X射线激发深层肌体温度传感材料La2O2S:Yb3+,Er3+的测温性质研究

汪欣; 李晓晓; 李天义; 杨艳民

doi:10.3788/fgxb20194001.0030

您当前的位置：

首页 >

文章列表页 >

X射线激发深层肌体温度传感材料La₂O₂S:Yb³⁺,Er³⁺的测温性质研究

材料合成及性能 | 更新时间：2020-08-12

- X射线激发深层肌体温度传感材料La₂O₂S:Yb³⁺,Er³⁺的测温性质研究
- Thermometric Properties of Deep Tissue Temperature Sensing Material La₂O₂S: Yb³⁺,Er³⁺ Excited by X-ray
- 发光学报 2019年40卷第1期页码：30-38
- 作者机构：
  
  河北大学物理科学与技术学院河北省光电信息材料重点实验室新能源光电器件国家地方联合工程实验室,河北保定,071002
- 作者简介：
- 基金信息：
  
  国家自然科学基金（11474083）();河北省自然科学基金（A2015201192）();河北省教育厅科研项目（ZD2014069）资助()
- DOI：10.3788/fgxb20194001.0030
  中图分类号： O482.31
- 收稿日期：2018-09-20，
  
  修回日期：2018-11-05，
  
  纸质出版日期：2019-01-05
- 稿件说明：
移动端阅览
汪欣, 李晓晓, 李天义等. X射线激发深层肌体温度传感材料La2O2S:Yb3+,Er3+的测温性质研究[J]. 发光学报, 2019,40(1): 30-38

WANG Xin, LI Xiao-xiao, LI Tian-yi etc. Thermometric Properties of Deep Tissue Temperature Sensing Material La2O2S: Yb3+,Er3+ Excited by X-ray[J]. Chinese Journal of Luminescence, 2019,40(1): 30-38
汪欣, 李晓晓, 李天义等. X射线激发深层肌体温度传感材料La2O2S:Yb3+,Er3+的测温性质研究[J]. 发光学报, 2019,40(1): 30-38 DOI： 10.3788/fgxb20194001.0030.

WANG Xin, LI Xiao-xiao, LI Tian-yi etc. Thermometric Properties of Deep Tissue Temperature Sensing Material La2O2S: Yb3+,Er3+ Excited by X-ray[J]. Chinese Journal of Luminescence, 2019,40(1): 30-38 DOI： 10.3788/fgxb20194001.0030.

摘要

、Er

共掺杂上转换发光材料能被红外光激发，可用于肌体内部温度测量，但上转换材料效率较低，无法实现较深组织温度探测。考虑到Er

能级可被多种光源布居，较好肌体穿透性的X射线无疑是理想的激发源。本文首次报道了一种新型的深层肌体温度传感材料La

S:Yb

，Er

。数据表明，X射线激发下，在不同温度下的两个绿光发射强度比符合玻尔兹曼分布，最高测温灵敏度达到了0.011 5 K

-1

。我们相信Yb

、Er

共掺的La

S是可以应用于临床的理想测温材料。

Abstract

co-doped up-conversion luminescent materials can be used to measure the internal temperature of tissue under infrared light excitation

but the lower efficiency of up-conversion materials makes it impossible to detect deep tissue temperature. Considering that Er

energy levels can be populated by various light sources

X-ray is undoubtedly an ideal excitation source with better penetration. In this article

we first reported a novel deep tissue temperature sensing material La

S:Yb

. The data show that the fluorescence intensity ratio of the two green levels at different temperatures conforms to Boltzmann distribution under X-ray excitation

and the maximum sensor sensitivity is 0.011 5 K

-1

. We believe that Yb

co-doped La

S can be used as an ideal temperature measuring material for clinical application.

关键词

Keywords

references

吴中立,吴红梅,姚震,等. GdNbO4:Er3+/Yb3+荧光粉的上转换发光与温度特性[J]. 发光学报, 2017,38(9):1129-1135. WU Z L,WU H M,YAO Z,et al.. Upconversion luminescence and temperature characteristics of GdNbO4:Er3+/Yb3+ phosphors[J]. Chin. J. Lumin., 2017,38(9):1129-1135. (in Chinese)

林杨杨,陈铠炀,唐霞艳,等. Er3+/Yb3+共掺杂氧氟硼硅酸盐微晶玻璃绿色上转换发光的温度特性[J]. 发光学报, 2015,36(9):1001-1005. LIN Y Y,CHEN K Y,TANG X Z,et al.. Temperature characteristic of green upconversion luminescence in Er3+/Yb3+ codoped oxyfluoride borosilicate glass ceramics[J]. Chin. J. Lumin., 2015,36(9):1001-1005. (in Chinese)

LI D Y,TIAN L L,HUANG Z,et al.. Optical temperature sensor based on infrared excited green upconversion emission in hexagonal phase NaLuF4:Yb3+/Er3+ nanorods[J]. J. Nanosci. Nanotechnol., 2016,16(4):3641-3645.

ZHENG H,CHEN B J,YU H Q,et al.. Microwave-assisted hydrothermal synthesis and temperature sensing application of Er3+/Yb3+ doped NaY(WO4)2 microstructures[J]. J. Colloid Interface Sci., 2014,420:27-34.

SAVCHUK O A,CARVAJAL J J,CASCALES C,et al.. Benefits of silica core-shell structures on the temperature sensing properties of Er,Yb:GdVO4 up-conversion nanoparticles[J]. ACS Appl. Mater. Interfaces, 2016,8(11):7266-7273.

ARAI K,HONDA N,MORI T,et al.. Sensitivity-enhancing scheme of a polarimetric heterodyne sensor using a birefringent fiber loop[J]. Opt. Lett., 1990,15(19):1103-1105.

ZHANG W W,WANG G Y,BAXTER G W,et al.. Methods for broadband spectral analysis:intrinsic fluorescence temperature sensing as an example[J]. Appl. Spectrosc., 2017,71(6):1256-1262.

GAO Y,HUANG F,LIN H,et al.. A novel optical thermometry strategy based on diverse thermal response from two intervalence charge transfer states[J]. Adv. Funct. Mater., 2016,26(18):3139-3145.

DONG B,HUA R N,CAO B S,et al.. Size dependence of the upconverted luminescence of NaYF4:Er,Yb microspheres for use in ratiometric thermometry[J]. Phys. Chem. Chem. Phys., 2014,16(37):20009-20012.

FANG H W,WEI X T,ZHOU S S,et al.. Terbium and holmium codoped yttrium phosphate as non-contact optical temperature sensors[J]. RSC Adv., 2017,7(17):10200-10205.

VETRONE F,NACCACHE R,ZAMARRN A,et al.. Temperature sensing using fluorescent nanothermometers[J]. ACS Nano, 2010,4(6):3254-3258.

SINGH S K,KUMAR K,RAI S B. Er3+/Yb3+ codoped Gd2O3 nano-phosphor for optical thermometry[J]. Sens. Actuators A:Phys., 2009,149(1):16-20.

JIANG S,ZENG P,LIAO L Q,et al.. Optical thermometry based on upconverted luminescence in transparent glass ceramics containing NaYF4:Yb3+/Er3+ nanocrystals[J]. J. Alloys Compd., 2014,617:538-541.

DUBEY A,SONI A K,KUMARI A,et al.. Enhanced green upconversion emission in NaYF4:Er3+/Yb3+/Li+ phosphors for optical thermometry[J]. J. Alloys Compd., 2017,693:194-200.

MUKHOPADHYAY L,RAI V K,BOKOLIA R,et al.. 980 nm excited Er3+/Yb3+/Li+/Ba2+:NaZnPO4 upconverting phosphors in optical thermometry[J]. J. Lumin., 2017,187:368-377.

YANG X X,FU Z L,YANG Y M,et al.. Optical temperature sensing behavior of high-efficiency upconversion:Er3+-Yb3+ Co-doped NaY(MoO4)2 phosphor[J]. J. Am. Ceram. Soc., 2015,98(8):2595-2600.

MADSEN S J,SUN C H,TROMBERG B J,et al.. Repetitive 5-aminolevulinic acid-mediated photodynamic therapy on human glioma spheroids[J]. J. Neurooncol., 2003,62(3):243-250.

ORION E,MATZ H,WOLFR. Interferons:unapproved uses,dosages,or indications[J]. Clin. Dermatol., 2002,20(5):493-504.

YANG Y M,MI C,JIAO F Y,et al.. A novel multifunctional upconversion phosphor:Yb3+/Er3+ codoped La2S3[J]. J. Am. Ceram. Soc., 2014,97(6):1769-1775.

LIU Y F,CHEN W,WANG S P,et al.. Investigation of water-soluble X-ray luminescence nanoparticles for photodynamic activation[J]. Appl. Phys. Lett., 2008,92(4):043901-1-3.

RAHMAN W N,BISHARA N,ACKERLY T,et al.. Enhancement of radiation effects by gold nanoparticles for superficial radiation therapy[J]. Nanomed.:Nanotechnol. Biol. Med., 2009,5(2):136-142.

CARTER J D,CHENG N N,QU Y Q,et al.. Nanoscale energy deposition by X-ray absorbing nanostructures[J]. J. Phys. Chem. B, 2007,111(40):11622-11625.

BRIXNER L H. New X-ray phosphors[J]. Mater. Chem. Phys., 1987,16(3-4):253-281.

CHEN H Y,PATRICK A L,YANG Z Q,et al.. High-resolution chemical imaging through tissue with an X-ray scintillator sensor[J]. Anal. Chem., 2011,83(13):5045-5049.

YANG Y M,MI C. Highly sensitive optical thermometry based on the upconversion fluorescence from Yb3+/Er3+ codoped La2(WO4)3:Yb3+,Er3+ phosphor[C]. International Conference on Optical Instruments and Technology:Optical Sensors and Applications,Beijing, 2013.

LIU G G,FU L L,GAO Z Y,et al.. Investigation into the temperature sensing behavior of Yb3+ sensitized Er3+ doped Y2O3,YAG and LaAlO3 phosphors[J]. RSC Adv., 2015,5(64):51820-51827.

YANG Y M,MI C,YU F,et al.. Optical thermometry based on the upconversion fluorescence from Yb3+/Er3+ codoped La2O2S phosphor[J]. Ceram. Int., 2013,40(7):9875-9880.

LI X D,SONG Y J,YANG Y M,et al.. Structure and optical thermometry characterization of Er3+/Yb3+ co-doped BaGd2CuO5[J]. J. Nanosci. Nanotechnol., 2016,16(4):3542-3546.

刘延洲,杨艳民,郭彦明,等. Er3+:Yb3+共掺杂BaGd2ZnO5纳米晶体上转换光学温度传感[J]. 光谱学与光谱分析, 2015,35(2):329-333. LIU Y Z,YANG Y M,GUO Y M,et al.. Er3+:Yb3+ Co-doped nanocrystals BaGd2 ZnO5 of Up-conversion optical temperature sensing[J]. Spectrosc. Spectr. Anal., 2015,35(2):329-333. (in Chinese)

MAURICE E,MONNOM G,DUSSARDIER B,et al.. Erbium-doped silica fibers for intrinsic fiber-optic temperature sensors[J]. Appl. Opt., 1995,34(34):8019-8025.

SHINN M D,SIBLEY W A,DREXHAGE M G,et al.. Optical transitions of Er3+ ions in fluorozirconate glass[J]. Phys. Rev. B, 1983,27(11):6635-6648.

WADE S A,COLLINS S F,BAXTER G W. Fluorescence intensity ratio technique for optical fiber point temperature sensing[J]. J. Appl. Phys., 2003,94(8):4743-4756.

MACIEL G S,MENEZES L D,GOMES A S L,et al.. Temperature sensor based on frequency upconversion in Er3+ -doped fluoroindate glass[J]. IEEE Photon. Technol. Lett., 1995,7(12):1474-1476.

CHEN Y,CHEN G H,LIU X Y,et al.. Enhanced up-conversion luminescence and optical thermometry characteristics of Er3+/Yb3+ co-doped transparent phosphate glass-ceramics[J]. J. Lumin., 2018,195:314-320.

LI X M,CAO J K,WEI Y L,et al.. Optical thermometry based on up-conversion luminescence behavior of Er3+ -doped transparent Sr2YbF7 glass-ceramics[J]. J. Am. Ceram. Soc., 2015,98(12):3824-3830.

YU H,LI S,QI Y S,et al.. Optical thermometry based on up-conversion emission behavior of Ba2LaF7 nano-crystals embedded in glass matrix[J]. J. Lumin., 2018,194:433-439.

CAI J J,WEI X T,HU F F,et al.. Up-conversion luminescence and optical thermometry properties of transparent glass ceramics containing CaF2:Yb3+/Er3+ nanocrystals[J]. Ceram. Int., 2016,42(12):13990-13995.

CAO J K,CHEN W P,XU D K,et al.. Wide-range thermometry based on green up-conversion of Yb3+/Er3+ co-doped KLu2F7 transparent bulk oxyfluoride glass ceramics[J]. J. Lumin., 2018,194:219-224.

CAO J K,HU F F,CHEN L P,et al.. Optical thermometry based on up-conversion luminescence behavior of Er3+-doped KYb2F7 nano-crystals in bulk glass ceramics[J]. J. Alloys Compd., 2017,693:326-331.

LI X M,CAO J K,HU F F,et al.. Transparent Na5Gd9F32:Er3+ glass-ceramics:enhanced up-conversion luminescence and applications in optical temperature sensors[J]. RSC Adv., 2017,7(56):35147-35153.

HU F F,CAO J K,WEI X T,et al.. Self-crystallized novel transparent Na5Yb9F32:Er3+ glass-ceramics for optical thermometry and spectral conversion[J]. J. Alloys Compd., 2017,722:669-675.

ZOU Z S,WU T,LU H,et al.. Structure,luminescence and temperature sensing in rare earth doped glass ceramics containing NaY(WO4)2 nanocrystals[J]. RSC Adv., 2018,8(14):7679-7686.

HU F F,CAO J K,WEI X T,et al.. Luminescence properties of Er3+-doped transparent NaYb2F7 glass-ceramics for optical thermometry and spectral conversion[J]. J. Mater. Chem. C, 2016,4(42):9976-9985.

CHEN D Q,LIU S,LI X Y,et al.. Gd-based oxyfluoride glass ceramics:phase transformation,optical spectroscopy and upconverting temperature sensing[J]. J. Eur. Ceram. Soc., 2017,37(13):4083-4094.

CHEN D Q,WAN Z Y,ZHOU Y,et al.. Bulk glass ceramics containing Yb3+/Er3+:-NaGdF4 nanocrystals:phase-separation-controlled crystallization,optical spectroscopy and upconverted temperature sensing behavior[J]. J. Alloys Compd., 2015,638:21-28.

LI C R,DONG B,LI S F,et al.. Er3+-Yb3+ co-doped silicate glass for optical temperature sensor[J]. Chem. Phys. Lett., 2007,443(4-6):426-429.

RAKOV N,MACIEL G S. Three-photon upconversion and optical thermometry characterization of Er3+:Yb3+ co-doped yttrium silicate powders[J]. Sens. Actuators B:Chem., 2012,164(1):96-100.

杨艳民,焦福运,苏红新,等. Yb3+/Er3+共掺BaGd2ZnO5上转换发光动力学过程的研究[J]. 光谱学与光谱分析, 2012, 2(10):2637-2641. YANG Y M,JIAO F Y,SU H X,et al.. Preparation and up-conversion luminescence dynamic process of Yb3+/Er3+ co-doped BaGd2ZnO5[J]. Spectrosc. Spectr. Anal., 2012,32(10):2637-2641. (in Chinese)

JUDD B R. Optical absorption intensities of rare-earth ions[J]. Phys. Rev., 1962,127(3):750-761.

OFELT G S. Intensities of crystal spectra of rare-earth ions[J]. J. Chem. Phys., 1962,37(3):511-520.

JRGENSEN C K,JUDD B R. Hypersensitive pseudoquadrupole transitions in lanthanides[J]. Mol. Phys., 1964,8(3):281-290.

浏览量

180

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于Sb₂O₃可饱和吸收体的2.8 μm被动调Q激光器

Er³⁺掺杂锗酸盐激光玻璃猝灭浓度的计算与预测

Er³⁺单掺、Er³⁺/Yb³⁺共掺杂Ca₁₂Al₁₄O₃₂F₂的制备及上转换发光性质

Er³⁺掺杂Na₅Lu₉F₃₂单晶体的红外光学特性

微乳液法制备NaYF₄：Yb³⁺, Er³⁺粉体及其发光性能