Luminescence Properties of Tm3+/Ho3+ Doped BaF2 Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm

Yan-qing FU; Shi-liang KANG; Shang-sheng GUAN; Yue-qi GUO; Dan CHEN; Xue-yun LIU; Tie-feng XU; Chang-gui LIN

doi:10.37188/CJL.20200310

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Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm

Synthesis and Properties of Materials | 更新时间：2021-01-12

- Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm
- Chinese Journal of Luminescence Vol. 42, Issue 1, Pages: 37-43(2021)
- 作者机构：
  
  1.宁波大学高等技术研究院红外材料及器件实验室, 浙江宁波 315211
  2.宁波海洋研究院, 浙江宁波 315211
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;National Natural Science Foundation of China;National Key Research and Development Program of China;National Key Research and Development Program of China;K. C. Wong Magna Fund in Ningbo University
- DOI：10.37188/CJL.20200310
  CLC： O482.31
- Published：2021-1，
  
  Received：18 October 2020，
  
  Accepted：30 November 2020
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Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm. [J]. Chinese Journal of Luminescence 42(1):37-43(2021)
DOI：

Yan-qing FU, Shi-liang KANG, Shang-sheng GUAN, et al. Luminescence Properties of Tm³⁺/Ho³⁺ Doped BaF₂ Nanocrystalline Fluorosilicate Glass Ceramics at 2.0 μm. [J]. Chinese Journal of Luminescence 42(1):37-43(2021) DOI： 10.37188/CJL.20200310.

摘要

由于在人眼安全、光电探测、中红外超连续谱产生等方面的应用，2.0 μm波段中红外激光器引起了人们越来越广泛的关注。本文采用熔融-淬冷法制备了含BaF

纳米晶、Tm

离子单掺及Ho

/Tm

共掺的85SiO

-7.5KF-7.5BaF

（SKB）玻璃陶瓷，表征了样品的拉曼光谱、吸收光谱、808 nm泵浦下在2.0 μm处的发光性能，得到了实验过程中Ho

/Tm

的最佳掺杂浓度。结果发现，Ho

、Tm

掺杂浓度均为1.0%时，2.0 μm处Ho

：

→

发射峰强度达到最大，并对Ho

和Tm

之间的能量转移机制进行了详细分析和讨论。研究表明，Tm

/Ho

共掺的BaF

纳米晶SiO

-KF-BaF

玻璃陶瓷有望成为2.0 μm波段中红外固体激光器的增益基质。

Abstract

2.0 μm band mid-infrared lasers have attracted more and more attention due to their applications in human eye safety

photoelectric detection

and generation of mid-infrared supercontinuum. In this paper

ion doped and Ho

/Tm

co-doped 85SiO

-7.5KF-7.5BaF

(SKB) glass containing BaF

nanocrystalline were prepared by melt-quenching method. The Raman spectrum

absorption spectrum and mid-infrared fluorescence performances of the samples at 2.0 μm exited by 808 nm laser diode were studied. The optimal doping concentration of Ho

/Tm

was obtained during the experiment. The measured fluorescence spectra manifest that the maximal emission intensity of Ho

→

at 2.0 μm can be achieved at the concentration of 1.0% Ho

and 1.0% Tm

in this component glass. Besides

the energy transfer mechanisms between Ho

and Tm

were also analyzed and discussed in detail. The results show that Tm

/Ho

co-doped SiO

-KF-BaF

glass ceramics can be used as the gain matrix for 2.0 μm band mid-infrared solid-state laser.

关键词

硅酸盐玻璃稀土离子掺杂2.0 μm发光BaF2中红外发光

Keywords

silicate glassrare earth ion doped2.0 μm fluorescenceBaF2mid-infrared emission

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Related Author

Chang-gui LIN

Xue-yun LIU

Dan CHEN

Yue-qi GUO

Shang-sheng GUAN

Shi-liang KANG

Yan-qing FU

Tie-feng XU

Related Institution

Laboratory of Infrared Materials and Devices， Research Institute of Advanced Technologies， Ningbo University

School of Material Science and Engineering, Tongji University

Key Laboratory of Advernced Civil Engineering Materials of Ministry of Education, Tongji University

Key Laboratory of Excited State Physics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

Laboratory of Photoelectric Materials, Ningbo University

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