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东北大学 材料科学与工程学院, 辽宁 沈阳 110819
Received:05 August 2020,
Accepted:2020-8-31,
Published:2020-12
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Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd3Al5O12-based Luminescent Materials[J]. Chinese journal of luminescence, 2020, 41(12): 1538-1553.
Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd3Al5O12-based Luminescent Materials[J]. Chinese journal of luminescence, 2020, 41(12): 1538-1553. DOI: 10.37188/CJL.20200237.
钆铝石榴石(Gd
3
Al
5
O
12
,GdAG)是性能优异的发光基质材料,但其在高温煅烧时易发生分解,导致得到纯相GdAG基发光材料比较困难。近年来,研究证实通过小半径
Ln
3+
(
Ln
=Y,Lu,Tb)取代部分Gd
3+
,或通过离子半径更大的
M
3+
来取代Al的位置扩大十二面体间隙,可以稳定GdAG晶格,得到纯相GdAG基发光材料。本文综述了GdAG基发光材料在晶格稳定化、下转换发光、上转换发光等方面的研究进展,并探讨了GdAG基单晶、薄膜和陶瓷的制备、性能及其在射线探测和医学成像等领域的应用前景。
Gadolinium aluminum garnet(Gd
3
Al
5
O
12
GdAG) is an excellent luminescent host material. But GdAG is easy to decompose during high temperature calcination
which makes it difficult to obtain a pure phase GdAG-based luminescent material. In recent years
research has confirmed that substituting the smaller radius
Ln
3+
(
Ln
=Y
Lu
Tb) for part of Gd
3+
or replacing the Al
3+
with the larger radius
M
3+
to expand the dodecahedral gap
can stabilize the GdAG lattice and thus obtain a pure phase GdAG-based luminescent material. This article reviews the research progress of GdAG-based luminescent materials including the lattice stabilization
down-conversion luminescence
and up-conversion luminescence
and also discusses the preparation and performances of GdAG-based single crystals
thin films and ceramics
and their applications in radiological detection and medical imaging.
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