Synthesis and Performance of La3Si6N11∶Ce3+ Phosphor-in-glass Films for Laser Lighting Applications

Min-hang HUANG; Qiang-qiang ZHU; Yao MENG; Xiang-yu HU; Hong ZHANG; Le WANG

doi:10.37188/CJL.20210076

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Synthesis and Performance of La₃Si₆N₁₁∶Ce³⁺ Phosphor-in-glass Films for Laser Lighting Applications

Invited Paper | 更新时间：2021-10-17

- Synthesis and Performance of La₃Si₆N₁₁∶Ce³⁺ Phosphor-in-glass Films for Laser Lighting Applications
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 10, Pages: 1482-1492(2021)
- 作者机构：
  
  中国计量大学　光学与电子科技学院，浙江　杭州　 310018
- 作者简介：
- 基金信息：
  
  Preeminence Youth Science Funds of Zhejiang Province(LR19F050001);National Natural Science Foundation of China(51832005;62075203;51702339);National Key R&D Program of China(2017YFB0403100;2017YFB0403105)
- DOI：10.37188/CJL.20210076
  CLC： O482.31
- Received：02 March 2021，
  
  Revised：2021-03-16，
  
  Published：01 October 2021
- 稿件说明：
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Min-hang HUANG, Qiang-qiang ZHU, Yao MENG, et al. Synthesis and Performance of La₃Si₆N₁₁∶Ce³⁺ Phosphor-in-glass Films for Laser Lighting Applications[J]. Chinese Journal of Luminescence, 2021, 42(10): 1482-1492.
DOI：

Min-hang HUANG, Qiang-qiang ZHU, Yao MENG, et al. Synthesis and Performance of La₃Si₆N₁₁∶Ce³⁺ Phosphor-in-glass Films for Laser Lighting Applications[J]. Chinese Journal of Luminescence, 2021, 42(10): 1482-1492. DOI： 10.37188/CJL.20210076.

摘要

高性能荧光转换材料的开发是激光照明技术发展的关键，由于荧光材料会受到高功率激光的激发，因此必须具有高导热性能及优良的高温稳定性。荧光玻璃薄膜材料由于其优异的综合性能，在激光照明显示领域表现出了良好的应用前景。传统Y

∶Ce

(YAG∶Ce

)荧光玻璃薄膜由于显色性能较差，难以满足高品质激光照明应用的需求。氮化物荧光材料La

∶Ce

由于结构的特性，表现出比YAG∶Ce

更宽的发光光谱和更好的热猝灭性能。本工作针对高显色激光照明的应用需求，在镀有光学薄膜(蓝光透过)的高导热蓝宝石基板上制备了La

∶Ce

(LSN∶Ce

)荧光玻璃薄膜，并研究了合成温度、荧光粉与玻璃粉的比例(PtG比)、薄膜厚度以及蓝光透过光学薄膜对最终样品发光性能的影响。通过工艺优化，在800 ℃条件下获得了综合性能优异的LSN∶Ce

荧光玻璃薄膜(PtG比为1∶1，厚度为50 μm)，样品可承受最大功率密度为12.73 W/mm

蓝色激光的激发，发光效率可以达到157.6 lm/W。此外，LSN∶Ce

荧光玻璃薄膜显色指数

相比YAG∶Ce

提高了9%左右，达到了74.9，在高显色、高功率激光照明领域表现出良好的应用前景。

Abstract

The development of high-performance color converters is the key to laser lighting technology. Due to the high-power excitation from the laser lighting

the color converters must have high thermal conductivity and excellent high-temperature stability. The phosphor-in-glass(PiG) film is promising for high-power laser lighting applications due to its excellent comprehensive performance. The traditional Y

∶Ce

(YAG∶Ce

) PiG film can hardly achieve high-quality white lighting due to its poor color rendering. Compared with YAG∶Ce

nitride phosphor La

∶Ce

(LSN∶Ce

) exhibits broader emission spectrum and better thermal quenching behavior. In this work

LSN∶Ce

PiG film was prepared on a blue-pass(BP) optical film coated high thermal conductivity sapphire substrate. The effects of sintering temperature

ratio of phosphor to glass powder(PtG)

film thickness

and BP optical film on the luminescence properties of final samples were studied. With the optimized synthetic process

LSN∶Ce

PiG film of excellent properties can be achieved at 800 ℃

1∶1 PtG ratio and 50 μm thickness. The sample could be excited by a blue-laser with high flux density up to 12.73 W/mm

and showed a luminous efficiency of 157.6 lm/W. Furthermore

the color rendering index of LSN∶Ce

PiG film can reach 74.9

which is 9% higher than that of YAG∶Ce

indicating great potential in high power laser lighting applications with high color rendering.

关键词

Keywords

references

NAKAMUR S , MUKAI T , SENOH M . Candela-class high-brightness InGaN/AlGaN double-heterostructure blue-light-emitting diodes [J]. Appl. Phys. Lett. , 1994 , 64 ( 13 ): 1687 - 1689 .

WANG L , XIE R J , SUEHIRO T , et al . Down-conversion nitride materials for solid state lighting: recent advances and perspectives [J]. Chem. Rev. , 2018 , 118 ( 4 ): 1951 - 2009 .

KIM M H , SCHUBERT M F , DAI Q , et al . Origin of efficiency droop in GaN-based light-emitting diodes [J]. Appl. Phys. Lett. , 2007 , 91 ( 18 ): 183507-1-3 .

CRAWFORD M H . LEDs for solid-state lighting: performance challenges and recent advances [J]. IEEE J. Sel. Top. Quantum Electron. , 2009 , 15 ( 4 ): 1028 - 1040 .

JR WIERER J J , TSAO J Y , SIZOV D S . Comparison between blue lasers and light-emitting diodes for future solid-state lighting [J]. Laser Photonics Rev. , 2013 , 7 ( 6 ): 963 - 993 .

WANG L , LU C M , LU J N , et al . Influence of carrier screening and band filling effects on efficiency droop of ingan light emitting diodes [J]. Opt. Express , 2011 , 19 ( 15 ): 14182 - 14187 .

胡盼 , 丁慧 , 刘永福 , 等 . YAG∶Ce3+在激光照明应用中的研究进展 [J]. 发光学报 , 2020 , 41 ( 12 ): 1504 - 1528 .

HU P , DING H , LIU Y F , et al . Recent progress of YAG∶Ce3+ for white laser diode lighting application [J]. Chin. J. Lumin. , 2020 , 41 ( 12 ): 1504 - 1528 . (in Chinese)

YAO Q , HU P , SUN P , et al . YAG∶Ce3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting [J]. Adv. Mater. , 2020 , 32 ( 19 ): 1907888-1-7 .

RAUKAS M , KELSO J , ZHENG Y , et al . Ceramic phosphors for light conversion in leds [J]. ECS J. Solid State Sci. Technol. , 2013 , 2 ( 2 ): R3168 - R3176 .

KOLODEZNYI E S , IVUKIN I N , SEREBRYAKOVA V S , et al . Thermal analysis of phosphor containing silicone layer in high power LEDs [J]. Mater. Phys. Mech. , 2014 , 21 ( 3 ): 283 - 287 .

ZHU Q Q , YANG P F , WANG Z Y , et al . Additive-free Y2O3∶Eu3+ red-emitting transparent ceramic with superior thermal conductivity for high-power UV LEDs and UV LDs [J]. J. Eur. Ceram. Soc. , 2020 , 40 ( 6 ): 2426 - 2431 .

ZHU Q Q , LI S X , YUAN Q , et al . Transparent YAG∶Ce ceramic with designed low light scattering for high-power blue LED and LD applications [J]. J. Eur. Ceram. Soc. , 2021 , 41 ( 1 ): 735 - 740 .

ZHU Q Q , MENG Y , ZHANG H , et al . YAGG∶Ce phosphor-in-YAG ceramic: an efficient green color converter suitable for high-power blue laser lighting [J]. ACS Appl. Electron. Mater. , 2020 , 2 ( 8 ): 2644 - 2650 .

CHEN D Q , XIANG W D , LIANG X J , et al . Advances in transparent glass-ceramic phosphors for white light-emitting diodes—a review [J]. J. Eur. Ceram. Soc. , 2015 , 35 ( 3 ): 859 - 869 .

LI S X , WANG L , HIROSAKI N , et al . Color conversion materials for high-brightness laser-driven solid-state lighting [J]. Laser Photonins Rev. , 2018 , 12 ( 12 ): 1800173-1-29 .

ZHONG J S , CHEN D Q , ZHOU Y , et al . Stable and chromaticity-tunable phosphor-in-glass inorganic color converter for high-power warm white light-emitting diode [J]. J. Eur. Ceram. Soc. , 2016 , 36 ( 7 ): 1705 - 1713 .

MOU Y , WANG H , LIANG D D , et al . Efficient and heat-conducting color converter of phosphor glass film printed on sapphire substrate for high-power white LEDs/LDs [J]. J. Non-Cryst. Solids , 2019 , 515 : 98 - 105 .

ZHENG P , LI S X , WANG L , et al . Unique color converter architecture enabling phosphor-in-glass(PiG) films suitable for high-power and high-luminance laser-driven white lighting [J]. ACS Appl. Mater. Interfaces , 2018 , 10 ( 17 ): 14930 - 14940 .

WEI R , WANG L , ZHENG P , et al . On the luminance saturation of phosphor-in-glass(PiG) films for blue-laser-driven white lighting: effects of the phosphor content and the film thickness [J]. J. Eur. Ceram. Soc. , 2019 , 39 ( 5 ): 1909 - 1917 .

ZHONG J Y , ZHUANG W D , XING X R , et al . Blue-shift of spectrum and enhanced luminescent properties of YAG∶Ce3+ phosphor induced by small amount of La3+ incorporation [J]. J. Alloys Compd. , 2016 , 674 : 93 - 97 .

WOIKE M , JEITSCHKO W . Preparation and crystal structure of the nitridosilicates Ln3Si6N11 (Ln=La, Ce, Pr, Nd, Sm) and LnSi3N5 (Ln=Ce, Pr, Nd) [J]. Inorg. Chem. , 1995 , 34 ( 21 ): 5105 - 5108 .

岳相铭 , 林航 , 林世盛 , 等 . La3Si6N11∶Ce3+荧光玻璃陶瓷及其在高功率固态照明中的应用 [J]. 发光学报 , 2020 , 41 ( 12 ): 1529 - 1537 .

YUE X M , LIN H , LIN S S , et al . La3Si6N11∶Ce3+ luminescent glass ceramics applicable to high-power solid-state lighting [J]. Chin. J. Lumin. , 2020 , 41 ( 12 ): 1529 - 1537 . (in Chinese)

YOU S H , LI S X , ZHENG P , et al . A thermally robust La3Si6N11∶Ce-in-glass film for high-brightness blue-laser-driven solid state lighting [J]. Laser Photonics Rev. , 2019 , 13 ( 2 ): 1800216-1-10 .

唐晋发 , 顾培夫 , 刘旭 , 等 . 现代光学薄膜技术 [M]. 杭州 : 浙江大学出版社 , 2006 .

TANG J F , GU P F , LIU X , et al . Modern Optical Thin Film Technology [M]. Hangzhou : Zhejiang University Press , 2006 . (in Chinese)

刘保剑 , 段微波 , 李大琪 , 等 . 退火温度对Ta2O5/SiO2多层反射膜结构和应力特性的影响 [J]. 物理学报 , 2019 , 68 ( 11 ): 114208-1-7 .

LIU B J , DUAN W B , LI D Q , et al . Effect of annealing temperature on structure and stress properties of Ta2O5/SiO2 multilayer reflective coatings [J]. Acta Phys. Sinica , 2019 , 68 ( 11 ): 114208-1-7 . (in Chinese)

KIM S , YIE H , CHOI S , et al . Pore characteristics for improving luminous efficacy of phosphor-in-glass [J]. Opt. Express , 2015 , 23 ( 24 ): A1499 - A1511 .

ZHANG R , LIN H , YU Y L , et al . A new-generation color converter for high-power white LED: transparent Ce3+∶YAG phosphor-in-glass [J]. J. Eur. Ceram. Soc. , 2014 , 8 ( 1 ): 158 - 164 .

王保柱 , 王晓亮 , 王晓燕 , 等 . 蓝宝石衬底上单晶InAlGaN外延膜的RF-MBE生长 [J]. 半导体学报 , 2006 , 27 ( 8 ): 1382 - 1385 .

WANG B Z , WANG X L , WANG X Y , et al . RF-MBE growth of InAlGaN epilayer on sapphire substrate [J]. Chin. J. Semicond. , 2006 , 27 ( 8 ): 1382 - 1385 . (in Chinese)

GAO X Y , WANG S Y , LI J , et al . Structural and optical investigation of GaN grown by met al-organic chemical vapor deposition [J]. J. Korean Phys. Soc. , 2004 , 44 ( 3 ): 765 - 768 .

ZHENG P , LI S X , WEI R , et al . Unique design strategy for laser-driven color converters enabling superhigh-luminance and high-directionality white light [J]. Laser Photonics Rev. , 2019 , 13 ( 10 ): 1900147-1-10 .

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Related Author

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Related Institution

College of Optics and Electronic Science and Technology， China Jiliang University

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