碱金属离子对稀土掺杂氟化物上转换荧光的影响

杨润柏; 李奕; 徐楠; 李建威

doi:10.3788/fgxb20194001.0001

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碱金属离子对稀土掺杂氟化物上转换荧光的影响

材料合成及性能 | 更新时间：2020-08-12

- 碱金属离子对稀土掺杂氟化物上转换荧光的影响
- Effects of Alkali Metal Ions on Upconversion of Rare Earth Doped Fluorides
- 发光学报 2019年40卷第1期页码：1-8
- 作者机构：
  
  1. 陕西能源职业技术学院,陕西咸阳,712000
  2. 中国计量科学研究院北京,100027
  3. 陕西省计量科学研究院,陕西西安,710065
- 作者简介：
- 基金信息：
  
  国家重点研发计划（2018YFF0212105）资助项目()
- DOI：10.3788/fgxb20194001.0001
  中图分类号： O482.31
- 收稿日期：2018-04-04，
  
  修回日期：2018-06-26，
  
  网络出版日期：2018-07-26，
  
  纸质出版日期：2019-01-05
- 稿件说明：
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杨润柏, 李奕, 徐楠等. 碱金属离子对稀土掺杂氟化物上转换荧光的影响[J]. 发光学报, 2019,40(1): 1-8

YANG Run-bai, LI Yi, XU Nan etc. Effects of Alkali Metal Ions on Upconversion of Rare Earth Doped Fluorides[J]. Chinese Journal of Luminescence, 2019,40(1): 1-8
杨润柏, 李奕, 徐楠等. 碱金属离子对稀土掺杂氟化物上转换荧光的影响[J]. 发光学报, 2019,40(1): 1-8 DOI： 10.3788/fgxb20194001.0001.

YANG Run-bai, LI Yi, XU Nan etc. Effects of Alkali Metal Ions on Upconversion of Rare Earth Doped Fluorides[J]. Chinese Journal of Luminescence, 2019,40(1): 1-8 DOI： 10.3788/fgxb20194001.0001.

摘要

提高稀土掺杂材料的上转换荧光效率具有重大的应用价值。本文通过水热法合成了不同种类的碱金属离子掺杂氟化物上转换荧光材料，通过对比样品上转换荧光特性研究其中碱金属离子的作用。发现锂离子能够明显改善稀土掺杂NaYF

的上转换荧光强度，并在稀土掺杂LiYF

中实现了比常用的NaYF

中强近7倍的上转换荧光发射。此外，在具有较高上转换效率的LiYF

基质中通过浓度优化，合成了具有高效白光上转换发射的荧光粉，其CIE坐标值为（0.32，0.36）。本项工作将对高效稀土掺杂上转换材料及照明器件的构建提供一定的参考。

Abstract

It remains a challenge for enhancing the limited upconversion efficiency of rare earth doped materials

which restricts their applications severely. In this paper

we synthesized alkali metal ions and rare earth ions co-doped fluorides using hydrothermal method

the upconversion properties were investigated as well. By comparing the upconversion spectra

effects of the doping alkali metal ions were discussed. It is found that doping Li

can significantly enhance the upconversion intensity of rare earth doped NaYF

nanocrystals

a nearly 7 times stronger emission was achieved in LiYF

host than that in NaYF

. In addition

efficient white light emission was obtained in rare earth doped LiYF

matrix (CIE coordinates

=0.32

=0.36)

after optimizing the doping concentrations. This work provides references for fabricating the highly efficient upconversion materials

as well as the new generation lighting devices.

关键词

Keywords

references

李洋洋,李大光,张丹,等. 小尺寸NaLuF4:Yb3+/Tm3+纳米晶的生长及上转换发光[J]. 发光学报, 2018,39(6):764-770. LI Y Y,LI D G,ZHANG D,et al.. Growth process and upconversion luminescence of NaLuF4:Yb3+/Tm3+ nanocrystals[J]. Chin. J. Lumin., 2018,39(6):764-770. (in Chinese)

NACCACHE R,RODRGUEZ E M,BOGDAN N,et al.. High resolution fluorescence imaging of cancers using lanthanide ion-doped upconverting nanocrystals[J]. Cancers, 2012,4(4):1067-1105.

PRODI L,RAMPAZZO E,RASTRELLI F,et al.. Imaging agents based on lanthanide doped nanoparticles[J]. Chem. Soc. Rev., 2015,44(14):4922-4952.

CHEN G Y,SEO J,YANG C H,et al.. Nanochemistry and nanomaterials for photovoltaics[J]. Chem. Soc. Rev., 2013,42(21):8304-8338.

HUANG X Y,HAN S Y,HUANG W,et al.. Enhancing solar cell efficiency:the search for luminescent materials as spectral converters[J]. Chem. Soc. Rev., 2013,42(1):173-201.

TANG J,SONG H J,ZENG B R,et al.. Cataluminescence gas sensor for ketones based on nanosized NaYF4:Er[J]. Sens. Actuators B:Chem., 2016,222:300-306.

LI L P,XU W,ZHENG L J,et al.. Valley-to-peak intensity ratio thermometry based on the red upconversion emission of Er3+[J]. Opt. Express, 2016,24(12):13244-13249.

DENG R R,LIU X G. Tunable lifetime nanocrystals[J]. Nat. Photon., 2013,8(1):10-12.

贺飞,盖世丽,杨飘萍,等. 稀土上转换荧光材料的发光性质调变及其应用[J]. 发光学报, 2018,39(1):92-106. HE F,GAI S L,YANG P P,et al.. Luminescence modification and application of the lanthanide upconversion fluorescence materials[J]. Chin. J. Lumin., 2018,39(1):92-106. (in Chinese)

WANG T,YU H,SIU C K,et al.. White-light whispering-gallery-mode lasing from Lanthanide-doped upconversion NaYF4 hexagonal microrods[J]. ACS Photon., 2017,4(6):1539-1543.

HUANG P,ZHENG W,ZHOU S Y,et al.. Lanthanide-doped LiLuF4 upconversion nanoprobes for the detection of disease biomarkers[J]. Angew. Chem. Int. Ed., 2014,53(5):1252-1257.

王睿,张凡. 镧系元素掺杂的高效率上转换纳米粒子的合成[J]. 发光学报, 2018,39(1):50-68. WANG R,ZHANG F. Synthesis of highly efficient lanthanide upconversion nanoparticles[J]. Chin. J. Lumin., 2018,39(1):50-68. (in Chinese)

SABOKTAKIN M,YE X C,CHETTIAR U K,et al.. Plasmonic enhancement of nanophosphor upconversion luminescence in Au nanohole arrays[J]. ACS Nano, 2013,7(8):7186-7192.

TU N N,WANG L Y. Surface plasmon resonance enhanced upconversion luminescence in aqueous media for TNT selective detection[J]. Chem. Commun., 2013,49(56):6319-6321.

SUDHEENDRA L,ORTALAN V,DEY S,et al.. Plasmonic enhanced emissions from cubic NaYF4:Yb:Er/Tm nanophosphors[J]. Chem. Mater., 2011,23(11):2987-2993.

WANG W,WANG J,LIU X G. Direct evidence of a surface quenching effect on size-dependent luminescence of upconversion nanoparticles[J]. Angew. Chem. Int. Ed., 2010,49(41):7456-7460.

ZHONG Y T,TIAN G,GU Z J,et al.. Elimination of photon quenching by a transition layer to fabricate a quenching-shield sandwich structure for 800 nm excited upconversion luminescence of Nd3+-sensitized nanoparticles[J]. Adv. Mater., 2014,26(18):2831-2837.

SU Q Q,HAN S Y,XIE X J,et al.. The effect of surface coating on energy migration-mediated upconversion[J]. J. Am. Chem. Soc., 2012,134(51):20849-20857.

LI X M,WANG R,ZHANG F,et al.. Engineering homogeneous doping in single nanoparticle to enhance upconversion efficiency[J]. Nano Lett., 2014,14(6):3634-3639.

CHEN G Y,ZHANG Y G,SOMESFALEAN G,et al.. Two-color upconversion in rare-earth-ion-doped ZrO2 nanocrystals[J]. Appl. Phys. Lett., 2006,89(16):163105-1-3.

MEZA-ROCHA A N,HUERTA E F,CALDIO U,et al.. Dependence of the up-conversion emission of Li+ co-doped Y2O3:Er3+ films with dopant concentration[J]. J. Lumin., 2015,167:352-359.

SUN Q,CHEN X Q,LIU Z K,et al.. Enhancement of the upconversion luminescence intensity in Er3+ doped BaTiO3 nanocrystals by codoping with Li+ ions[J]. J. Alloys Compd., 2011,509(17):5336-5340.

SUN Q,ZHAO H,CHEN X Q,et al.. Upconversion emission enhancement in silica-coated Gd2O3:Tm3+,Yb3+ nanocrystals by incorporation of Li+ ion[J]. Mater. Chem. Phys., 2010,123(2-3):806-810.

CHENG Q,SUI J H,CAI W. Enhanced upconversion emission in Yb3+ and Er3+ codoped NaGdF4 nanocrystals by introducing Li+ ions[J]. Nanoscale, 2012,4(3):779-784.

LIANG Z Q,CUI Y,ZHAO S L,et al.. The enhanced upconversion fluorescence and almost unchanged particle size of -NaYF4:Yb3+,Er3+ nanoparticles by codoping with K+ ions[J]. J. Alloys Compd., 2014,610:432-437.

翟雪松,刘世虎,范柳燕,等. 强上转换发光的LiLu1-xYbxF4:Tm@LiGdF4核壳纳米晶的制备[J]. 发光学报, 2017,38(9):1149-1154. ZHAI X S,LIU S H,FAN L Y,et al.. Preparation of LiLu1-xYbxF4:Tm@LiGdF4 core-shell nanocrystals with enhanced upconversion luminescence[J]. Chin. J. Lumin., 2017,38(9):1149-1154. (in Chinese)

POLLNAU M,GAMELIN D R,LTHI S R,et al.. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J]. Phys. Rev. B, 2000,61(5):3337-3346.

VETRONE F,BOYER J C,CAPOBIANCO J A,et al.. Concentration-dependent near-infrared to visible upconversion in nanocrystalline and bulk Y2O3:Er3+[J]. Chem. Mater., 2003,15(14):2737-2743.

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