Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption

Hui-zhen WANG; Song-song XUE; Xia ZHOU; Jia-qin LIU; Zheng-feng XIE

doi:10.37188/CJL.20210134

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Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption

Luminescence Applications and Interdisciplinary Fields | 更新时间：2021-09-13

- Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 9, Pages: 1427-1435(2021)
- 作者机构：
  
  1.西华大学　理学院，四川　成都　 610039
  2.西南石油大学　化学化工学院，四川　成都　 610500
- 作者简介：
- 基金信息：
  
  the Ministry of Education Chunhui Project(191630);Sichuan Provincial Department of Education Project(18ZB0571)
- DOI：10.37188/CJL.20210134
  CLC： O625.6
- Published：01 September 2021，
  
  Received：07 June 2021，
  
  Revised：30 June 2021，
- 稿件说明：
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HUI-ZHEN WANG, SONG-SONG XUE, XIA ZHOU, et al. Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption. [J]. Chinese journal of luminescence, 2021, 42(9): 1427-1435.
DOI：

HUI-ZHEN WANG, SONG-SONG XUE, XIA ZHOU, et al. Synthesis of Highly Selective Copper Ion Probe and Its Application in Adsorption. [J]. Chinese journal of luminescence, 2021, 42(9): 1427-1435. DOI： 10.37188/CJL.20210134.

摘要

以3-羟基-2-萘甲酰肼和4-二苯氨基苯甲醛为原料，设计合成了一种新型萘甲酰腙铜离子荧光探针L(N'-(4-(二苯胺基)亚苄基)-3-羟基-2-萘酰肼)，并通过

H NMR、

C NMR、HR-MS、IR和X射线单晶衍射法对L的结构进行了表征。在H

O/DMSO(

V∶V

=3∶7

pH=7)溶液体系中，可以高选择性和高灵敏性识别Cu

。通过质谱法、核磁滴定和DFT计算对L与Cu

可能的作用机理进行了研究。通过将L掺杂到聚丙烯酰胺(PAM)中，制备了凝胶(PAML)。研究表明，PAML对Cu

有很好的吸附性能，且不受其他离子的干扰，对水中Cu

去除率可以达到96.99%，并且在紫外灯下通过肉眼很容易进行区分。之后通过SEM-EDS对PAML吸附前后的微观形貌和成分进行了分析。

Abstract

A novel Schiff base fluorescent probe (N'-(4-(diphenylamino)benzylidene)-3-hydroxy-2-Naphtho-hydrazide)(L) was designed and synthesized using 3-hydroxy-2-naphthoic acid hydrazide and 4-diphenylaminobenzaldehyde as raw materials. The structure of L was characterized through

H NMR

C NMR

HR-MS

IR and X-ray. The study found that probe L showed high sensitivity and selectivity response to copper ions(Cu

) in H

O/DMSO(

∶

=3∶7

pH=7) solution. The possible mechanism of coordination between L and Cu

was studied by HR-MS

H NMR and DFT calculation. PAML was prepared by the method of doping L into polyacrylamide(PAM). PAML had high adsorption of Cu

and the removal rate of Cu

by PAML in water reached 96.99%

in addition

the color change could be distinguished by naked eyes under UV lamp. The microscopic morphology of PAML before and after adsorption of Cu

was observed by SEM-EDS.

关键词

酰腙铜离子荧光探针聚丙烯酰胺掺杂

Keywords

Schiff baseCu2+fluorescence probepolyacrylamide(PAM) doping

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