喷墨打印镉基绿光量子点发光二极管及其界面

熊雪莹; 魏昌庭; 苏文明; 崔铮

doi:10.3788/fgxb20194010.1274

您当前的位置：

首页 >

文章列表页 >

喷墨打印镉基绿光量子点发光二极管及其界面

器件制备及器件物理 | 更新时间：2020-08-12

- 喷墨打印镉基绿光量子点发光二极管及其界面
- Performance and Interface of Inkjet-printed Cadmium(Cd)-based Green Quantum Dot Light-emitting Diodes
- 发光学报 2019年40卷第10期页码：1274-1280
- 作者机构：
  
  1. 中国科学技术大学纳米技术与纳米仿生学院,安徽合肥,230026
  2. 中国科学院苏州纳米技术与纳米仿生研究所印刷电子技术研究中心,江苏苏州,215123
- 作者简介：
- 基金信息：
  
  国家重点研发计划项目（2016YFB0401600）;国家自然科学基金（U1605244）;江苏省研究生科研创新计划（SJKY19_0319）资助项目
- DOI：10.3788/fgxb20194010.1274
  中图分类号： TN383+.1
- 收稿日期：2019-04-24，
  
  修回日期：2019-05-24，
  
  网络出版日期：2019-05-27，
  
  纸质出版日期：2019-10-05
- 稿件说明：
移动端阅览
熊雪莹, 魏昌庭, 苏文明等. 喷墨打印镉基绿光量子点发光二极管及其界面[J]. 发光学报, 2019,40(10): 1274-1280

XIONG Xue-ying, WEI Chang-ting, SU Wen-ming etc. Performance and Interface of Inkjet-printed Cadmium(Cd)-based Green Quantum Dot Light-emitting Diodes[J]. Chinese Journal of Luminescence, 2019,40(10): 1274-1280
熊雪莹, 魏昌庭, 苏文明等. 喷墨打印镉基绿光量子点发光二极管及其界面[J]. 发光学报, 2019,40(10): 1274-1280 DOI： 10.3788/fgxb20194010.1274.

XIONG Xue-ying, WEI Chang-ting, SU Wen-ming etc. Performance and Interface of Inkjet-printed Cadmium(Cd)-based Green Quantum Dot Light-emitting Diodes[J]. Chinese Journal of Luminescence, 2019,40(10): 1274-1280 DOI： 10.3788/fgxb20194010.1274.

摘要

喷墨打印镉基量子点发光二极管（QLEDs）有望应用于大尺寸全彩显示面板且具有材料利用率高的特点而广受关注。但目前喷墨打印器件效率远低于旋涂制备的同结构器件，针对这一问题，本文研究了在PVK空穴传输层上喷墨打印绿光量子点器件及量子点墨水溶剂对传输层界面的影响。研究发现，喷墨打印过程中的层间互溶是影响器件效率的关键，在采用正交溶剂结合喷墨工艺优化实现了高质量的膜层与界面后，获得了6.3%的喷墨印刷绿光QLEDs外量子效率。

Abstract

Inkjet-printed quantum dot light-emitting diodes(QLEDs) have received widely attention

owing to their potential for use in large-area full-color pixelated display with high material utilization. However

the performance of the inkjet-printed QLEDs is always inferior to the spin coated devices with the same structure. In this study

the performance of the inkjet-printed green QLEDs based on PVK layer and the effects of quantum dot ink formula on transport layer interfaces were investigated. It is revealed that layer erosion is a key issue for performance of inkjet-printed QLEDs. An external quantum efficiency of 6.3% was achieved in inkjet-printed green QLEDs with high-quality film and interface by employing the orthogonal solvent

via

optimizing inkjet printing technology.

关键词

Keywords

references

SHIRASAKI Y,SUPRAN G J,BAWENDI M G,et al.. Emergence of colloidal quantum-dot light-emitting technologies[J]. Nat. Photon., 2013,7(1):13-23.

SHANG Y Q,NING Z J. Colloidal quantum-dots surface and device structure engineering for high-performance light-emitting diodes[J]. Nat. Sci. Rev., 2017,4(2):170-183.

VOZNYY O,SUTHERLAND B R,IP A H,et al.. Engineering charge transport by heterostructuring solution-processed semiconductors[J]. Nat. Rev. Mater., 2017,2:17026-1-10.

DAI X L,DENG Y Z,PENG X G,et al.. Quantum-dot light-emitting diodes for large-area displays:towards the dawn of commercialization[J]. Adv. Mater., 2017,29(14):1607022-1-22.

张锋,薛建设,喻志农,等. 量子点发光在显示器件中的应用[J]. 液晶与显示, 2012,27(2):163-167. ZHANG F,XUE J S,YU Z N,et al.. Quantum-dot light emitting device for displays[J]. Chin. J. Liq. Cryst. Disp., 2012,27(2):163-167. (in Chinese)

QIN H Y,NIU Y,MENG R Y,et al.. Single-dot spectroscopy of zinc-blende CdSe/CdS core/shell nanocrystals:nonblinking and correlation with ensemble measurements[J]. J. Am. Chem. Soc., 2014,136(1):179-187.

KIM B H,NAM S,OH N,et al.. Multilayer transfer printing for pixelated,multicolor quantum dot light-emitting diodes[J]. ACS Nano, 2016,10(5):4920-4925.

HO M D,KIM N,KIM D,et al.. CdSe/ZnS quantum dot thin film formation by an electrospray deposition process for light-emitting devices[J]. Small, 2014,10(20):4142-4146.

COLVIN V L,SCHLAMP M C,ALIVISATOS A P. Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer[J]. Nature, 1994,370(6488):354-357.

BAE W K,LIM J,LEE D,et al.. R/G/B/natural white light thin colloidal quantum dot-based light-emitting devices[J]. Adv. Mater., 2014,26(37):6387-6393.

PENG X G,SCHLAMP M C,KADAVANICH A V,et al.. Epitaxial growth of highly luminescent CdSe/CdS core/shell nanocrystals with photostability and electronic accessibility[J]. J. Am. Chem. Soc., 1997,119(30):7019-7029.

COE S,WOO W K,BAWENDI M,et al.. Electroluminescence from single monolayers of nanocrystals in molecular organic devices[J]. Nature, 2002,420(6917):800-803.

CHEN H T,DING K,FAN L W,et al.. All-solution-processed quantum dot light emitting diodes based on double hole transport layers by hot spin-coating with highly efficient and low turn-on voltage[J]. ACS Appl. Mater. Interfaces, 2018,10(34):29076-29082.

HO S,LIU S Y,CHEN Y,et al.. Review of recent progress in multilayer solution-processed organic light-emitting diodes[J]. J. Photon. Energy, 2015,5(1):057611-1-17.

DE GANS B J,SCHUBERT U S. Inkjet printing of well-defined polymer dots and arrays[J]. Langmuir, 2004,20(18):7789-7793.

陈文斌,郭文瑞,牟婉莹,等. 喷墨打印和旋涂法制备有机电致发光显示器件中空穴注入及发光层的比较研究[J]. 发光学报, 2018,39(10):1451-1457. CHEN W B,GUO W R,MOU W Y,et al.. Comparing of inkjet printing versus spin coating for preparing fine structure hole transfer and emitting layers in OLED display construction[J]. Chin. J. Lumin., 2018,39(10):1451-1457. (in Chinese)

何慧,王刚,赵谡玲,等. 有机绝缘层材料聚(4-乙烯基苯酚)喷墨打印工艺研究[J]. 液晶与显示, 2012,27(5):590-594. HE H,WANG G,ZHAO S L,et al.. Inkjet printing organic dielectric material-poly(4-vinylphenol)[J]. Chin. J. Liq. Cryst. Disp., 2012,27(5):590-594. (in Chinese)

LIU Y,LI F S,XU Z W,et al.. Efficient all-solution processed quantum dot light emitting diodes based on inkjet printing technique[J]. ACS Appl. Mater. Interfaces, 2017,9(30):25506-25512.

JIANG C B,ZHONG Z M,LIU B Q,et al.. Coffee-ring-free quantum dot thin film using inkjet printing from a mixed-solvent system on modified ZnO transport layer for light-emitting devices[J]. ACS Appl. Mater. Interfaces, 2016,8(39):26162-26168.

KIM J H,HAN C Y,LEE K H,et al.. Performance improvement of quantum dot-light-emitting diodes enabled by an alloyed ZnMgO nanoparticle electron transport layer[J]. Chem. Mater., 2015,27(1):197-204.

浏览量

199

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

中性蓝光铱配合物及其OLED研究进展

喷墨打印量子点电致发光显示关键材料与技术的前世与今生

含四元环Ir-S-C-S骨架的高效红光铱（Ⅲ）配合物及其OLED性能

基于准二维钙钛矿的窄线宽红光电致发光器件性能研究

维生素C添加剂改善纯红锡基钙钛矿电致发光性能