phen complex were synthesized and introduced into polypropylene (PP)
obtaining the composite Eu(DBM)
3
phen/PP film with smooth surface and transparency. Room-temperature spectroscopy and decay dynamics were performed to explore the luminescence properties of Eu(DBM)
3
phen and Eu(DBM)
3
phen/PP film. The results indicated that the Eu(DBM)
3
phen/PP film displays strong characteristic luminescence and interesting decay lifetime of the Eu
3+
ions. Furthermore
the luminescence of Eu-(DBM)
3
phen/PP film exhibits an improved thermal stability compared with Eu(DBM)
3
phen.
关键词
Keywords
references
Sabbatini N, Guardigli M, Lehn J M. Luminescent lanthanide complexes as photochemical supramolecular devices
. Coordin. Chem. Rev., 1993, 123 (1-2):201-228.
Zhang Mei, Zhao Yongliang, Zhao Yanfang, et al. Studies on fluorescence property of Eu3+ dinuclear complexes with 2-thiopheneacetic acid and 1,10-phenanthroline
. Chin. J. Lumin.(发光学报), 2008, 29 (5):827-832 (in Chinese).
Wang Lianmeng, Zhao Yongliang, Zhou Yongsheng, et al. Synthesis, characterization and photoluminescence properties of (Eu<em>xRE1-x)(FTFA)3phen complexes
. Chin. J. Lumin. (发光学报), 2008, 29 (6):1086-1090 (in Chinese).
Ren Xiaoming, Wei Changping, Wang Peng, et al. Preparation and fluorescence properties of ternary complexes of Eu(BA)3PIP and Eu(BA)3phen
. Chin. J. Lumin. (发光学报), 2009, 30 (2):252-256 (in Chinese).
Zhao Dan, Qin Weiping, Zhang Jisen, et al. Improved thermal stability of europium complex nanoclusters embedded in silica colloidal spheres
. Chem. Lett., 2005, 34 (3):366-368.
Wang Yan, Qin Weiping, Zhang Jisen, et al. Self-assembly of 3D ordered Eu(DBM)3phen/SiO2 colloedal spheres via sedimentation
. Chin. J. Lumin. (发光学报), 2008, 29 (5):784-788 (in English).
Ye Z, Tan M, Wang G, et al. Preparation, characterization, and time-resolved fluorometric application of silica-coated terbium fluorescent nanoparticles
. Anal. Chem., 2004, 76 (3):513-518.
Tan M, Ye Z, Wang G, et al. Preparation and time-resolved fluorometric application of luminescent europium nanoparticles
. Chem. Mater., 2004, 16 (12):2494-2498.
Kido J, Okamoto Y. Organic lanthanide metal complexes for electroluminescent materials
. Chem. Rev., 2002, 102 (6):2357-2368.
Licha K. Contrast agents for optical imaging
. Topics in Current Chemistry, 2002, 222 :1-29.
Liang C J, Zhao D, Hong Z R, et al. Improved performance of electroluminescent devices based on an europium complex
. Appl. Phys. Lett., 2000, 76 (1):67-69.
Li W L, Wang Q R, Wei G D, et al. Study on the vegetable greenhouse covered by phototransformational film with rare earth complexes
. China Rare Earth(稀土),1993, 14 (1):25-28 (in Chinese).
Wen Y X, Wen Y, Wang Z M, et al. Study on Eu-doping PP film
. China Rare Earth (稀土), 1998, 19 (2):33-35 (in Chinese).
Yang W, Gao J Z, Kang J W, et al. Preparation and properties of Ln(I)--diketone-acetyl cellulose fIuorescence membrame
. China Eare Earth (稀土), 1998, 19 (1):10-14 (in Chinese).
Wang L T, Zhang Y G, Gu W Z, et al. Study on Ce/Pr separation coefficient in cascade extraction of La,Ce,Pr,Nd tetra-component system and application in technology design
. China Rare Earth (稀土), 2001, 22 (2):34-36 (in Chinese).
Wang Fuhe, Wang Xuehua, Gu Benyuan, et al. Lifetime distribution of spontaneous emission from an assembly of atoms in a dielectric slab
. Phys. Review A, 2003, 67 (3):035802-1-4.
Urbach H P, Rikken G L J A. Spontaneous emission from a dielectric slab