Effect of Defect Structure on Thermal Stability of Fluorescent Materials for LED Applications

Chao WANG; Rong-bin WANG; Hao ZHANG; Zhi-chao LIU; Xiu-xia YANG; Hong-yu LYU; Yi-yu CAI; Xue YU; Jian-bei QIU; Xu-hui XU

doi:10.37188/CJL.20200254

您当前的位置：

首页 >

文章列表页 >

Effect of Defect Structure on Thermal Stability of Fluorescent Materials for LED Applications

Invited Paper | 更新时间：2020-12-10

- Effect of Defect Structure on Thermal Stability of Fluorescent Materials for LED Applications
- Chinese Journal of Luminescence Vol. 41, Issue 12, Pages: 1554-1566(2020)
- 作者机构：
  
  昆明理工大学材料科学与工程学院, 云南昆明 650093
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;National Natural Science Foundation of China;Yunnan Ten Thousand Talents Plan Young & Elite Talents Project;Yunnan Ten Thousand Talents Plan Young & Elite Talents Project
- DOI：10.37188/CJL.20200254
  CLC： O482.31
- Received：24 August 2020，
  
  Accepted：2020-9-14，
  
  Published：2020-12
- 稿件说明：
移动端阅览
Chao WANG, Rong-bin WANG, Hao ZHANG, et al. Effect of Defect Structure on Thermal Stability of Fluorescent Materials for LED Applications[J]. Chinese journal of luminescence, 2020, 41(12): 1554-1566.
DOI：

Chao WANG, Rong-bin WANG, Hao ZHANG, et al. Effect of Defect Structure on Thermal Stability of Fluorescent Materials for LED Applications[J]. Chinese journal of luminescence, 2020, 41(12): 1554-1566. DOI： 10.37188/CJL.20200254.

摘要

稀土或过渡金属离子掺杂荧光材料因其环保、易于制备、高效率、低成本、长发光寿命、全光谱、高亮度等性能在多重防伪、光学信息存储、温度传感等众多领域具有广泛的应用，特别是在LED照明领域。然而，荧光材料热稳定性差是阻碍其快速发展的核心问题。近年来，关于在热扰动作用下，缺陷态对载流子的俘获及释放过程，作为抑制LED用荧光材料热猝灭效应的有效途径被广泛研究。本文主要概述了LED用荧光材料中缺陷态对其热稳定性影响的研究现状，以及缺陷态作为陷阱中心对载流子的俘获、释放及其抑制LED用荧光材料热猝灭效应的机理，并对当前研究中存在的问题进行了总结和展望。

Abstract

Rare earth or transition metal ions doped into fluorescent materials have a wide range of applications

such as multiple anti-counterfeiting

optical information storage

temperature sensing and other fields because of its environmental protection

easy preparation

high efficiency

low cost

long luminous life

full spectrum

high brightness

especially in the LED lighting field. However

the poor thermal stability of fluorescent materials is still a significantly challenge

which limits its rapidly applied development

particularly in the high temperature environments. Recently

under the excited of thermal disturbance

the capture and release processes of carriers from defect structure have been widely studied as an effective way to suppress the thermal quenching effect of fluorescent materials. This paper mainly focused on the summaries on the effect of the defect structures on the thermal stabilities of the fluorescent material. Besides

the influence of the defects structures

acting as the trapping centers

on the capturing and releasing processes of carriers

and the suppressing process of thermal quenching phenomenon are also summarized. Finally

the above critical issues in the current research are summarized and prospected.

关键词

Keywords

references

AZEVEDO I L, MORGAN M G, MORGAN F. The transition to solid-state lighting[J]. Proc. IEEE , 2009, 97(3):481-510.

TIAN Y C. Development of phosphors with high thermal stability and efficiency for phosphor-converted LEDs[J]. J. Solid State Light. , 2014, 1(1):11.

HERMUS M, PHAN P C, DUKE A C, et al .. Tunable optical properties and increased thermal quenching in the blue-emitting phosphor series:Ba 2 (Y 1- x Lu x ) 5 B 5 O 17 :Ce 3+ ( x =0-1)[J]. Chem. Mater. , 2017, 29(12):5267-5275.

ZHU Y L, LIANG Y J, LIU S Q, et al .. Narrow-band green-emitting Sr 2 MgAl 22 O 36 :Mn 2+ phosphors with superior thermal stability and wide color gamut for backlighting display applications[J]. Adv. Opt. Mater. , 2019, 7(6):1801419-1-9.

张斌. GaN基LED材料特性研究及芯片结构设计[D].武汉: 华中科技大学, 2008.

ZHANG B. Research of Material Characteristic of GAN Based LED and Design of Chip Structure [D]. Wuhan: Huazhong University of Science and Technology, 2008. (in Chinese)

ZHANG L Q, YANG X L, JIANG Q, et al .. Ultra-bright and highly efficient inorganic based perovskite light-emitting diodes[J]. Nat. Commun. , 2017, 8:15640-1-8.

VISHWAKARMA P K, SHAHI P K, RAI S B, et al .. Low temperature optical sensor based on non-thermally coupled level of Ho 3+ and defect level of Zn 2+ in Yb 3+ :Y 2 TI 2 O 7 phosphor[J]. J. Phys. Chem. Solids , 2020, 142:109445.

BACK M, UEDA J, XU J, et al .. Effective ratiometric luminescent thermal sensor by Cr 3+ -doped mullite Bi 2 Al 4 O 9 with robust and reliable performances[J]. Adv. Opt. Mater. , 2020, 8(11):2000124.

ZHU C C, LONG Z W, WANG Q, et al .. Insights into anti-thermal quenching of photoluminescence from SrCaGa 4 O 8 based on defect state and application in temperature sensing[J]. J. Lumin. , 2019, 208:284-289.

FANG S Q, LANG T C, HAN T, et al .. Zero-thermal-quenching of Mn 4+ far-red-emitting in LaAlO 3 perovskite phosphor via energy compensation of electrons' traps[J]. Chem. Eng. J. , 2020, 389:124297.

WANG B, WANG H W, HUANG J H, et al .. Trap distribution and photo-stimulated luminescence in LaSrAl 3 O 7 :Eu 2+ long-lasting phosphors for optical data storage[J]. J. Am. Ceram. Soc. , 2020, 103(1):315-323.

刘志超. LED用荧光材料在缺陷态辅助下的热稳定性机理研究[D].昆明: 昆明理工大学, 2019.

LIU Z C. Study on The Thermal Stability Mechanism of Fluorescent Materials for Led with The Assist of Defect State [D]. Kunming: Kunming University of Science and Technology, 2019. (in Chinese)

LIU D, JIN Y H, LV Y, et al .. A single-phase full-color emitting phosphor Na 3 Sc 2 (PO 4 ) 3 :Eu 2+ /Tb 3+ /Mn 2+ with near-zero thermal quenching and high quantum yield for near-UV converted warm w-LEDs[J]. J. Am. Ceram. Soc. , 2018, 101(12):5627-5639.

SHI R, NING L X, WANG Z Q, et al .. Zero-thermal quenching of Mn 2+ red luminescence via efficient energy transfer from Eu 2+ in BaMgP 2 O 7 [J]. Adv. Opt. Mater. , 2019, 7(23):1901187.

QIAO J W, ZHAO J, LIU Q L. Recent advances in solid-state LED phosphors with thermally stable luminescence[J]. J. Rare Earths , 2019, 37(6):565-572.

DUKE A C, HARIYANI S, BRGOCH J. Ba 3 Y 2 B 6 O 15 :Ce 3+ —a high symmetry, narrow-emitting blue phosphor for wide-gamut white lighting[J]. Chem. Mater. , 2018, 30(8):2668-2675.

XIA Z G, MOLOKEEV M S, BIN W B, et al .. Crystal structure and photoluminescence evolution of La 5 (Si 2+ x B 1- x )(O 13- x N x ):Ce 3+ solid solution phosphors[J]. J. Phys. Chem . C, 2015, 119(17):9488-9495.

DENAULT K A, BRGOCH J, KLO S F, et al .. Average and local structure, Debye temperature, and structural rigidity in some oxide compounds related to phosphor hosts[J]. ACS Appl. Mater. Interfaces , 2015, 7(13):7264-7272.

XIA Z G, LIU Q L. Progress in discovery and structural design of color conversion phosphors for LEDs[J]. Prog. Mater. Sci. , 2016, 84:59-117.

WEI Y, CAO L, LV L M, et al .. Highly efficient blue emission and superior thermal stability of BaAl 12 O 19 :Eu 2+ phosphors based on highly symmetric crystal structure[J]. Chem. Mater. , 2018, 30(7):2389-2399.

FAN X T, CHEN W B, XIN S Y, et al .. Achieving long-term zero-thermal-quenching with the assistance of carriers from deep traps[J]. J. Mater. Chem . C, 2018, 6(12):2978-2982.

KANG F W, PENG M Y, ZHANG Q Y, et al .. Abnormal anti-quenching and controllable multi-transitions of Bi 3+ luminescence by temperature in a yellow-emitting LuVO 4 :Bi 3+ phosphor for UV-converted white LEDs[J]. Chem.-Eur. J. , 2014, 20(36):11522-11530.

LIU Z C, ZHAO L, CHEN W B, et al .. Effects of the deep traps on the thermal-stability property of CaAl 2 O 4 :Eu 2+ phosphor[J]. J. Am. Ceram. Soc. , 2018, 101(8):3480-3488.

SHAO Q Y, LIN H Y, DONG Y, et al .. Thermostability and photostability of Sr 3 SiO 5 :Eu 2+ phosphors for white LED applications[J]. J. Solid State Chem. , 2015, 225:72-77.

KIM Y H, ARUNKUMAR P, KIM B Y, et al .. A zero-thermal-quenching phosphor[J]. Nat. Mater. , 2017, 16(5):543-550.

LIN C C, TSAI Y T, JOHNSTON H E, et al .. Enhanced photoluminescence emission and thermal stability from introduced cation disorder in phosphors[J]. J. Am. Chem. Soc. , 2017, 139(34):11766-11770.

QIAO J W, NING L X, MOLOKEEV M S, et al .. Eu 2+ site preferences in the mixed cation K 2 BaCa(PO 4 ) 2 and thermally stable luminescence[J]. J. Am. Chem. Soc. , 2018, 140(30):9730-9736.

LI H M, CAI J Z, PANG R, et al .. A strategy for developing thermal-quenching-resistant emission and super-long persistent luminescence in BaGa 2 O 4 :Bi 3+ [J]. J. Mater. Chem . C, 2019, 7(42):13088-13096.

WEI Q, DING J Y, WANG Y H. A novel tunable extra-broad yellow-emitting nitride phosphor with zero-thermal-quenching property[J]. Chem. Eng. J. , 2020, 386:124004.

ZHANG B B, CHEN J K, MA J P, et al .. Antithermal quenching of luminescence in zero-dimensional hybrid metal halide solids[J]. J. Phys. Chem. Lett. , 2020, 11(8):2902-2909.

MONDAL N, DE A, SAMANTA A. Achieving near-unity photoluminescence efficiency for blue-violet-emitting perovskite nanocrystals[J]. ACS Energy Lett. , 2019, 4(1):32-39.

MA J P, CHEN Y M, ZHANG L M, et al .. Insights into the local structure of dopants, doping efficiency, and luminescence properties of lanthanide-doped CsPbCl 3 perovskite nanocrystals[J]. J. Mater. Chem . C, 2019, 7(10):3037-3048.

ZHONG J Y, ZHUO Y, HARIYANI S, et al .. Closing the cyan gap toward full-spectrum LED lighting with NaMgBO 3 :Ce 3+ [J]. Chem. Mater. , 2020, 32(2):882-888.

YU X, WANG S B, ZHU Y C, et al .. High-temperature long persistent and photo-stimulated luminescence in Tb 3+ doped gallate phosphor[J]. J. Alloys Compd. , 2017, 701:774-779.

LIN H H, BAI G X, YU T, et al .. Site occupancy and near-infrared luminescence in Ca 3 Ga 2 Ge 3 O 12 :Cr 3+ persistent phosphor[J]. Adv. Opt. Mater. , 2017, 5(18):1700227.

LINS P, XIONG C W, MA D C, et al .. Persistent luminescence found in Mg 2+ and Pr 3+ co-doped LiNbO 3 single crystal[J]. J. Mater. Chem . C, 2018, 37(6):10067-10072.

WANG Z Z, SONG Z, NING L X, et al .. Enhanced yellow persistent luminescence in Sr 3 SiO 5 :Eu 2+ through Ge incorporation[J]. Inorg. Chem. , 2019, 58(13):8694-8701.

WANG Z Z, SONG Z, NING L X, et al .. Sunlight-activated yellow long persistent luminescence from Nb-doped Sr 3 SiO 5 :Eu 2+ for warm-color mark applications[J]. J. Mater. Chem . C, 2020, 8(3):1143-1150.

QU B Y, ZHANG B, WANG L, et al .. Mechanistic study of the persistent luminescence of CaAl 2 O 4 :Eu, Nd[J]. Chem. Mater. , 2015, 27(6):2195-2202.

SUN W Z, PANG R, LI H M, et al .. Investigation of a novel color tunable long afterglow phosphor KGaGeO 4 :Bi 3+ :luminescence properties and mechanism[J]. J. Mater. Chem . C, 2017, 5(6):1346-1355.

KATAYAMA Y, VIANA B, GOURIER D, et al .. Photostimulation induced persistent luminescence in Y 3 Al 2 Ga 3 O 12 :Cr 3+ [J]. Opt. Mater. Express , 2016, 6(4):1405-1413.

SONG Z, WANG Z Z, HE L Z, et al .. After-glow, luminescent thermal quenching, and energy band structure of Ce-doped yttrium aluminum-gallium garnets[J]. J. Lumin. , 2017, 192:1278-1287.

XU J, JU Z H, YANG X J, et al .. Considerable improvement of Na 2 CaSn 2 Ge 3 O 12 :Eu 3+ reddish orange long-persistent phosphorescence with co-doping of Dy 3+ [J]. Dyes Pigm. , 2019, 162:951-958.

UEDA J, HASHIMOTO A, TANABE S. Orange persistent luminescence and photodarkening related to paramagnetic defects of nondoped CaO-Ga 2 O 3 GeO 2 glass[J]. J. Phys. Chem . C, 2019, 123(49):29946-29953.

HU R, ZHANG Y, ZHAO Y, et al .. UV-Vis-NIR broadband-photostimulated Luminescence of LiTaO 3 :Bi 3+ long-persistent phosphor and the optical storage properties[J]. Chem. Eng. J. , 2020, 392:124807.

WANG F X, GUO J Z, WANG S X, et al .. Yellow persistent luminescence and electronic structure of Ca-α-Sialon:Eu 2+ [J]. J. Alloys Compd. , 2020, 821:153482.

ZHANG S Y, SONG Z, WANG S X, et al .. Red persistent and photostimulable phosphor SrLiAl 3 N 4 :Eu 2+ [J]. J. Mater. Chem . C, 2020, 8(14):4956-4964.

ZHOU X F, GENG W Y, LI J Y, et al .. An ultraviolet-visible and near-infrared-responded broadband NIR phosphor and its NIR spectroscopy application[J]. Adv. Opt. Mater. , 2020, 8(8):1902003.

Views

486

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Luminescence Properties and Thermal Stability of Sm³⁺, Eu³⁺Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor

Near-infrared Phosphor BaY₂Al₂Ga₂SiO₁₂∶Cr³⁺ with Excellent Thermal Stability and Considerable Quantum Efficiency

Advances in Relationship Between Lattice Defects and Luminescent Characteristics

Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺

Related Author

Chao Wang

Rongbin Wang

Hao Zhang

Zhichao Liu

Xiuxia Yang

Hongyu Lv

Yiyu Cai

xue Yu

Related Institution

Faculty of Materials Science and Engineering Kunming University of Science and Technology

School of Physics， Nankai University

School of Applied Chemistry and Engineering， University of Science and Technology of China

State Key Laboratory of Rare Earth Resource Utilization， Changchun Institute of Applied Chemistry， Chinese Academy of Sciences

School of Electronic Information and Optical Engineering， Nankai University

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰