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1.天津大学化工学院 化学工程联合国家重点实验室, 天津 300350
2.日本北海道大学 全球软物质研究中心, 日本 札幌 001-0021
3.河北大学 化学与环境科学学院, 河北 保定 071002
[ "张丹(1995-),女,山西兴县人,硕士研究生,2018年于天津科技大学获得学士学位,主要从事苝二酰亚胺有机小分子的合成与性质的研究。Email: zhangdannnn@tju.edu.cn" ]
[ "任相魁(1980-),男,河北邢台人,博士,副教授,2010年于南开大学获得博士学位,主要从事小分子及高分子材料的聚集态结构和性质的研究。Email: renxiangkui@tju.edu.cn" ]
Received:19 February 2021,
Revised:04 March 2021,
Published:01 June 2021
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Dan ZHANG, Jie LIU, Dong SHI, et al. Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties[J]. 发光学报, 2021, 42(6): 855-862.
Dan ZHANG, Jie LIU, Dong SHI, et al. Fluorescent Sensor for Fluoride Ions Based on Perylene Diimide Tethered with Siloxane Moieties[J]. 发光学报, 2021, 42(6): 855-862. DOI: 10.37188/CJL.20210068.
通过简单的一步反应合成了一种新型含硅氧烷基团的苝二酰亚胺(PDI-TES)荧光传感器. 结合小角X射线衍射、紫外-可见吸收光谱、荧光光谱和动态光散射等实验方法,阐明了PDI-TES的晶体结构、自组装行为和检测性能. 实验结果表明,PDI-TES具有良好的热稳定性和有序的晶体结构. 此外,由于Si—O键的断裂,PDI-TES对氟离子具有较高的选择性和灵敏度,检出限低至1.58×10
-6
mol/L. 这些优良的检测性能和简单、低成本的合成方法,有望使PDI-TES成为一种实用的氟离子检测荧光传感器.
A novel perylene diimide(PDI) derivative bearing siloxane moieties(PDI-TES) was synthesized as fluorescent sensor by simple one-step reaction with high yield. The crystal structure
self-assembly behavior and detection property of the compound were then elucidated
via
a combination of different experimental techniques such as small-angle X-Ray scattering
UV-Vis absorption spectra
photoluminescence spectra and dynamic light scattering experiments. The experimental results reveal that PDI-TES has good thermal stability and ordered crystal structure. Moreover
due to the cleavage of Si—O bonds
PDI-TES exhibits high selectivity and sensitivity to F
-
with a detection limit as low as 1.58×10
-6
mol/L. These excellent detection performances
in combination with the simple and low-cost synthesis method
make PDI-TES a practical fluorescent sensor for detection of F
-
.
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