Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties

Dan ZHANG; Jie LIU; Dong SHI; Xin-yi ZHANG; Bao-xiang GAO; Ya-kai FENG; Xiang-kui REN

doi:10.37188/CJL.20210068

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Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties

Device Fabrication and Physics | 更新时间：2021-06-18

- Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties
  增强出版
- 发光学报 Vol. 42, Issue 6, Pages: 855-862(2021)
- 作者机构：
  
  1.天津大学化工学院化学工程联合国家重点实验室, 天津　 300350
  2.日本北海道大学全球软物质研究中心, 日本　札幌　 001-0021
  3.河北大学化学与环境科学学院, 河北保定　 071002
- 作者简介：
  
  [ "张丹(1995-)，女，山西兴县人，硕士研究生，2018年于天津科技大学获得学士学位，主要从事苝二酰亚胺有机小分子的合成与性质的研究。Email: zhangdannnn@tju.edu.cn" ]
  [ "任相魁(1980-)，男，河北邢台人，博士，副教授，2010年于南开大学获得博士学位，主要从事小分子及高分子材料的聚集态结构和性质的研究。Email: renxiangkui@tju.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(21875157;21304069);化学工程联合国家重点实验室开放课题(SKL-ChE-20B04);国家重点研发计划(2016YFC1100300)
- DOI：10.37188/CJL.20210068
  CLC： TP212.2
- Published：01 June 2021，
  
  Received：19 February 2021，
  
  Revised：04 March 2021，
- 稿件说明：
移动端阅览
DAN ZHANG, JIE LIU, DONG SHI, et al. Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties. [J]. 发光学报, 2021, 42(6): 855-862.
DOI：

DAN ZHANG, JIE LIU, DONG SHI, et al. Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties. [J]. 发光学报, 2021, 42(6): 855-862. DOI： 10.37188/CJL.20210068.

摘要

通过简单的一步反应合成了一种新型含硅氧烷基团的苝二酰亚胺(PDI-TES)荧光传感器. 结合小角X射线衍射、紫外-可见吸收光谱、荧光光谱和动态光散射等实验方法，阐明了PDI-TES的晶体结构、自组装行为和检测性能. 实验结果表明，PDI-TES具有良好的热稳定性和有序的晶体结构. 此外，由于Si—O键的断裂，PDI-TES对氟离子具有较高的选择性和灵敏度，检出限低至1.58×10

-6

mol/L. 这些优良的检测性能和简单、低成本的合成方法，有望使PDI-TES成为一种实用的氟离子检测荧光传感器.

Abstract

A novel perylene diimide(PDI) derivative bearing siloxane moieties(PDI-TES) was synthesized as fluorescent sensor by simple one-step reaction with high yield. The crystal structure

self-assembly behavior and detection property of the compound were then elucidated

via

a combination of different experimental techniques such as small-angle X-Ray scattering

UV-Vis absorption spectra

photoluminescence spectra and dynamic light scattering experiments. The experimental results reveal that PDI-TES has good thermal stability and ordered crystal structure. Moreover

due to the cleavage of Si—O bonds

PDI-TES exhibits high selectivity and sensitivity to F

with a detection limit as low as 1.58×10

-6

mol/L. These excellent detection performances

in combination with the simple and low-cost synthesis method

make PDI-TES a practical fluorescent sensor for detection of F

关键词

苝二酰亚胺荧光传感器硅氧烷氟离子

Keywords

perylene diimidefluorescent sensorsiloxanefluoride ions

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Related Author

Jie LIU

Dong SHI

Xinyi ZHANG

Baoxiang GAO

Yakai FENG

Xiangkui REN

Dan ZHANG

Related Institution

aSchool of Chemical Engineering and Technology， State Key Laboratory of Chemical Engineering，Tianjin University

bGlobal Station for Soft Matter GI-CoRE， Hokkaido University， Kita-ku， Sapporo

cCollege of Chemistry and Environmental Science， Hebei University

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