Luminescence Properties of Tm3+/Ho3+ Doped BaF2 Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm

Yan-qing FU; Shi-liang KANG; Shang-sheng GUAN; Yue-qi GUO; Dan CHEN; Xue-yun LIU; Tie-feng XU; Chang-gui LIN

doi:10.37188/CJL.20200310

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Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm

Synthesis and Properties of Materials | 更新时间：2021-01-12

- Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm
- Chinese Journal of Luminescence Vol. 42, Issue 1, Pages: 37-43(2021)
- 作者机构：
  
  1.宁波大学高等技术研究院红外材料及器件实验室, 浙江宁波 315211
  2.宁波海洋研究院, 浙江宁波 315211
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;National Natural Science Foundation of China;National Key Research and Development Program of China;National Key Research and Development Program of China;K. C. Wong Magna Fund in Ningbo University
- DOI：10.37188/CJL.20200310
  CLC： O482.31
- Received：18 October 2020，
  
  Accepted：2020-11-30，
  
  Published：2021-01
- 稿件说明：
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Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm[J]. Chinese journal of luminescence, 2021, 42(1): 37-43.
DOI：

Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm[J]. Chinese journal of luminescence, 2021, 42(1): 37-43. DOI： 10.37188/CJL.20200310.

摘要

由于在人眼安全、光电探测、中红外超连续谱产生等方面的应用，2.0 μm波段中红外激光器引起了人们越来越广泛的关注。本文采用熔融-淬冷法制备了含BaF

纳米晶、Tm

离子单掺及Ho

/Tm

共掺的85SiO

-7.5KF-7.5BaF

（SKB）玻璃陶瓷，表征了样品的拉曼光谱、吸收光谱、808 nm泵浦下在2.0 μm处的发光性能，得到了实验过程中Ho

/Tm

的最佳掺杂浓度。结果发现，Ho

、Tm

掺杂浓度均为1.0%时，2.0 μm处Ho

：

→

发射峰强度达到最大，并对Ho

和Tm

之间的能量转移机制进行了详细分析和讨论。研究表明，Tm

/Ho

共掺的BaF

纳米晶SiO

-KF-BaF

玻璃陶瓷有望成为2.0 μm波段中红外固体激光器的增益基质。

Abstract

2.0 μm band mid-infrared lasers have attracted more and more attention due to their applications in human eye safety

photoelectric detection

and generation of mid-infrared supercontinuum. In this paper

ion doped and Ho

/Tm

co-doped 85SiO

-7.5KF-7.5BaF

(SKB) glass containing BaF

nanocrystalline were prepared by melt-quenching method. The Raman spectrum

absorption spectrum and mid-infrared fluorescence performances of the samples at 2.0 μm exited by 808 nm laser diode were studied. The optimal doping concentration of Ho

/Tm

was obtained during the experiment. The measured fluorescence spectra manifest that the maximal emission intensity of Ho

→

at 2.0 μm can be achieved at the concentration of 1.0% Ho

and 1.0% Tm

in this component glass. Besides

the energy transfer mechanisms between Ho

and Tm

were also analyzed and discussed in detail. The results show that Tm

/Ho

co-doped SiO

-KF-BaF

glass ceramics can be used as the gain matrix for 2.0 μm band mid-infrared solid-state laser.

关键词

Keywords

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Related Institution

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