

LuYO

∶Tm

(0.3%)-Yb

(5%) phosphor was prepared by CO

laser zone melting method. Under the excitation of 980 nm laser

the sample exhibits up-conversion luminescence(UCL) corresponding to

→

transition in the visible light region

among which obvious Stark splits of luminescence are observed in the blue UCL corresponding to

→

transition. The temperature sensing characteristics of

4(a)

4(b)

and

thermally coupled levels(TCLs) are investigated by fluorescence intensity ratio(FIR) method. The results show that the temperature measurement range of the two pairs of TCLs is 223~723 K. The Stark sub-levels

4(a)

and

4(b)

have higher sensitivity at low temperatures with maximum absolute sensitivity 5.62×10

-3

-1

and maximum relative sensitivity 28.2×10

-3

-1

at 223 K

the

and

TCLs are more suitable for high temperature measurement with maximum absolute sensitivity 1.44×10

-3

-1

(723 K) and maximum relative sensitivity 4.61×10

-3

-1

(516.3 K)

indicating that the prepared fluorescent material is very suitable for fluorescent temperature sensing.

关键词

Tm3+/Yb3+∶LuYO3上转换发光荧光强度比(FIR)荧光温度传感

Keywords

Tm3+/Yb3+∶LuYO3upconversion luminescencefluorescence intensity ratio(FIR)optical temperature sensing

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