Spectroscopic Properties of Pr3+ Doped Transparent Oxyfluoride Glass Ceramic
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Spectroscopic Properties of Pr3+ Doped Transparent Oxyfluoride Glass Ceramic
Chinese Journal of LuminescenceVol. 30, Issue 2, Pages: 135-141(2009)
作者机构:
1. 中国科学院长春光学精密机械与物理研究所激发态物理重点实验室,吉林 长春,130022
2. 中国科学院研究生院 北京,100049
3. 新加坡国立大学 物理系 新加坡,117542
4. 南乔治亚大学 物理系, 乔治亚州,美国,30460
5. 南洋理工大学 数学物理学院物理系 新加坡,637371
作者简介:
基金信息:
DOI:
CLC:O482.31
Published:30 April 2009,
Published Online:30 April 2009,
Received:25 August 2008,
Revised:2 January 1900,
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WANG Ying-ying, NI Zhen-hua, WANG Xiao-jun, et al. Spectroscopic Properties of Pr3+ Doped Transparent Oxyfluoride Glass Ceramic. [J]. Chinese Journal of Luminescence 30(2):135-141(2009)
DOI:
WANG Ying-ying, NI Zhen-hua, WANG Xiao-jun, et al. Spectroscopic Properties of Pr3+ Doped Transparent Oxyfluoride Glass Ceramic. [J]. Chinese Journal of Luminescence 30(2):135-141(2009)DOI:
Spectroscopic Properties of Pr3+ Doped Transparent Oxyfluoride Glass Ceramic
we reported the spectroscopic properties of praseodymium ions (Pr
3+
) doped transparent oxyfluoride glass ceramic excited with different laser lines
such as 532
514.5 and 476.5 nm. and the spectroscopic features of Pr
3+
ions in LaF
3
nanocrystals (NCs) and in oxide glass were presented. It was found that the population on
3
P
0
state of Pr
3+
ion in NCs and in glass can be achieved by multi-phonon assistance process when excited by 514.5 nm laser lines. As a comparison
476.5 nm laser line which is mainly resonant with the
3
H
4
to
3
P
0
transition of Pr
3+
ions in NCs is used as the excitation source
transitions from
3
P
0
state to many lower states
such as
3
H
5
3
H
6
3
F
2
manifolds were observed and it showed significant difference from those excited by 532 nm and 514.5 nm laser lines in which only transition from
3
P
0
to
3
H
5
exists. We attribute those different spectroscopic features as selectively excitation of Pr
3+
ions in different environments where exist strong/weak electron-phonon coupling in the
3
P
0
1
states of Pr
3+
ion in NCs and in glass. Crystallization behavior and vibrational properties of transparent glass ceramic were also stu-died by Raman spectroscopy excited by 532 nm and 514.5 nm laser lines.
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