Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN<sub>3</sub>∶Eu Composite Phosphor Ceramics

Xing-lin PENG; Shu-xing LI; Ao-chen DU; Zi-qiu CHENG; Xiu-min YAO; Zheng-ren HUANG; Rong-jun XIE; Xue-jian LIU

doi:10.37188/CJL.20210146

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Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics

Invited Paper | 更新时间：2021-10-17

- Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 10, Pages: 1502-1509(2021)
- 作者机构：
  
  1.中国科学院　上海硅酸盐研究所，上海　 200050
  2.中国科学院大学　材料科学与光电技术学院，北京　 100049
  3.厦门大学　材料学院，福建　厦门　 361005
- 作者简介：
- 基金信息：
  
  National Key R&D Program of China(2018YFB0406700)
- DOI：10.37188/CJL.20210146
  CLC： TQ174
- Received：22 April 2021，
  
  Revised：11 May 2021，
  
  Published：01 October 2021
- 稿件说明：
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Xing-lin PENG, Shu-xing LI, Ao-chen DU, et al. Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics[J]. Chinese journal of luminescence, 2021, 42(10): 1502-1509.
DOI：

Xing-lin PENG, Shu-xing LI, Ao-chen DU, et al. Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics[J]. Chinese journal of luminescence, 2021, 42(10): 1502-1509. DOI： 10.37188/CJL.20210146.

摘要

目前报道的高热导AlN-CaAlSiN

∶Eu红色复相荧光陶瓷由于放电等离子体烧结(SPS)产生的碳污染问题导致发光性能难以提高。本研究工作提出了一种减少氮化物荧光陶瓷碳污染的有效方法，即采用热等静压(HIP)在N

气氛中处理SPS烧结的样品。实验表明，经过HIP处理后样品的发光强度和量子效率最高均提高了一倍左右，光通量提高了51%，发光饱和阈值提高了15%以上。其中，性能最佳的样品在入射激光功率高达15 W时依然保持完好且未发生发光饱和，光通量高达197 lm。本研究工作利用HIP处理制备出具有优异发光性能和极高发光饱和阈值的红色荧光陶瓷，促进了大功率激光照明领域的发展。

Abstract

The previously reported highly thermal conductive red-emitting AlN-CaAlSiN

∶Eu composite phosphor ceramic is difficult to improve the luminescence performance due to the carbon contamination problem caused by spark plasma sintering(SPS). In this paper

hot isostatic pressing(HIP) post-treatment is used to prepare red-emitting phosphor ceramics with excellent luminescence performance and extremely high saturation threshold

which promotes the development of high-power laser lighting. The SPS sintered samples were treated by HIP in N

atmosphere. The experimental results show that the luminescence intensity and quantum efficiency of the samples are doubled after HIP post-treatment

the luminous flux is increased by 51%

and the saturation threshold is increased by more than 15%. The sample with the best performance remains intact without luminance saturation when the incident laser power is as high as 15 W

and the luminous flux is up to 197 lm.

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Related Author

Xing-lin PENG

Shu-Xing LI

Ao-chen DU

Zi-qiu Cheng

Xiu-min YAO

Zheng-ren HUANG

Rong-Jun XIE

Xue-jian LIU

Related Institution

College of Materials Science and Opto-Electronic Technology， University of Chinese Academy of Sciences

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Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN3∶Eu Composite Phosphor Ceramics

DOI：10.37188/CJL.20210146

摘要

Abstract

关键词

Keywords

references

Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics