Pr<sup>3+</sup> Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism

Ting LI; Yun-ling YANG; Yu-ting FAN; Jia-yong YUAN; Yu-fang SHEN; Zhi-jun ZHANG

doi:10.37188/CJL.20210094

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Pr³⁺ Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism

Synthesis and Properties of Materials | 更新时间：2021-06-18

- Pr³⁺ Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 6, Pages: 818-828(2021)
- 作者机构：
  
  1.桂林理工大学材料科学与工程学院, 广西桂林　 541000
  2.上海大学材料科学与工程学院, 上海　 200444
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51772185;U1832159;11905122);China Postdoctoral Science Foundation(2019M651469)
- DOI：10.37188/CJL.20210094
  CLC： O482.31
- Published：01 June 2021，
  
  Received：17 March 2021，
  
  Revised：31 March 2021，
扫描看全文
Ting LI, Yun-ling YANG, Yu-ting FAN, et al. Pr³⁺ Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism. [J]. Chinese Journal of Luminescence 42(6):818-828(2021)
DOI：

Ting LI, Yun-ling YANG, Yu-ting FAN, et al. Pr³⁺ Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism. [J]. Chinese Journal of Luminescence 42(6):818-828(2021) DOI： 10.37188/CJL.20210094.

摘要

采用高温固相法成功制备出新型Sr

1-2

ZnOS应力发光材料。通过XRD、扫描电镜、漫反射、光致发光、荧光衰减、应力发光和热释光等测试详细研究了晶体结构、形貌、光致和力致发光性能及其发光机理。在298 nm激发下，Sr

1-2

ZnOS的发光位于522 nm和674 nm，分别来自于Pr

离子从激发态

到

、

的跃迁。随着Pr

浓度增加，发光强度先增加后减小，在

=0.015时发光最强，且衰减时间从17.79 μs减短到5.93 μs。在载荷为5 000 N激发下可以获得Pr

离子的522 nm和674 nm的应力发光发射带。位于522 nm和674 nm的两个发射带的相对强度

随着掺杂浓度的增加呈线性减小，且在色坐标图(CIE)和实物应力发光照片中均能观测到应力发光的颜色从黄绿光到橙黄光的转变。该材料的研究将为应力发光领域提供调控颜色的新思路，在压力显示成像和应力传感领域具有潜在的应用价值。

Abstract

The development of new mechanoluminescence(ML) materials for stress sensor and imaging is of great importance

owing to their unique physical

chemical

and optical properties. A series of novel Sr

1-2

ZnOS phosphor were successfully synthesized by the high temperature solid state reaction method. The crystal structure

morphology

photoluminescence(PL)

ML properties and luminescence mechanism of Sr

1-2

ZnOS were studied in detail. The unit cell volume of Sr

1-2

ZnOS decreased from 0.153 52 to 0.153 05 nm

with the concentration Pr

increasing from

=0.005 to 0.04. The emission bands of the Pr

ion at 522 and 674 nm originated from the transition from excited state

to lower energy levels

and

. The PL intensity reaches the maximum when the Pr

ion concentration reached 0.015. The decay time decreases from 17.79 to 5.93 μs with increasing Pr

concentration. At the same time

the emission peaked at 522 and 674 nm were observed under the load of 5 000 N. Meanwhile

the ML intensity first increases reaching the maximum of the Pr

ion concentration at

=0.02

and then decreases with the doped concentration increasing. In addition

the relative intensity

value of the two emission bands at 522 and 674 nm decreased with the Pr

concentration increasing from

=0.005 to 0.04. Moreover

the ML color transition from yellow-green light to orange-yellow light emission can be observed in both the color coordinate diagram and the sample photos under pressure. Therefore

these materials offer a new approach to controlling luminescent colors in the ML field

with potential applications in the fields of stress display

imaging and stress sensors.

关键词

应力发光SrZnOSPr3+

Keywords

mechanoluminescenceSrZnOSPr3+

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Related Author

Ting LI

Yun-ling YANG

Yu-ting FAN

Jia-yong YUAN

Yu-fang SHEN

Zhi-jun ZHANG

HE Ling

WEN Shun

Related Institution

School of Materials Science and Engineering， Guilin University of Technology

School of Materials Science and Engineering， Shanghai University

School of Material Science Engineering， Lanzhou University of Technology

State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals， Lanzhou University of Technology

Gansu Rare Earth New Materials Co.， Ltd

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⁰

Pr3+ Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism

DOI：10.37188/CJL.20210094

摘要

Abstract

关键词

Keywords

references

Pr³⁺ Doped SrZnOS to Achieve Tunable Mechanoluminescence Color and Mechanoluminescence Mechanism