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Research Progress on Optical Quenching of Ce3+- and Eu2+-doped Luminescent Materials
增强出版- Chinese Journal of Luminescence Vol. 42, Issue 10, Pages: 1447-1457(2021)
- 作者机构：
1.厦门大学 材料学院，福建 厦门 361005
- 作者简介：
- 基金信息：National Key R&D Program of China(2017YFB04043);National Natural Science Foundation of China(51802274;51572232)
DOI：10.37188/CJL.20210173
CLC：
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Peng ZHENG, Guo-zhen DING, Rong-jun XIE. Research Progress on Optical Quenching of Ce3+- and Eu2+-doped Luminescent Materials. [J]. Chinese Journal of Luminescence 42(10):1447-1457(2021)
Peng ZHENG, Guo-zhen DING, Rong-jun XIE. Research Progress on Optical Quenching of Ce3+- and Eu2+-doped Luminescent Materials. [J]. Chinese Journal of Luminescence 42(10):1447-1457(2021) DOI： 10.37188/CJL.20210173.
摘要
Ce,3+,和Eu,2+,掺杂荧光材料具有吸收率高、发射宽、荧光寿命短、光谱可调等优点，是激光照明与显示应用的理想荧光材料。然而，Ce,3+,和Eu,2+,掺杂荧光材料在激光激发下的发光猝灭严重限制了激光荧光光源的光效和光亮度。传统观点认为发光猝灭主要由热猝灭效应引起，然而近些年的研究结果显示，即使热猝灭效应被有效控制，高强度的激发光本身也会导致荧光材料发射效率显著下降，这种非热效应的发光猝灭可以被简称为光猝灭。本文简要概述了目前已知的四种光猝灭效应，即基态耗尽、激发态吸收、能量传递上转换和光释光效应的研究进展，并对光猝灭的未来研究方向进行了展望。
Abstract
Ce,3+,- and Eu,2+,-doped luminescent materials featuring high absorbance, broad emission band, short decay time, and tunable emission spectra, are ideal candidates for laser lighting and display applications. However, luminescence quenching of Ce,3+,- and Eu,2+,-doped luminescent materials under laser excitation severely restricts the luminous efficacy and luminance of laser-driven lighting devices. As a rule of thumb, the luminescence quenching is attributed to thermal quenching. However, recent studies have found that even if the thermal quenching is controlled, the high-intensity excitation light itself can lead to a significant decrease in the luminous efficiency of luminescent materials. This non-thermal luminescence quenching effect can be referred to as optical quenching. This article briefly reviews the latest research progress of four known optical quenching effects, namely, ground-state depletion, excited-state absorption, energy-transfer upconversion, and optically stimulated luminescence, and the prospects of studies on optical quenching are outlined.
关键词
激光照明与显示荧光材料光猝灭光饱和
Keywords
laser lighting and displayluminescent materialsoptical quenchingoptical saturation
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