Research Progress of Gd3Al5O12-based Luminescent Materials

Bing-guo XUE; Qing-yang LYU; Ting-ting Wang; Li-na LIU; Shi-li WANG; Hai-cheng ZHU; Shao-hong LIU; Xu-dong SUN

doi:10.37188/CJL.20200237

您当前的位置：

首页 >

文章列表页 >

Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials

Invited Paper | 更新时间：2020-12-10

- Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials
- Chinese Journal of Luminescence Vol. 41, Issue 12, Pages: 1538-1553(2020)
- 作者机构：
  
  东北大学材料科学与工程学院, 辽宁沈阳 110819
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;the Fundamental Research Funds for the Central Universities
- DOI：10.37188/CJL.20200237
  CLC： O482.31
- Received：05 August 2020，
  
  Accepted：31 August 2020，
  
  Published：2020-12
- 稿件说明：
移动端阅览
Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials[J]. Chinese Journal of Luminescence, 2020, 41(12): 1538-1553.
DOI：

Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials[J]. Chinese Journal of Luminescence, 2020, 41(12): 1538-1553. DOI： 10.37188/CJL.20200237.

摘要

钆铝石榴石（Gd

，GdAG）是性能优异的发光基质材料，但其在高温煅烧时易发生分解，导致得到纯相GdAG基发光材料比较困难。近年来，研究证实通过小半径

（

=Y，Lu，Tb）取代部分Gd

，或通过离子半径更大的

来取代Al的位置扩大十二面体间隙，可以稳定GdAG晶格，得到纯相GdAG基发光材料。本文综述了GdAG基发光材料在晶格稳定化、下转换发光、上转换发光等方面的研究进展，并探讨了GdAG基单晶、薄膜和陶瓷的制备、性能及其在射线探测和医学成像等领域的应用前景。

Abstract

Gadolinium aluminum garnet(Gd

GdAG) is an excellent luminescent host material. But GdAG is easy to decompose during high temperature calcination

which makes it difficult to obtain a pure phase GdAG-based luminescent material. In recent years

research has confirmed that substituting the smaller radius

(

Tb) for part of Gd

or replacing the Al

with the larger radius

to expand the dodecahedral gap

can stabilize the GdAG lattice and thus obtain a pure phase GdAG-based luminescent material. This article reviews the research progress of GdAG-based luminescent materials including the lattice stabilization

down-conversion luminescence

and up-conversion luminescence

and also discusses the preparation and performances of GdAG-based single crystals

thin films and ceramics

and their applications in radiological detection and medical imaging.

关键词

Keywords

references

陈积阳, 施鹰, 冯涛, 等.闪烁陶瓷及其在医学X-CT上的应用[J].硅酸盐学报, 2004, 32(7):868-872.

CHEN J Y, SHI Y, FENG T, et al .. Scintillation ceramics and their application on medical X-CT[J]. J. Chin. Ceram. Soc ., 2004, 32(7):868-872. (in Chinese)

FENG X Q. Anti-site defects in YAG and LuAG crystals[J]. J. Inorg. Mater ., 2010, 25(8):785-794.

GEUSIC J E, MARCOS H M, VAN UITERT L G. Laser oscillations in Nd-doped yttrium aluminum, yttrium gallium and gadolinium garnets[J]. Appl. Phys. Lett ., 1964, 4(10):182-184.

汪超, 任国浩.石榴石系列闪烁晶体的研究进展[J].硅酸盐学报, 2015, 43(7):882-891.

WANG C, REN G H. Recent studies on garnet scintillation crystals[J]. J. Chin. Ceram. Soc ., 2015, 43(7):882-891. (in Chinese)

李会利, 刘学建, 黄莉萍.固相反应法制备Ce:LuAG透明陶瓷[J].无机材料学报, 2006, 21(5):1161-1166.

LI H L, LIU X J, HUANG L P. Fabrication of transparent Ce:LuAG ceramics by a solid-state reaction method[J]. J. Inorg. Mater ., 2006, 21(5):1161-1166. (in Chinese)

BLASSE G, BRIL A. Investigation of some Ce 3+ -activated phosphors[J]. J. Chem. Phys ., 1967, 47(12):5139-5145.

BOUKERIKA A, GUERBOUS L, CHELEF H, et al .. Preparation and characterization of bright high quality YAG:Eu 3+ thin films grown by sol-gel dip-coating technique[J]. Thin Solid Films , 2019, 683:74-81.

LI J G, LI X D, SUN X D, et al .. Monodispersed colloidal spheres for uniform Y 2 O 3 :Eu 3+ red-phosphor particles and greatly enhanced luminescence by simultaneous Gd 3+ doping[J]. J. Phys. Chem. C, 2008, 112(31):11707-11716.

LI J G, LI X D, SUN X D, et al .. Uniform colloidal spheres for (Y 1- x Gd x ) 2 O 3 ( x =0-1):formation mechanism, compositional impacts, and physicochemical properties of the oxides[J]. Chem. Mat ., 2008, 20(6):2274-2281.

LI Y H, HONG G Y. Synthesis and luminescence properties of nanocrystalline Gd 2 O 3 :Eu 3+ by combustion process[J]. J. Lumin ., 2007, 124(2):297-301.

DENG Y, FOWLKES J D, FITZ-GERALD J M, et al .. Combinatorial thin film synthesis of Gd-doped Y 3 Al 5 O 12 ultraviolet emitting materials[J]. Appl. Phys . A, 2005, 80(4):787-789.

DENG Y, FOWLKES J D, RACK P D, et al .. Thin film RF magnetron sputtering of gadolinium-doped yttrium aluminum garnet ultraviolet emitting materials[J]. Opt. Mater ., 2006, 29(2-3):183-191.

NISHIURA S, TANABE S, FUJIOKA K, et al .. Preparation of transparent Ce 3+ :GdYAG ceramics phosphors for white LED[J]. IOP Conf. Ser.:Mater. Sci. Eng ., 2011, 18:102005.

KUČERA M, NIKL M, HANUŠ M, et al .. Gd 3+ to Ce 3+ energy transfer in multi-component GdLuAG and GdYAG garnet scintillators[J]. Phys. Status Solidi R. Res. Lett ., 2013, 7(8):571-574.

MIZUNO M, YAMADA T, NOGUCHI T. Phase diagrams of the systems Al 2 O 3 -Eu 2 O 3 and Al 2 O 3 -Gd 2 O 3 at high temperatures[J]. Yogyo-Kyokai-Shi , 1977, 85(11):543-548.

MIZUNO M, YAMADA T. Phase diagram of the system Ga 2 O 3 -Sm 2 O 3 at high temperatures[J]. J. Ceram. Soc. Jpn. , 1989, 97(1131):1334-1338.

MIZUNO M, YAMADA T, NOGUCHI T. Phase diagram of the system Al 2 O 3 -Dy 2 O 3 at high temperatures[J]. J. Ceram. Soc. Jpn. , 1979, 86(8):360-364.

SHISHIDO T, OKAMURA K, YAJIMA S. Gd 3 Al 5 O 12 phase obtained by crystallization of amorphous Gd 2 O 3 ·5/3Al 2 O 3 [J]. J. Am. Ceram. Soc ., 1978, 61(7-8):373-375.

LI J K, LI J G, ZHANG Z J, et al .. Gadolinium aluminate garnet (Gd 3 Al 5 O 12 ):crystal structure stabilization via lutetium doping and properties of the (Gd 1- x Lu x ) 3 Al 5 O 12 solid solutions ( x =0-0.5)[J]. J. Am. Ceram. Soc ., 2012, 95(3):931-936.

CHAUDHURY S, PARIDA S C, PILLAI K, et al .. High-temperature X-ray diffraction and specific heat studies on GdAlO 3 , Gd 3 Al 5 O 12 and Gd 4 Al 2 O 9 [J]. J. Solid State Chem ., 2007, 180(8):2393-2399.

XIA Z G, MEIJERINK A. Ce 3+ -doped garnet phosphors:composition modification, luminescence properties and applications[J]. Chem. Soc. Rev ., 2017, 46(1):275-299.

WANG W Z, LI J K, TENG X, et al .. Luminescence properties of Y 3+ stabilized Gd 3 Al 5 O 12 :Tb 3+ /Ce 3+ phosphors with yellow light-emitting for warm white LEDs[J]. J. Lumin ., 2018, 202:176-185.

NAZAROV M, NOH D Y, SOHN J, et al .. Influence of additional Eu 3+ coactivator on the luminescence properties of Tb 3 Al 5 O 12 :Ce 3+ , Eu 3+ [J]. Opt. Mater ., 2008, 30(9):1387-1392.

ZORENKO Y, GORBENKO V, VOZNYAK T, et al .. Luminescence and Tb 3+ -Ce 3+ -Eu 3+ ion energy transfer in single-crystalline films of Tb 3 Al 5 O 12 :Ce, Eu garnet[J]. J. Lumin ., 2008, 128(4):652-660.

LI J K, LI J G, WU X L, et al .. Crystal structure stabilization of gadolinium aluminum garnet (Gd 3 Al 5 O 12 ) and photoluminescence properties[J]. Key Eng. Mater ., 2013, 544:245-251.

CHIANG C C, TSAI M S, HON M H. Preparation of cerium-activated GAG phosphor powders influence of co-doping on crystallinity and luminescent properties[J]. J. Electrochem. Soc ., 2007, 154(10):J326-J329.

苑航, 陈宇潇, 王英杰, 等.无机闪烁体钆镓铝石榴石(GAGG)的性能研究及应用[J].现代工业经济和信息化, 2018, 8(11):24-26.

YUAN H, CHEN Y X, WANG Y J, et al .. Inorganic scintillator gadolinium gallium aluminum garnet(GAGG)'s performance research and application[J]. Mod. Ind. Econ. Inform ., 2018, 8(11):24-26. (in Chinese)

OGIEGłO J M, KATELNIKOVAS A, ZYCH A, et al .. Luminescence and luminescence quenching in Gd 3 (Ga, Al) 5 O 12 scintillators doped with Ce 3+ [J]. J. Phys. Chem. A, 2013, 117(12):2479-2484.

CAO Q, HE L N, FENG X J, et al .. Effect of annealing on the structural and optical properties of β -Ga 2 O 3 films prepared on gadolinium gallium garnet (110) by MOCVD[J]. Ceram. Int ., 2018, 44(1):830-835.

PIAO R Q, XU Q, ZHANG Z B, et al .. A study on ratiometric thermometry based on upconversion emissions of erbium ions in gadolinium gallium garnet single-crystal[J]. J. Lumin ., 2018, 204:116-121.

RONDA C. Luminescent materials with quantum efficiency larger than 1, status and prospects[J]. J. Lumin ., 2002, 100(1-4):301-305.

LI J G, SAKKA Y. Recent progress in advanced optical materials based on gadolinium aluminate garnet (Gd 3 Al 5 O 12 )[J]. Sci. Technol. Adv. Mater ., 2015, 16(1):014902-1-18.

DORENBOS P. The 5d level positions of the trivalent lanthanides in inorganic compounds[J]. J. Lumin ., 2000, 91(3-4):155-176.

WU J L, GUNDIAH G, CHEETHAM A K. Structure-property correlations in Ce-doped garnet phosphors for use in solid state lighting[J]. Chem. Phys. Lett ., 2007, 441(4-6):250-254.

DOTSENKO V P, BEREZOVSKAYA I V, VOLOSHINOVSKII A S, et al .. Luminescence properties and electronic structure of Ce 3+ -doped gadolinium aluminum garnet[J]. Mater. Res. Bull ., 2015, 64:151-155.

BACHMANN V M. Studies on Luminescence and Quenching Mechanisms in Phosphors for Light Emitting Diodes [D]. Netherlands: Utrecht University, 2007.

JOSHI C, YADAV P, MOHARIL S V. Improved white light emitting diode characteristics by coating GdAG:Ce phosphor[J]. Trans. Electr. Electron. Mater , 2014, 15(2):69-72.

LI J K, LI J G, LIU S H, et al .. The development of Ce 3+ -activated (Gd, Lu) 3 Al 5 O 12 garnet solid solutions as efficient yellow-emitting phosphors[J]. Sci. Technol. Adv. Mater ., 2013, 14(5):054201-1-9.

JAIN A, KOYANI R, MUñOZ C, et al .. Blue light triggered generation of reactive oxygen species from silica coated Gd 3 Al 5 O 12 :Ce 3+ nanoparticles loaded with rose Bengal[J]. Data Brief , 2018, 20:1023-1028.

JAIN A, KOYANI R, MUÑOZ C, et al .. Magnetic-luminescent cerium-doped gadolinium aluminum garnet nanoparticles for simultaneous imaging and photodynamic therapy of cancer cells[J]. J. Colloid Interface Sci ., 2018, 526:220-229.

CASTILLO R R, VALLET-REGÍ M. Functional mesoporous silica nanocomposites:biomedical applications and biosafety[J]. Int. J. Mol. Sci ., 2019, 20(4):929-1-30.

DENG Z H, CHEN J, LIU Z G, et al .. Structure, chemical state and luminescent properties of Ce, Gd:YAG transparent ceramic for flip-chip white LED application[J]. Chin. J. Struct. Chem ., 2018, 37(6):948-954.

LI M J, WU Y C, YEN F S, et al .. Influence of ionic mobility on the phase transformation route in Y 3 Al 5 O 12 (YAG) stoichiometry[J]. J. Eur. Ceram. Soc ., 2011, 31(12):2099-2106.

XIAO W G, LIU X F, ZHANG J H, et al .. Realizing visible light excitation of Tb 3+ via highly efficient energy transfer from Ce 3+ for LED-based applications[J]. Adv. Opt. Mater ., 2019, 7(9):1801677.

HERNÁNDEZ-ADAME L, MÉNDEZ-BLAS A, RUIZ-GARCÍA J, et al .. Synthesis, characterization, and photoluminescence properties of Gd:Tb oxysulfide colloidal particles[J]. Chem. Eng. J ., 2014, 258:136-145.

TENG X, LI J K, DUAN G B, et al .. Development of Tb 3+ activated gadolinium aluminate garnet (Gd 3 Al 5 O 12 ) as highly efficient green-emitting phosphors[J]. J. Lumin ., 2016, 179:165-170.

GUO K, HUANG M L, CHEN H H, et al .. Comparative study on photoluminescence of amorphous and nano-crystalline YAG:Tb phosphors prepared by a combustion method[J]. J. Non-Cryst. Solids , 2012, 358(1):88-92.

PARK J Y, JUNG H C, RAJU G S R, et al .. Solvothermal synthesis and luminescence properties of Tb 3+ -doped gadolinium aluminum garnet[J]. J. Lumin ., 2010, 130(3):478-482.

Hertle E, Chepyga L, Batentschuk M, et al .. Influence of codoping on the luminescence properties of YAG:Dy for high temperature phosphor thermometry[J]. J. Lumin ., 2017, 182:200-207.

ISHIWADA N, FUJII E, YOKOMORI T. Evaluation of Dy-doped phosphors (YAG:Dy, Al 2 O 3 :Dy, and Y 2 SiO 5 :Dy) as thermographic phosphors[J]. J. Lumin ., 2018, 196:492-497.

HASHEMI A, VETTER A, JOVICIC G, et al .. Temperature measurements using YAG:Dy and YAG:Sm under diode laser excitation (405 nm)[J]. Meas. Sci. Technol ., 2015, 26(7):075202.

LI J K, LI J G, LIU S H, et al .. Greatly enhanced Dy 3+ emission via efficient energy transfer in gadolinium aluminate garnet (Gd 3 Al 5 O 12 ) stabilized with Lu 3+ [J]. J. Mater. Chem. C, 2013, 1(45):7614-7622.

HERTLE E E, CHEPYGA L, OSVET A, et al .. (Gd, Lu)AlO 3 :Dy 3+ and (Gd, Lu) 3 Al 5 O 12 :Dy 3+ as high-temperature thermographic phosphors[J]. Meas. Sci. Technol ., 2019, 30(3):034001.

RYBA-ROMANOWSKI W, KOMAR J, NIEDŹWIEDZKI T, et al .. Excited state relaxation dynamics and up-conversion phenomena in Gd 3 (Al, Ga) 5 O 12 single crystals co-doped with holmium and ytterbium[J]. J. Lumin ., 2016, 656:573-580.

NIEDŹWIEDZKI T, RYBA-ROMANOWSKI W, KOMAR J, et al .. Excited state relaxation dynamics and up-conversion phenomena in Gd 3 (Al, Ga) 5 O 12 single crystals co-doped with erbium and ytterbium[J]. J. Lumin ., 2016, 177:219-227.

KOMAR J, SOLARZ P, JEOWSKI A, et al .. Investigation of intrinsic and extrinsic defects in solid solution Gd 3 (Al, Ga) 5 O 12 crystals grown by the Czochralski method[J]. J. Alloys Compd ., 2016, 688:96-103.

LI J K, LI J G, LI J, et al .. Photoluminescent properties of new up-conversion phosphors of Yb/Tm co-doped (Gd 1- x -Lu x ) 3 Al 5 O 12 ( x =0.1-0.5) garnet solid solutions[J]. J. Alloys Compd ., 2014, 582:623-627.

BOHACEK P, KRASNIKOV A, KUČERA M, et al .. Defects creation in the undoped Gd 3 (Ga, Al) 5 O 12 single crystals and Ce 3+ -doped Gd 3 (Ga, Al) 5 O 12 single crystals and epitaxial films under irradiation in the Gd 3+ -related absorption bands[J]. Opt. Mater ., 2019, 88:601-605.

KAMADA K, YANAGIDA T, PEJCHAL J, et al .. Scintillator-oriented combinatorial search in Ce-doped (Y, Gd) 3 (Ga, Al) 5 O 12 multicomponent garnet compounds[J]. J. Phys. D -Appl. Phys ., 2011, 44(50):505104.

FERRI A, GOLA A, SERRA N, et al .. Performance of FBK high-density SiPM technology coupled to Ce:LYSO and Ce:GAGG for TOF-PET[J]. Phys. Med. Biol ., 2014, 59(4):869-880.

KAMADA K, YANAGIDA T, PEJCHAL J, et al .. Crystal growth and scintillation properties of Ce doped Gd 3 (Ga, Al) 5 O 12 single crystals[J]. IEEE Trans. Nucl. Sci ., 2012, 59(5):2112-2115.

KUROSAWA S, SHOJI Y, YOKOTA Y, et al .. Czochralski growth of Gd 3 (Al 5- x Ga x )O 12 (GAGG) single crystals and their scintillation properties[J]. J. Cryst. Growth , 2014, 393:134-137.

ZORENKO Y, GORBENKO V, ZORENKO T, et al .. High-perfomance Ce-doped multicomponent garnet single crystalline film scintillators[J]. Phys. Status Solidi R. Res. Lett ., 2015, 9(8):489-493.

ZORENKO Y, GORBENKO V, VASYLKIV J, et al .. Growth and luminescent properties of scintillators based on the single crystalline films of Lu 3- x Gd x Al 5 O 12 :Ce garnet[J]. Mater. Res. Bull ., 2015, 64:355-363.

BOK J, LALINSKY' O, HANUŠ M, et al .. GAGG:Ce single crystalline films:new perspective scintillators for electron detection in SEM[J]. Ultramicroscopy , 2016, 163:1-5.

LI J, SAHI S, GROZA M, et al .. Optical and scintillation properties of Ce 3+ -doped LuAG and YAG transparent ceramics:a comparative study[J]. J. Am. Ceram. Soc ., 2017, 100(1):150-156.

CHEN X Q, QIN H M, ZHANG Y, et al .. Highly transparent ZrO 2 -doped (Ce, Gd) 3 Al 3 Ga 2 O 12 ceramics prepared via oxygen sintering[J]. J. Eur. Ceram. Soc ., 2015, 35(14):3879-3883.

XU J, UEDA J, TANABE S. Design of deep-red persistent phosphors of Gd 3 Al 5- x Ga x O 12 :Cr 3+ transparent ceramics sensitized by Eu 3+ as an electron trap using conduction band engineering[J]. Opt. Mater. Express , 2015, 5(5):963-968.

YANAGIDA T, KAMADA K, FUJIMOTO Y, et al .. Comparative study of ceramic and single crystal Ce:GAGG scintillator[J]. Opt. Mater ., 2013, 35(12):2480-2485.

OMIDVARI N, SHARMA R, GANKA T R, et al .. Characterization of 1.2×1.2 mm 2 silicon photomultipliers with Ce:LYSO, Ce:GAGG, and Pr:LuAG scintillation crystals as detector modules for positron emission tomography[J]. J. Instrum ., 2017, 12(4):P04012.

LIU S, SUN P, LIU Y F, et al .. Warm white light with a high color-rendering index from a single Gd 3 Al 4 GaO 12 :Ce 3+ transparent ceramic for high-power LEDs and LDs[J]. ACS Appl. Mater. Interfaces , 2019, 11(2):2130-2139.

Views

1020

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

High-quality White Light OLED Devices Utilizing SiO₂ Nanospheres and Fluorescent Color-conversion Layer

Preparation and Color Tune in Ca₃Ga₄O₉∶Tb³⁺, Eu³⁺ Phosphors

Luminescence Properties and Application of Ce³⁺ Doped Ba₃Y₂(BO₃)₄ Phosphor

Methods for Evaluating Hydrolytic Degradation of Mn⁴⁺-activated Fluoride Phosphors

Related Author

Qing-yang LYU

CHEN Feile

HAN Changfeng

XIAO Yuqi

LU Yunsheng

HU Liehong

LIU Yanfeng

PAN Junyou

Related Institution

School of Materials Science and Chemical Engineering， Ningbo University

Laboratoryof Optoelectronic Materials and Devices， Ningbo Institute of Materials Technology and Engineering， Chinese Academy of Sciences

Zhejiang Guanghao Optoelectronic Technology Co.， Ltd

School of Materials Science and Engineering， Central South University

Department of Physics， Changchun Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰