Emission from Divalent Dysprosium(Dy2+) in Crystalline Strontium Tetraborate
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Emission from Divalent Dysprosium(Dy2+) in Crystalline Strontium Tetraborate
Chinese Journal of LuminescenceVol. 22, Issue 4, Pages: 367-672(2001)
作者机构:
1. 中国科学院长春光学精密机械与物理研究所, 吉林, 长春, 130022
2. Transuranium Research Laboratory (Chemical and Analytical Sciences Division), Oak Ridge National Laboratory, P. O. Box 2008, Oak Ridge, TN 37831-6375, USA
作者简介:
基金信息:
DOI:
CLC:O482.31
Received:17 August 2001,
Revised:15 September 2001,
Published:30 November 2001
稿件说明:
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许武, Peterson J R. 晶态四硼酸锶中二价镝的发射[J]. 发光学报, 2001,22(4): 367-672
Xu Wu, Peterson J R. Emission from Divalent Dysprosium(Dy<sup>2+</sup>) in Crystalline Strontium Tetraborate[J]. Chinese Journal of Luminescence, 2001,22(4): 367-672
许武, Peterson J R. 晶态四硼酸锶中二价镝的发射[J]. 发光学报, 2001,22(4): 367-672DOI:
Xu Wu, Peterson J R. Emission from Divalent Dysprosium(Dy<sup>2+</sup>) in Crystalline Strontium Tetraborate[J]. Chinese Journal of Luminescence, 2001,22(4): 367-672DOI:
Emission from Divalent Dysprosium(Dy2+) in Crystalline Strontium Tetraborate
and heated in air have been recorded at room temperature.A change in oxidation state from Dy
3+
to Dy
2+
was observed.Optimum production of Dy
2+
ion occurs when the sample is heated in air at about 650℃.Two broad emission bands centered in the vicinity of 550 and 660nm have been observed from the sample under the excitation of 457.9nm.It is suggested that these bands are due to Dy
2+
ion emission from the 5d band into the ground state 4f level(
5
I
8
).Several conditions promoting the reduction of Dy
3+
ion in this matrix are discussed.To aid the reduction of Dy
3+
ion
we have also prepared SrB
4
O
7
doped with Dy
2
O
3
in Ar/H
2
(4%) atmosphere and compared the optical characteristics of Dy
2+
ion in these samples with those from the samples prepared in air.The range of g-element reducibility and stabilization in SrB
4
O
7
has been extended from Tm
2+
[E
0
(Tm
3+
/Tm
2+
)=-2.3V] to Dy
2+
[E
0
(Dy
3+
/Dy
2+
)=-2.6V] in the present work;however
the limit of this facile reduction process has not been determined yet.