Enhanced Luminescence of BaSi2O2N2∶Eu2+ By Co-doping Er3+
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Enhanced Luminescence of BaSi2O2N2∶Eu2+ By Co-doping Er3+
增强出版
Chinese Journal of LuminescenceVol. 42, Issue 9, Pages: 1323-1330(2021)
作者机构:
1.中国科学院长春光学精密机械与物理研究所 发光学及应用国家重点实验室,吉林 长春 130033
2.中国科学院大学,北京 100049
作者简介:
基金信息:
National Natural Science Foundation of China(11874055;51772286;11974346;11904361);National Key R&D Program of China(2016YFB0400605;2016YFB0701003;2017YFB0403104);Youth Innovation Promotion Association CAS(2020222);Jilin Province Young and Middle-aged Science and Technology Innovation Leading Talents and Team Projects(20190101001JH);The Opening Project Key Laboratory of Transparent Opto-functional Inorganic Material,Chinese Academy of Sciences
Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi2O2N2∶Eu2+ By Co-doping Er3+. [J]. Chinese Journal of Luminescence 42(9):1323-1330(2021)
DOI:
Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi2O2N2∶Eu2+ By Co-doping Er3+. [J]. Chinese Journal of Luminescence 42(9):1323-1330(2021) DOI: 10.37188/CJL.20210145.
Enhanced Luminescence of BaSi2O2N2∶Eu2+ By Co-doping Er3+增强出版
mainly focusing on the internal difference and possible mechanism. The Er
3+
co-doped crystal structure was demonstrated through XRD test
and the purity of the sample and the difference in growth were confirmed by analysis. In order to find out the sources of differences
the emission spectra of doped ions with different valence states have been monitored
and the emission spectra of the changes with the content of Er
3+
have been compared. The internal physical mechanism of co-doping Er
3+
enhanced luminescence is seen from the change of the luminescence. The internal physical mechanism of the co-doping Er
3+
enhanced luminescence is to control the crystal texture and adjust the valence state. For practical applications in the future
a temperature characteristic test was carried out to show the emission spectrum changes under temperature variation. This research provides new ideas for the work of regulating the luminous intensity and improving quantum efficiency.
GU Y X, ZHANG Q H, LI Y G, et al. Nitridation from core-shell oxides for tunable luminescence of BaSi2O2N2∶Eu2+ LED phosphors [J].J. Mater. Chem., 2010, 20(29):6050-6056.
YUN B G, HORIKAWA T, HANZAWA H, et al. Preparation and luminescence properties of single-phase BaSi2O2N2∶Eu2+, a bluish-green phosphor for white light-emitting diodes [J].J. Electrochem. Soc., 2010, 157(10):J364.
WANG L L, NI H Y, ZHANG Q H. Luminescence and encapsulation properties of BaSi2O2N2 doped with divalent europium [J].Chin. J. Lumin., 2012, 33(5):465-469. (in Chinese)
QIN J L, ZHANG H R, LEI B F, et al. Thermoluminescence and temperature-dependent afterglow properties in BaSi2O2N2∶Eu2+ [J].J. Am. Ceram. Soc., 2013, 96(10):3149-3154.
MA Z D, ZHOU J Y, ZHANG J C, et al. Mechanics-induced triple-mode anticounterfeiting and moving tactile sensing by simultaneously utilizing instantaneous and persistent mechanoluminescence [J].Mater. Horiz., 2019, 6(10):2003-2008.
PETIT R R, MICHELS S E, FENG A, et al. Adding memory to pressure-sensitive phosphors [J].Light:Sci. Appl., 2019, 8:124-1-10.
BOTTERMAN J, VAN DEN EECKHOUT K, DE BAERE I, et al. Mechanoluminescence in BaSi2O2N2∶Eu [J].Acta Mater., 2012, 60(15):5494-5500.
ZHAO C L, HU Y S, CHEN K, et al. Research progress in silicon-based (oxy) nitride phosphors for phosphor-converted white LED [J].Chin. J. Rare Met., 2017, 41(12):1374-1385. (in Chinese)
PAWLIK T, MICHALIK D, BARZOWSKA J, et al. The influence of synthesis temperature on manufacturing and properties of SrSi2O2N2∶Eu2+ powders [J].Arch. Metall. Mater., 2017, 62(2):687-690.
SONG Y, SONG Y, TODA K, et al. Synthesis and photoluminescence properties of oxynitride phosphors M0.98Si2O2N2∶Ehttp://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210965&type=http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210973&type=http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210969&type=(M=Ba, Sr, Ca) using the cellulose assisted liquid phase precursor process [J].Ceram. Int., 2016, 42(8):9667-9672.
HUANG J S, LIU R H, LIU Y H, et al. Effect of fluxes on synthesis and luminescence properties of BaSi2O2N2∶Eu2+ oxynitride phosphors [J].J. Rare Earths, 2018, 36(3):225-230.
ADAMCZYK B J, BRIK M G, NAGIRNYI V, et al. Optical properties of SrSi2O2N2∶Eu2+ phosphor enhanced by the addition of carbonate or fluoride reactive agents [J].J. Alloys Compd., 2020, 845:155468.
ADAMCZYK B J, JÜSTEL T, PLEWA J, et al. The influence of Na2CO3 flux on photoluminescence properties of SrSi2O2N2∶Eu2+ phosphor [J].Ceram. Int., 2017, 43(15):12381-12387.
HUO J S, LÜ W, SHAO B Q, et al. Enhanced luminescence intensity of CaSi2O2N2∶Eu2+ phosphor by using flux in the preparation process and incorporating Gd3+ ions [J].J. Lumin., 2016, 180:46-50.
LI H L, CHEN H, YANG L, et al. Facile synthesis and systematic study of Eu2+ doped SrSi2O2N2 green-emitting phosphor based on a new method [J].J. Lumin., 2018, 194:661-666.
XIE A, WANG Y W, ZHANG Y J, et al. Structure and photoluminescence properties of SrSi2O2N2∶Eu2+ phosphors prepared by two-step solid state reaction using Sr2SiO4∶Eu2+ as a precursor [J].Sci. Sinica-Phys. Mech. Astron., 2014, 44(7):712-719. (in Chinese)
WU D, FU L, HE S A, et al. Significantly enhanced luminescence efficiency and thermal stability of BaSi2O2N2∶Eu2+ phosphor by doping a very small amount of SiC [J].Ceram. Int., 2020, 46(16):25382-25391.
LI X C, DENG C Y, LONG F, et al. Effect of silicon powder content in starting materials on the phase and luminescence properties of SrSi2O2N2∶Eu2+ phosphors [J].J. Mater. Sci.:Mater. Electron., 2017, 28(17):12551-12554.
SONG X F, FU R L, AGATHOPOULOS S, et al. Synthesis of BaSi2O2N2∶Ce3+, Eu2+ phosphors and determination of their luminescence properties [J].J. Am. Ceram. Soc., 2011, 94(2):501-507.
MAJEWSKA N, LEŚNIEWSKI T, MAHLIK S, et al. Study of persistent luminescence and thermoluminescence in SrSi2N2O2∶Eu2+, M3+(M=Ce, Dy, and Nd) [J].Phys. Chem. Chem. Phys., 2020, 22(30):17152-17159.
ZOU Y X, YU L X, GAO Z Y, et al. Synthesis, crystal structure, and photoluminescence of Eu2+, Ce3+, Mn2+ doped oxynitride phosphors [J].Opt. Mater., 2019, 92:411-417.
HAO J R, CAO L, WEI Y, et al. Improving photoluminescence and thermal stability of CaSi2O2N2∶Eu2+ phosphors by codoping lanthanide ions (Ln=Sc, La, Gd, Yb, Lu) [J].Mater. Lett., 2018, 211:122-125.
KECHELE J A, OECKLER O, STADLER F, et al. Structure elucidation of BaSi2O2N2—a host lattice for rare-earth doped luminescent materials in phosphor-converted (pc)-LEDs [J].Solid State Sci., 2009, 11(2):537-543.
MIYAZAKI H, YOSHIDA S, SUZUKI H, et al. Phosphorescence properties of MSi2O2N2∶Eu(M=Ca, Sr, Ba) mixture-phase phosphors using Si2N2O powder [J].J. Ceram. Soc. Japan, 2015, 123(1435):152-155.
LI G G, LIN C C, CHEN W T, et al. Photoluminescence tuning via cation substitution in oxonitridosilicate phosphors:DFT calculations, different site occupations, and luminescence mechanisms [J].Chem. Mater., 2014, 26(9):2991-3001.
SEIBALD M, ROSENTHAL T, OECKLER O, et al. Highly efficient pc-LED phosphors Sr1-xBaxSi2O2N2∶Eu2+(0 x 1)-crystal structures and luminescence properties revisited [J].Crit. Rev. Solid State Mater. Sci., 2014, 39(3):215-229.
CHEN Y, ZHANG J. Investigation on luminescence of bifunctional Y4.67(SiO4)3O∶Ce3+/Tb3+/Eu3+ phosphors [J].J. Lumin., 2020, 218:116842.
HUANG D Y, WEI Y, DANG P P, et al. Tunable color emission in LaScO3∶Bi3+, Tb3+, Eu3+ phosphor [J].J. Am. Ceram. Soc., 2020, 103(5):3273-3285.
ZHANG L L, HAO Z D, ZHANG X, et al. Enhanced ~2 μm emission of Tm3+ in Lu2O3 by addition of a trace amount of Er3+ [J].Inorg. Chem., 2017, 56(21):13062-13069.
WU H, HAO Z D, ZHANG L L, et al. Phonon energy dependent energy transfer upconversion for the red emission in the Er3+/Yb3+ system [J].J. Phys. Chem. C, 2018, 122(17):9611-9618.
KIM J S, PARK Y H, KIM S M, et al. Temperature-dependent emission spectra of M2SiO4∶Eu2+(M=Ca, Sr, Ba) phosphors for green and greenish white LEDs [J].Solid State Commun., 2005, 133(7):445-448.
BAGINSKIY I, LIU R S, WANG C L, et al. Temperature dependent emission of strontium-barium orthosilicate (Sr2-xBax)-SiO4∶Eu2+ phosphors for high-power white light-emitting diodes [J].J. Electrochem. Soc., 2011, 158(10):P118.
XIAO W E, ZHANG X, HAO Z D, et al. Blue-emitting K2Al2B2O7∶Eu2+phosphor with high thermal stability and high color purity for near-UV-pumped white light-emitting diodes [J].Inorg. Chem., 2015, 54(7):3189-3195.