Preparation and Application of Bio-based Carbon Dots for LED Chips

Qin WANG; Wen YANG; Jing-ru ZHUANG; Jing LI; Pei-zhi YANG; Zheng-liang WANG

doi:10.37188/CJL.20210159

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Preparation and Application of Bio-based Carbon Dots for LED Chips

Invited Paper | 更新时间：2021-09-03

- Preparation and Application of Bio-based Carbon Dots for LED Chips
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 8, Pages: 1314-1322(2021)
- 作者机构：
  
  1.云南师范大学　可再生能源材料先进技术与制备教育部重点实验室，云南　昆明　 650500
  2.云南师范大学　化学化工学院，云南　昆明　 650500
  3.云南民族大学　化学与环境学院，云南　昆明　 650500
- 作者简介：
  
  wangzhengliang@foxmail.com
- 基金信息：
  
  National Natural Science Foundation of China(U1802257);the Joint Funds of the National Natural Science Foundation of China-Yunnan Provinces(U1702254);The Program for Innovative Research Team (in Science and Technology) in University of Yunnan Province
- DOI：10.37188/CJL.20210159
  CLC： O482.31
- Received：30 April 2021，
  
  Revised：12 May 2021，
  
  Published：01 August 2021
- 稿件说明：
移动端阅览
Qin WANG, Wen YANG, Jing-ru ZHUANG, et al. Preparation and Application of Bio-based Carbon Dots for LED Chips[J]. Chinese journal of luminescence, 2021, 42(8): 1314-1322.
DOI：

Qin WANG, Wen YANG, Jing-ru ZHUANG, et al. Preparation and Application of Bio-based Carbon Dots for LED Chips[J]. Chinese journal of luminescence, 2021, 42(8): 1314-1322. DOI： 10.37188/CJL.20210159.

摘要

以大麦苗为碳源，采用一锅热解法成功获得碳点(CDs)，并对其硼、氮及混合掺杂体系进行了研究。该类型碳点在水溶液中表现出很强的紫外光区宽带吸收，并产生独特的近紫外光和蓝光双发射光学特性；单掺硼及硼氮共掺的CDs粉体表现出良好的固体发光特性，在蓝光区具有较强激发并产生明亮的绿光发射。将这两种CDs作为荧光粉与蓝光GaN芯片结合，制作出LED器件，表现出良好的发光性能。通过K

SiF

∶Mn

红粉的引入可得到高效、高显色性的白光LED。

Abstract

Carbon dots(CDs) were successfully prepared by the one-pot pyrolysis method using the barley seedling as carbon source. The boron

nitrogen and mixed doping system of CDs were studied. The solution of CDs exhibits broad absorption in the UV region. Two emission bands can be observed in the near UV and blue regions. It is worth to note that CDs powder doped with B and co-doped with B and N can be effectively excited by the blue light and emit bright green light. The LED devices were fabricated by combining such two kinds of CDs powder

which exhibit excellent luminescent properties. Using commercial K

SiF

∶Mn

as red components

white LEDs with high luminous efficiency and color rendering index can be obtained.

关键词

Keywords

references

CHANDRA S , DAS P , BAG S , et al . Synthesis, functionalization and bioimaging applications of highly fluorescent carbon nanoparticles [J]. Nanoscale , 2011 , 3 ( 4 ): 1533 - 1540 .

LUO P G , YANG F , YANG S T , et al . Carbon-based quantum dots for fluorescence imaging of cells and tissues [J]. RSC Adv. , 2014 , 4 ( 21 ): 10791 - 10807 .

曲松楠 , 孙铭鸿 , 田震 , 等 . 氮掺杂碳点的合成与应用 [J]. 发光学报 , 2019 , 40 ( 5 ): 557 - 580 .

QU S N , SUN M H , TIAN Z , et al . Synthesis and application of nitrogen-doped carbon dots [J]. Chin. J. Lumin. , 2019 , 40 ( 5 ): 557 - 580 . (in Chinese)

ZHAI F , FENG Y Y , ZHOU K , et al . Graphene-based chiral liquid crystal materials for optical applications [J]. J. Mater. Chem. C , 2019 , 7 ( 8 ): 2146 - 2171 .

LING Y C , YUAN Z , TIAN Y , et al . Bright light-emitting diodes based on organometal halide perovskite nanoplatelets [J]. Adv. Mater. , 2016 , 28 ( 2 ): 305 - 311 .

XU X Y , RAY R , GU Y L , et al . Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments [J]. J. Am. Chem. Soc. , 2004 , 126 ( 40 ): 12736 - 12737 .

SUN Y P , ZHOU B , LIN Y , et al . Quantum-sized carbon dots for bright and colorful photoluminescence [J]. J. Am. Chem. Soc. , 2006 , 28 ( 24 ): 7756 - 7757 .

LIU H P , YE T , MAO C D . Fluorescent carbon nanoparticles derived from candle soot [J]. Angew. Chem. Int. Ed. Engl. , 2007 , 46 ( 34 ): 6473 - 6475 .

BAKER S N , BAKER G A . Luminescent carbon nanodots: emergent nanolights [J]. Angew. Chem. Int. Ed. Engl. , 2010 , 49 ( 38 ): 6726 - 6744 .

LU J , YANG J X , WANG J Z , et al . One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids [J]. ACS Nano , 2009 , 3 ( 8 ): 2367 - 2375 .

PAN D Y , ZHANG J C , LI Z , et al . Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots [J]. Adv. Mater. , 2010 , 22 ( 6 ): 734 - 738 .

MING H , MA Z , LIU Y , et al . Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property [J]. Dalton Trans. , 2012 , 41 ( 31 ): 9526 - 9531 .

ANANTHANARAYANAN A , WANG X W , ROUTH P , et al . Facile synthesis of graphene quantum dots from 3D graphene and their application for Fe3+ sensing [J]. Adv. Funct. Mater. , 2014 , 24 ( 20 ): 3021 - 3026 .

ZHANG J , YUAN Y , LIANG G L , et al . Scale-up synthesis of fragrant nitrogen-doped carbon dots from bee pollens for bioimaging and catalysis [J]. Adv. Sci. , 2015 , 2 ( 4 ): 1500002-1-6 .

GORYACHEVA I Y , SAPELKIN A V , SUKHORUKOV G B . Carbon nanodots: mechanisms of photoluminescence and principles of application [J]. TrAC Trend. Anal. Chem. , 2017 , 90 : 27 - 37 .

LIU S , TIAN J Q , WANG L , et al . Hydrothermal treatment of grass: a low-cost, green route to nitrogen-doped, carbon-rich, photoluminescent polymer nanodots as an effective fluorescent sensing platform for label-free detection of Cu(Ⅱ) ions [J]. Adv. Mater. , 2012 , 24 ( 15 ): 2037 - 2041 .

GE L , GE J C , LIU W M , et al . Tunable multicolor carbon dots prepared from well-defined polythiophene derivatives and their emission mechanism [J]. Nanoscale , 2016 , 8 ( 2 ): 729 - 734 .

WANG Y F , HU A G . Carbon quantum dots: synthesis, properties and applications [J]. J. Mater. Chem. C , 2014 , 2 ( 34 ): 6921 - 6939 .

ZHU S J , SONG Y B , ZHAO X H , et al . The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): current state and future perspective [J]. Nano. Res. , 2015 , 8 ( 2 ): 355 - 381 .

WANG Y , KALYTCHUK S , ZHANG Y , et al . Thickness-dependent full-color emission tunability in a flexible carbon dot ionogel [J]. J. Phys. Chem. Lett. , 2014 , 5 ( 8 ): 1412 - 1420 .

AI L , YANG Y S , WANG B Y , et al . Insights into photoluminescence mechanisms of carbon dots: advances and perspectives [J]. Sci. Bull. , 2021 , 66 ( 8 ): 839 - 856 .

MIAO X , QU D , YANG D X , et al . Synthesis of carbon dots with multiple color emission by controlled graphitization and surface functionalization [J]. Adv. Mater. , 2018 , 30 ( 1 ): 1704740-1-8 .

ZHANG Y Q , LIU X Y , FAN Y , et al . One-step microwave synthesis of N-doped hydroxyl-functionalized carbon dots with ultra-high fluorescence quantum yields [J]. Nanoscale , 2016 , 8 ( 33 ): 15281 - 15287 .

朱盼盼 . 多发射碳点的合成及其在可视化传感中的分析应用 [D]. 重庆 : 西南大学 , 2019 .

ZHU P P . Synthesis of Multi-emission Carbon Dots and Their Analytical Application in Visual Sensing [D]. Chongqing : Southwest University , 2019 . (in Chinese)

周婉 . 碳点的制备及其荧光和磷光性质的研究 [D]. 广州 : 华南农业大学 , 2018 .

ZHOU W . Preparation of Carbon Dots and Their Fluorescence and Phosphorescence Properties [D]. Guangzhou : South China Agriculture University , 2018 . (in Chinese)

XU A L , WANG G , LI Y Q , et al . Carbon-based quantum dots with solid-state photoluminescent: mechanism, implementation, and application [J]. Small , 2020 , 16 ( 48 ): 2004621 .

ZHOU W , ZHUANG J L , LI W , et al . Towards efficient dual-emissive carbon dots through sulfur and nitrogen co-doped [J]. J. Mater. Chem. C , 2017 , 5 ( 32 ): 8014 - 8021 .

SONG X Q , GUO Q Y , CAI Z L , et al . Synthesis of multi-color fluorescent carbon quantum dots and solid state CQDs@SiO2 nanophosphors for light-emitting devices [J]. Ceram. Int. , 2019 , 45 ( 14 ): 17387 - 17394 .

MENG W X , BAI X , WANG B Y , et al . Biomass-derived carbon dots and their applications [J]. Energy Environ. Mater. , 2019 , 2 ( 3 ): 172 - 192 .

YANG Y H , CUI J H , ZHENG M T , et al . One-step synthesis of amino-functionalized fluorescent carbon nanoparticles by hydrothermal carbonization of chitosan [J]. Chem. Commum. , 2012 , 48 ( 3 ): 380 - 382 .

YIN J Y , LIU H J , JIANG S Z , et al . Hyperbranched polymer functionalized carbon dots with multistimuli-responsive property [J]. ACS Macro Lett. , 2013 , 2 ( 11 ): 1033 - 1037 .

ZHENG M , LIU S , LI J , et al . Integrating oxaliplatin with highly luminescent carbon dots: an unprecedented theranostic agent for personalized medicine [J]. Adv. Mater. , 2014 , 26 ( 21 ): 3554 - 3560 .

DONG Y Q , WANG R X , LI H , et al . Polyamine-functionalized carbon quantum dots for chemical sensing [J]. Carbon , 2012 , 50 ( 8 ): 2810 - 2815 .

CHEN Y H , HE J L , HU C F , et al . Room temperature phosphorescence from moisture-resistant and oxygen-barred carbon dot aggregates [J]. J. Mater. Chem. C , 2017 , 5 ( 25 ): 6243 - 6250 .

HE J L , HE Y L , CHEN Y H , et al . Solid-state carbon dots with red fluorescence and efficient construction of dual-fluorescence morphologies [J]. Small , 2017 , 13 ( 26 ): 1700075-1-10 .

JIANG K , WANG Y H , GAO X L , et al . Facile, quick, and gram-scale synthesis of ultralong-lifetime room-temperature-phosphorescent carbon dots by microwave irradiation [J]. Angew. Chem. Int. Ed. Engl. , 2018 , 57 ( 21 ): 6216 - 6220 .

FENG X Y , JIANG K , ZENG H B , et al . A facile approach to solid-state white emissive carbon dots and their application in UV-excitable and single-component-based white LEDs [J]. Nanomaterials , 2019 , 9 ( 5 ): 725-1-5 .

LIU J J , LI R , YANG B . Carbon dots: a new type of carbon-based nanomaterial with wide applications [J]. ACS Cent. Sci. , 2020 , 6 ( 12 ): 2179 - 2195 .

LI H L , ZHANG Y W , WANG L , et al . Nucleic acid detection using carbon nanoparticles as a fluorescent sensing platform [J]. Chem. Commum. , 2011 , 47 ( 3 ): 961 - 963 .

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