(Mg1-xSrx)2SiO4:(Eu3+,F-)荧光粉的物相及光谱

汪雨; 罗岚; 郭锐; 徐诗林; 孙传耀

doi:10.3788/fgxb20194009.1086

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(Mg_1-xSr_x)₂SiO₄:(Eu³⁺,F^-)荧光粉的物相及光谱

材料合成及性能 | 更新时间：2020-08-12

- (Mg_1-xSr_x)₂SiO₄:(Eu³⁺,F^-)荧光粉的物相及光谱
- Phase Constitutions and Luminescent Spectra of(Mg_1-xSr_x)₂SiO₄: (Eu³⁺,F^-) Phosphors
- 发光学报 2019年40卷第9期页码：1086-1095
- 作者机构：
  
  1. 南昌大学材料科学与工程学院, 江西南昌 330001
  2. 南昌大学江西省轻质高强结构材料重点实验室, 江西南昌 330001
- 作者简介：
- 基金信息：
  
  国家重点研发计划（2016YFB0701201，2016YFB0701203，2017YFB1103701）;国家自然科学基金（11564025，51671101，51062003）;江西省自然科学基金（20172BCB22002）;江西省教育厅重点计划（GJJ150010）资助项目
- DOI：10.3788/fgxb20194009.1086
  中图分类号： TB332
- 收稿日期：2018-12-27，
  
  修回日期：2019-02-27，
  
  网络出版日期：2019-03-14，
  
  纸质出版日期：2019-09-05
- 稿件说明：
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汪雨, 罗岚, 郭锐等. (Mg1-xSrx)2SiO4:(Eu3+,F-)荧光粉的物相及光谱[J]. 发光学报, 2019,40(9): 1086-1095

WANG Yu, LUO Lan, GUO Rui etc. Phase Constitutions and Luminescent Spectra of(Mg1-xSrx)2SiO4: (Eu3+,F-) Phosphors[J]. Chinese Journal of Luminescence, 2019,40(9): 1086-1095
汪雨, 罗岚, 郭锐等. (Mg1-xSrx)2SiO4:(Eu3+,F-)荧光粉的物相及光谱[J]. 发光学报, 2019,40(9): 1086-1095 DOI： 10.3788/fgxb20194009.1086.

WANG Yu, LUO Lan, GUO Rui etc. Phase Constitutions and Luminescent Spectra of(Mg1-xSrx)2SiO4: (Eu3+,F-) Phosphors[J]. Chinese Journal of Luminescence, 2019,40(9): 1086-1095 DOI： 10.3788/fgxb20194009.1086.

摘要

采用高温固相法在空气氛围下在1 150℃制备（Mg

）

SiO

（

=0~1）粉末。物相分析表明，随着Sr离子含量由小到大，（Mg

）

SiO

基质晶相组成将发生如下变化:-Mg

SiO

、-Mg

SiO

混合相（

=0）-Sr

SiO

、-Sr

SiO

、-Mg

SiO

、-Mg

SiO

、Sr

MgSi

混合相（0.2

0.8）-Sr

SiO

和-Sr

SiO

混合相（

=1）；当

=0.2时主晶相为高温-Mg

SiO

，而在

=0时主晶相为低温-Mg

SiO

。紫外发光照相和光谱表明，当

=0.2时，（Mg

）

1.96

SiO

:0.04（Eu

，F

）红光发射亮度最大。进一步晶体结构分析发现Sr离子可以固溶入-Mg

SiO

使得-Mg

SiO

更为稳定，同时晶格略微增大；化学配比为（Mg

0.8

0.2

）

SiO

粉末在1 250℃煅烧可以得到平均粒径为21.68 m的单相-Mg

SiO

粉末。对于单相（Mg

0.8

0.2

）

SiO

（Eu

，F

）系列荧光粉，其XPS分析表明Eu离子以三价进入晶格；光谱分析表明在365 nm和254 nm激发下，有595，615（主峰），655，705 nm红光锐峰发射（对应

，

=1，2，3，4）；且

=0.04为最佳铕离子掺杂浓度（此时其量子效率、寿命均达到最大）；基于Blasse理论可判断铕离子间能量传递方式为基于辐射跃迁的电四极-电四极作用。

Abstract

(Mg

)

SiO

(

=0~1) powder was prepared at 1 150℃ by high temperature solid-state method. As Sr ion content in matrix increasing

the phase constitutions change from -Mg

SiO

-Mg

SiO

mixture(

=0) to -Sr

SiO

-Sr

SiO

-Mg

SiO

-Mg

SiO

MgSi

mixture(0.2

0.8)

then to -Sr

SiO

-Sr

SiO

mixture(

=1). Furthermore

when

=0.2

the main phase is -Mg

SiO

while

the main phase is -Mg

SiO

. UV light excitation and luminescent spectra analysis show (Mg

0.8

0.2

)

1.96

SiO

:0.04(Eu

) has been picked out as the best red phosphor composition among (Mg

)

1.96

SiO

:0.04(Eu

). Sr ion would go into -Mg

SiO

crystal lattice

and makes the phase more stable. When the annealing temperature reaching at 1 250℃

the powder has the composition as (Mg

0.8

0.2

)

SiO

would be single phase as -Mg

SiO

. (Mg

0.8

0.2

)

SiO

(Eu

) series(~21.68 m) have red-band emission peaks at 595

615(main)

655

705 nm(related to

4) under 365 nm or 254 nm excitation

and the most suitable Eu

doping amount is 4%(the quantum yields and lifetime both reaching to maxium value among the series). Based on Blasse theory

the main energy transfer mode for activators should be the four electric dipoles(q-q).

关键词

Keywords

references

周珺. 稀土掺杂硅酸盐荧光粉的结构与发光性能的调控研究[D]. 北京:中国地质大学(北京), 2016. ZHOU J. Structure and Luminescence Properties Modulaton of Rare Earth Doped Silicate Phosphors[D]. Beijing:China University of Geosciences(Beijing), 2016. (in Chinese)

张慧. 碱土氯硅酸盐白光荧光粉的溶胶-凝胶法合成及性质研究[D]. 湘潭:湖南科技大学, 2017. ZHANG H. Sol-gel Synthesis and Properties of White Light-emitting Powder Alkaline Chlorosilicate[D]. Xiangtan:Hunan University of Science and Technology, 2017. (in Chinese)

苗世海. ABSiO4基正硅酸盐荧光粉的结构与发光性能调控研究[D]. 北京:中国地质大学(北京), 2016. MIAO S H. ABSiO4 Based Orthosilicate Phosphors and The Investigation on Photoluminescence and Structure Properties[D]. Beijing:China University of Geosciences(Beijing), 2016. (in Chinese)

ZHOU X J,XIONG Z X,XUE H,et al.. Hydrothermal synthesis and photoluminescent properties of Li2Sr0.996SiO4:Pr3+0.004 phosphors for white-LED lightings[J]. J. Rare Earths, 2015,33(3):244-248.

周青超,柏泽龙,鲁路,等. 白光LED远程荧光粉技术研究进展与展望[J]. 中国光学, 2015,8(3):313-328. ZHOU Q C,BAI Z L,LU L,et al.. Remote phosphor technology for white LED applications:advances and prospects[J]. Chin. Opt., 2015,8(3):313-328. (in Chinese)

POORT S H M,JANSSEN W,BLASSE G. Optical properties of Eu2+ -activated orthosilicates and orthophosphates[J]. J. Alloys Compd., 1997,260(1-2):93-97.

POORT S H M,VAN KREVEL J W H,STOMPHORST R,et al.. Luminescence of Eu2+ in host lattices with three alkaline earth ions in a row[J]. J. Solid State Chem., 1996,122(2):432-435.

LI X J,LIANG Y J,YANG F,et al.. Green emission enhancement of Ba2SiO4:Eu2+ phosphor via Gd co-doping and charge compensation[J]. J. Mater. Sci. Mater. Electron., 2013,24(9):3199-3203.

姜涛. 稀土掺杂硅酸盐荧光粉的制备及发光特性研究[D]. 哈尔滨:哈尔滨理工大学, 2014. JIANG T. Study on Preparation and Fluorescence Properties of Rare Earth Ion Doped Silicate Phosphors[D]. Harbin:Harbin University of Science and Technology, 2014. (in Chinese)

LI L K,ZENG R J,WANG H H. Ba1.3Ca0.7SiO4:Eu2+,Mn2+:a white-lighting-emitting phosphor with extra afterglow properties via YF3 addition[J]. J. Alloys Compd., 2018,765:249-252.

WEN D W,KUWAHARA H,KATO H. Anomalous orange light-emitting (Sr,Ba)2SiO4:Eu2+ phosphors for warm white LEDs[J]. ACS Appl. Mater. Interfaces, 2016,8(18):11615-11620.

LV W Z,JIAO M M,ZHAO Q,et al.. Ba1.3Ca0.7SiO4:Eu2+,Mn2+:a promising single-phase,color-tunable phosphor for near-ultraviolet white-light-emitting diodes[J]. Inorg. Chem., 2014,53(20):11007-11014.

孙亮. A3MgSi2O8:Eu2+,Mn2+(A=Ba、Sr、Ca)荧光体的结构调控及红光增强[D]. 天津:天津理工大学, 2015. SUN L. Structural Adjustment and Red Emission Enhancement of A3MgSi2O8:Eu2+,Mn2+ (A=Ba,Sr,Ca) Phosphor[D]. Tianjin:Tianjin University of Technology, 2015. (in Chinese)

谢木标,VAN DER KOLK E,DORENBOS P. Eu2+掺杂Sr3MgSi2O8荧光粉的UV-VUV和X射线激发发光及应用[C]. 中国稀土学会2017学术年会摘要集,北京, 2017:1. XIE M B,VAN DER KOLK E,DORENBOS P. UV-VUV and X-ray excitation luminescence of Eu2+ doped Sr3MgSi2O8 phosphors[C]. China Rare Earth Society 2017 Academic Annual Meeting Summary,Beijing, 2017:1. (in Chinese)

MAO Z Y,CHEN J J,LI J,et al.. Dual-responsive Sr2SiO4:Eu2+ -Ba3MgSi2O8:Eu2+,Mn2+ composite phosphor to human eyes and plant chlorophylls applications for general lighting and plant lighting[J]. Chem. Eng. J., 2016,284:1003-1007.

王胜楠. Ca3MgSi2O8:Eu2+,Dy3+长余辉发光材料的制备及发光性能研究[D]. 杭州:杭州电子科技大学, 2016. WANG S N. Ca3MgSi2O8:Eu2+,Dy3+ Long Afterglow Luminescent Preparation and Properties[D]. Hangzhou:Hangzhou Dianzi University, 2016. (in Chinese)

STEFAИSKA D,DEREИ P J. Luminescence investigation and thermal stability of blue-greenish emission generated from Ca3MgSi2O8:Eu2+ phosphor[J]. Opt. Mater., 2018,80:62-64.

MAO Z Y,CHEN J J,SUN L,et al.. Control of green emitting intermediate phases in (Ba,Sr)3MgSi2O8:Eu2+,Mn2+ phosphors for dual-bands or tri-bands emission[J]. Mater. Res. Bull., 2015,70:908-913.

张家骅,吕伟,郝振东,等. 利用能量传递实现可调全色单一白光BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+荧光粉(特邀)[J]. 中国光学, 2012,5(3):203-208. ZHANG J H,L W,HAO Z D,et al.. Color-tunable white-light emitting BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+ phosphors via energy transfer (Invited)[J]. Chin. Opt., 2012,5(3):203-208. (in Chinese)

LI J,DENG J C,LU Q F,et al.. Direct white-light from core-shell-like sphere with Sr3Mg-Si2O8:Eu2+,Mn2+ coated on Sr2SiO4:Eu2+[J]. Optoelectron. Lett., 2013,9(4):293-296.

ASHBROOK S E,BERRY A J,HIBBERSON W O,et al.. High-resolution17O MAS NMR spectroscopy of forsterite (-Mg2SiO4),wadsleyite (-Mg2SiO4),and ringwoodite (-Mg2SiO4)[J]. Am. Mineral., 2005,90(11-12):1861-1870.

LI X J,HUA Y J,MA H P,et al.. Luminescence properties and crystal structure of '-Sr2Si3x/4O2Nx:Eu2+ phosphors with different concentrations of N3- ions[J]. RSC Adv., 2015,5(77):62659-62669.

SHUKLA A,DECTEROV S A,PELTON A D. Thermodynamic evaluation and optimization of the SrO-MgO,SrO-SiO2 and SrO-MgO-SiO2 systems[J]. J. Phase Equilib. Diff., 2017,38(5):615-629.

CATTI M,GAZZONI G,IVALDI G. Structures of twinned -Sr2SiO4 and of '-Sr1.9Ba0.1SiO4[J]. Acta Crystallogr. Sect. C, 1983,39(1):29-34.

NAG A,KUTTY T R N. The light induced valence change of europium in Sr2SiO4:Eu involving transient crystal structure[J]. J. Mater. Chem., 2004,14(10):1598-1604.

王林香,庹娟,叶颖,等. Li+,Zn2+,Mg2+掺杂Lu2O3:Er3+荧光粉的制备及发光特性[J]. 中国光学, 2019,12(1):112-121. WANG L X,TUO J,YE Y,et al.. Preparation and luminescence properties of Li+,Zn2+,Mg2+ Doped Lu2O3:Er3+ phosphors[J]. Chin. Opt., 2019,12(1):112-121. (in Chinese)

GUPTA S K,SUDARSHAN K,SHARMA S K,et al.. Positron annihilation studies of Eu and Dy doped '-Sr2SiO4[J]. J. Phys. Conf. Ser., 2015,618(1):012016-1-4.

李国爱,张坤,陆政,等. 固溶温度对Al-11.7Zn-2.2Mg-2.0Cu-0.12Zr铝合金组织及性能的影响[J]. 稀有金属材料与工程, 2016,45(4):1040-1044. LI G A,ZHANG K,LU Z,et al.. Effect of solution temperature on microstructure and properties of Al-11.7Zn-2.2Mg-2.0Cu-0.12Zr aluminum alloy[J]. Rare Metal Mater. Eng., 2016,45(4):1040-1044. (in Chinese)

马格林. 一种新的SiC外延材料质量评估方法[D]. 西安:西安电子科技大学, 2011. MA G L. A New Quality Evaluation Method for Silicon Epitaxial Materials[D]. Xi'an:Xidian University, 2011. (in Chinese)

姜贵君,姜贵全,林晓梅. 固溶体Ce0.8Eu0.2O2-的合成与表征[J]. 武汉理工大学学报, 2009,31(15):15-17. JIANG G J,JIANG G Q,LIN X M. Preparation and characterization for solid solution Ce0.8Eu0.2O2-[J]. J. Wuhan Univ. Technol., 2009,31(15):15-17. (in Chinese)

王庆平. 白光LED用硅酸盐荧光粉的发光特性及其应用研究[D]. 重庆:重庆理工大学, 2016. WANG Q P. The Luminescence Properties of Silicate Phosphor Based on White LED[D]. Chongqing:Chongqing University of Technology, 2016. (in Chinese)

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