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Narrow-band Blue Emission of Bi3+ Based on High Crystal Structure Symmetry
增强出版- Chinese Journal of Luminescence Vol. 42, Issue 9, Pages: 1365-1375(2021)
- 作者机构：
中国地质大学(武汉)材料与化学学院 教育部纳米矿物材料及应用工程研究中心，湖北 武汉 430074
- 作者简介：
- 基金信息：National Natural Science Foundation of China(52072349);Fundamental Research Founds for National University, China University of Geosciences (Wuhan)(1910491T02)
DOI：10.37188/CJL.20210141
CLC： O482.31Received：21 April 2021，
Revised：08 May 2021，
Published：01 September 2021
- 稿件说明：
移动端阅览
Yi WEI, Guo-gang LI. Narrow-band Blue Emission of Bi3+ Based on High Crystal Structure Symmetry[J]. Chinese journal of luminescence, 2021, 42(9): 1365-1375.
Yi WEI, Guo-gang LI. Narrow-band Blue Emission of Bi3+ Based on High Crystal Structure Symmetry[J]. Chinese journal of luminescence, 2021, 42(9): 1365-1375. DOI： 10.37188/CJL.20210141.
摘要
采用高温固相法合成了系列K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10)荧光粉材料。通过精细Rietveld结构精修、光致激发和发射光谱、X射线光电子衍射及热稳定性等手段对晶体结构和发光性能进行了研究。实验结果表明，在紫外光激发下，Bi
3+
展现了半高宽低至43 nm的窄带蓝光发射。这是由于K
4
CaGe
3
O
9
基质拥有高对称性的晶体结构。与此同时，制备的K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10)荧光粉材料展现了卓越的发光热稳定性，在423 K时，发光强度可以保持在室温状态下的83%。上述研究证明制备的K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10)荧光粉材料在白光发光二极管(LED)或背光显示中有潜在的应用前景。在高对称性晶体结构中掺杂Bi
3+
实现窄带发光的研究思路可以为未来窄带荧光粉的研发提供理论研究基础和科学依据。
Abstract
A series of new K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10) phosphors are prepared
via
traditional high-temperature solid solution route. The detailed crystal structure and photoluminescence properties of K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10) materials are studied through precise Rietveld structure refinement
photoluminescence excitation and emission spectra
XPS and thermal stability measurements. According to experimental data
Bi
3+
displays narrow blue emission with spectral width at around 43 nm under n-UV light excitation. The main reason is that K
4
CaGe
3
O
9
shows highly-symmetric crystal structure. Meanwhile
the as-prepared K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10) phosphors show excellent thermal stability
of which photoluminescence intensity at 423 K remains 83% than that at 298 K. The above results confirm that the as-prepared K
4
CaGe
3
O
9
∶
x
Bi
3+
(0.003≤
x
≤0.10) phosphors show potential application in white LED lighting and backlight display areas. This work proposes that Bi
3+
can achieve narrow-band emission when doping into highly-symmetric crystal structure. This approach can provide theoretical basis and guidance to exploit Bi
3+
activated narrow-band emitting phosphor materials.
关键词
Keywords
references
ZAMPETTI A , MINOTTO A , CACIALLI F . Near-infrared(NIR) organic light-emitting diodes(OLEDs): challenges and opportunities [J]. Adv. Funct. Mater. , 2019 , 29 ( 21 ): 1807623-1-22 .
WANG L , XIE R J , SUEHIRO T , et al . Down-conversion nitride materials for solid state lighting:recent advances and perspectives [J]. Chem. Rev. , 2018 , 118 ( 4 ): 1951 - 2009 .
ZHAO M , ZHANG Q Y , XIA Z G . Narrow-band emitters in LED backlights for liquid-crystal displays [J]. Mater. Today , 2020 , 40 : 246 - 265 .
FANG M H , JR LEAÑO J L , LIU R S . Control of narrow-band emission in phosphor materials for application in light-emitting diodes [J]. ACS Energy Lett. , 2018 , 3 ( 10 ): 2573 - 2586 .
MA Z Z , SHI Z F , YANG D W , et al . High color-rendering index and stable white light-emitting diodes by assembling two broadband emissive self-trapped excitons [J]. Adv. Mater. , 2021 , 33 ( 2 ): e2001367 .
FANG M H , MENG S Y , MAJEWSKA N , et al . Chemical control of SrLi(Al1-xGax)3N4∶Eu2+ red phosphors at extreme conditions for application in light-emitting diodes [J]. Chem. Mater. , 2019 , 31 ( 12 ): 4614 - 4618 .
FANG M H , MAHLIK S , LAZAROWSKA A , et al . Structural evolution and effect of the neighboring cation on the photoluminescence of Sr(LiAl3)1-x(SiMg3)xN4∶Eu2+ phosphors [J]. Angew. Chem. Int. Ed. , 2019 , 58 ( 23 ): 7767 - 7772 .
YOSHIMURA K , FUKUNAGA H , IZUMI M , et al . Achieving superwide-color-gamut display by using narrow-band green-emitting γ-AlON∶Mn, Mg phosphor [J]. Jpn. J. Appl. Phys. , 2017 , 56 ( 4 ): 041701-1-5 .
PUST P , WEILER V , HECHT C , et al . Narrow-band red-emitting Sr[LiAl3N4]∶Eu2+ as a next-generation LED-phosphor material [J]. Nat. Mater. , 2014 , 13 ( 9 ): 891 - 896 .
HUANG L , ZHU Y W , ZHANG X J , et al . HF-free hydrothermal route for synthesis of highly efficient narrow-band red emitting phosphor K2Si1-xF6∶xMn4+ for warm white light-emitting diodes [J]. Chem. Mater. , 2016 , 28 ( 5 ): 1495 - 1502 .
HUANG D C , ZHU H M , DENG Z H , et al . Moisture-resistant Mn4+-doped core-shell-structured fluoride red phosphor exhibiting high luminous efficacy for warm white light-emitting diodes [J]. Angew. Chem. Int. Ed. , 2019 , 58 ( 12 ): 3843 - 3847 .
AMARASINGHE D K , RABUFFETTI F A . Bandshift luminescence thermometry using Mn4+∶Na4Mg(WO4)3 phosphors [J]. Chem. Mater. , 2019 , 31 ( 24 ): 10197 - 10204 .
ZHOU Z W , ZHENG J M , SHI R , et al . Ab initio site occupancy and far-red emission of Mn4+ in cubic-phase La(MgTi)1/2O3 for plant cultivation [J]. ACS Appl. Mater. Interfaces , 2017 , 9 ( 7 ): 6177 - 6185 .
RAINÒ G , BECKER M A , BODNARCHUK M I , et al . Superfluorescence from lead halide perovskite quantum dot superlattices [J]. Nature , 2018 , 563 ( 7733 ): 671 - 675 .
KANG C H , DURSUN I , LIU G Y , et al . High-speed colour-converting photodetector with all-inorganic CsPbBr3 perovskite nanocrystals for ultraviolet light communication [J]. Light:Sci. Appl. , 2019 , 8 : 94-1-12 .
DIROLL B T , NEDELCU G , KOVALENKO M V , et al . High-temperature photoluminescence of CsPbX3(X=Cl, Br, I) nanocrystals [J]. Adv. Funct. Mater. , 2017 , 27 ( 21 ): 1606750-1-7 .
TANG Z B , ZHANG G Y , WANG Y H . Design and development of a bluish-green luminescent material(K2HfSi3O9∶Eu2+) with robust thermal stability for white light-emitting diodes [J]. ACS Photonics , 2018 , 5 ( 9 ): 3801 - 3813 .
LIAO H X , ZHAO M , MOLOKEEV M S , et al . Learning from a mineral structure toward an ultra-narrow-band blue-emitting silicate phosphor RbNa3(Li3SiO4)4∶Eu2+ [J]. Angew. Chem. Int. Ed. , 2018 , 57 ( 36 ): 11728 - 11731 .
ZHAO M , LIAO H X , NING L X , et al . Next-generation narrow-band green-emitting RbLi(Li3SiO4)2∶Eu2+ phosphor for backlight display application [J]. Adv. Mater. , 2018 , 30 ( 38 ): e1802489 .
ZHAO M , CAO K , LIU M J , et al . Dual-shelled RbLi(Li3SiO4)2∶Eu2+@Al2O3@ODTMS phosphor as a stable green emitter for high-power LED backlights [J]. Angew. Chem. Int. Ed. , 2020 , 59 ( 31 ): 12938 - 12943 .
STROBEL P , MAAK C , WEILER V , et al . Ultra-narrow-band blue-emitting oxoberyllates AELi2[Be4O6]∶Eu2+(AE=Sr, Ba) paving the way to efficient RGB pc-LEDs [J]. Angew. Chem. Int. Ed. , 2018 , 57 ( 28 ): 8739 - 8743 .
DUTTA S , SOM S , MEENA M L , et al . Multisite-occupancy-driven intense narrow-band blue emission from Sr5SiO4Cl6∶Eu2+ phosphor with excellent stability and color performance [J]. Inorg. Chem. , 2020 , 59 ( 3 ): 1928 - 1939 .
WANG Z B , YE W K , CHU I H , et al . Elucidating structure-composition-property relationships of the β-SiAlON∶Eu2+ phosphor [J]. Chem. Mater. , 2016 , 28 ( 23 ): 8622 - 8630 .
DANG P , ZHANG Q , LIU D , et al . Hetero-valent substitution strategy toward orange-red luminescence in Bi3+ doped layered perovskite oxide phosphors for high color rendering index white light-emitting diodes [J]. Chem. Eng. J. , 2021 , 420 : 127640 .
LIU D J , YUN X H , DANG P P , et al . Yellow/orange-emitting ABZn2Ga2O7∶B3+ (A=Ca, Sr; B=Ba, Sr) phosphors:optical temperature sensing and white light-emitting diode applications [J]. Chem. Mater. , 2020 , 32 ( 7 ): 3065 - 3077 .
ARFIN H , KAUR J , SHEIKH T , et al . Bi3+-Er3+ and Bi3+ -Yb3+ codoped Cs2AgInCl6 double perovskite near-infrared emitters [J]. Angew. Chem. Int. Ed. , 2020 , 59 ( 28 ): 11307 - 11311 .
LI X , LI P L , WANG Z J , et al . Color-tunable luminescence properties of Bi3+ in Ca5(BO3)3F via changing site occupation and energy transfer [J]. Chem. Mater. , 2017 , 29 ( 20 ): 8792 - 8803 .
WU Q S , LI Y Y , WANG Y J , et al . A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs [J]. Chem. Eng. J. , 2020 , 401 : 126130 .
GUAN M Y , WANG W , YAN W , et al . Novel narrow-band blue-emitting Cs3Zn6B9O21∶B3+ phosphor with superior thermal stability [J]. CrystEngComm , 2020 , 22 ( 35 ): 5792 - 5798 .
YE S S , LIU H , WANG Y J , et al . Design of a bismuth-activated narrow-band cyan phosphor for use in white light emitting diodes and field emission displays [J]. ACS Sustainable Chem. Eng. , 2020 , 8 ( 49 ): 18187 - 18195 .
ZHOU X F , GENG W Y , GUO H J , et al . K4CaGe3O9∶Mn2+, Yb3+:a novel orange-emitting long persistent luminescent phosphor with a special nanostructure [J]. J. Mater. Chem. C , 2018 , 6 ( 27 ): 7353 - 7360 .
WEI Q , DING J Y , WANG Y H . A novel tunable extra-broad yellow-emitting nitride phosphor with zero-thermal-quenching property [J]. Chem. Eng. J. , 2020 , 386 : 124004 .
LI H M , PANG R , LIU G Y , et al . Synthesis and luminescence properties of Bi3+-activated K2MgGeO4:a promising high-brightness orange-emitting phosphor for WLEDs conversion [J]. Inorg. Chem. , 2018 , 57 ( 19 ): 12303 - 12311 .
KANG F W , ZHANG H S , WONDRACZEK L , et al . Band-gap modulation in single Bi3+-doped yttrium-scandium-niobium vanadates for color tuning over the whole visible spectrum [J]. Chem. Mater. , 2016 , 28 ( 8 ): 2692 - 2703 .
WANG D Y , TANG Z B , KHAN W U , et al . Photoluminescence study of a broad yellow-emitting phosphor K2ZrSi2O7∶Bi3+ [J]. Chem. Eng. J. , 2017 , 313 : 1082 - 1087 .
WEI Y , GAO Z Y , YUN X H , et al . Abnormal Bi3+-activated NIR emission in highly symmetric XAl12O19 (X=Ba, Sr, Ca) by selective sites occupation [J]. Chem. Mater. , 2020 , 32 ( 19 ): 8747 - 8753 .
DANG P P , LIU D J , YUN X H , et al . Ultra-broadband cyan-to-orange emitting Ba1+xSr1-xGa4O8∶Bi3+ phosphors:luminescence control and optical temperature sensing [J]. J. Mater. Chem. C , 2020 , 8 ( 5 ): 1598 - 1607 .
WEI Y , YANG H , GAO Z Y , et al . Anti-thermal-quenching Bi3+ luminescence in a cyan-emitting Ba2ZnGe2O7∶Bi phosphor based on zinc vacancy [J]. Laser Photonics Rev. , 2021 , 15 ( 1 ): 2000048-1-10 .
WEI Y , XING G C , LIU K , et al . New strategy for designing orangish-red-emitting phosphor via oxygen-vacancy-induced electronic localization [J]. Light:Sci. Appl. , 2019 , 8 ( 1 ): 15-1-9 .
CAO R P , CHEN T , REN Y C , et al . Tunable emission of LiCa3MgV3O12∶Bi3+ via energy transfer and changing excitation wavelength [J]. Mater. Res. Bull. , 2019 , 111 : 87 - 92 .
CAO R P , QUAN G J , SHI Z H , et al . Synthesis and luminescence properties of LiBaPO4∶Bi3+ yellow-emitting phosphor for solid-state lighting [J]. J. Mater. Sci.:Mater. Electron. , 2018 , 29 ( 7 ): 5287 - 5292 .
CAO R P , QUAN G J , SHI Z H , et al . A double perovskite Ca2MgWO6∶Bi3+ yellow-emitting phosphor:synthesis and luminescence properties [J]. J. Lumin. , 2017 , 181 : 332 - 336 .
WANG W , TAO M X , LIU Y X , et al . Photoluminescence control of UCr4C4-type phosphors with superior luminous efficiency and high color purity via controlling site selection of Eu2+ activators [J]. Chem. Mater. , 2019 , 31 ( 21 ): 9200 - 9210 .
WEI Y , CAO L , LV L M , et al . Highly efficient blue emission and superior thermal stability of BaAl12O19∶Eu2+ phosphors based on highly symmetric crystal structure [J]. Chem. Mater. , 2018 , 30 ( 7 ): 2389 - 2399 .
XING Z H , LI P L , DAI D J , et al . Self-luminescence of perovskite-like LaSrGaO4 via intrinsic defects and anomalous luminescence analysis of LaSrGaO4∶Mn2+ [J]. Inorg. Chem. , 2019 , 58 ( 8 ): 4869 - 4879 .
KIM Y H , ARUNKUMAR P , KIM B Y , et al . A zero-thermal-quenching phosphor [J]. Nat. Mater. , 2017 , 16 ( 5 ): 543 - 550 .
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