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1. 哈尔滨工业大学材料科学与工程学院,黑龙江 哈尔滨,150001
2. 太原学院 物理系,山西 太原,030032
收稿日期:2018-05-02,
修回日期:2018-08-06,
网络出版日期:2018-08-20,
纸质出版日期:2018-12-05
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方向明, 李想, 高世勇等. 自供能TiO<sub>2</sub>纳米管紫外探测器的制备与性能研究[J]. 发光学报, 2018,39(12): 1743-1748
FANG Xiang-ming, LI Xiang, GAO Shi-yong etc. Fabrication and Properties of Self-powered Ultraviolet Detector Based on TiO<sub>2</sub> Nanotubes[J]. Chinese Journal of Luminescence, 2018,39(12): 1743-1748
方向明, 李想, 高世勇等. 自供能TiO<sub>2</sub>纳米管紫外探测器的制备与性能研究[J]. 发光学报, 2018,39(12): 1743-1748 DOI: 10.3788/fgxb20183912.1743.
FANG Xiang-ming, LI Xiang, GAO Shi-yong etc. Fabrication and Properties of Self-powered Ultraviolet Detector Based on TiO<sub>2</sub> Nanotubes[J]. Chinese Journal of Luminescence, 2018,39(12): 1743-1748 DOI: 10.3788/fgxb20183912.1743.
采用液相沉积法在ITO衬底上以ZnO纳米棒阵列为模板合成了TiO
2
纳米管阵列,并采用SEM、XRD对样品的形貌、结构等进行表征。在此基础上,以空白ITO导电玻璃为对电极制备了光电化学型紫外探测器,并对其光响应特性进行测试。实验结果表明,制得的TiO
2
纳米管轻微弯曲,由单一稳定的锐钛矿相组成。制得的自供能TiO
2
纳米管紫外探测器对300~400 nm紫外波段非常敏感而对可见光区无响应。在无外加偏压的条件下,TiO
2
纳米管紫外探测器能够对紫外光实现探测,表现出自供能特性并且具有较高的光敏性。循环测试结果表明,制得的自供能TiO
2
纳米管紫外探测器能够循环工作且性能稳定,上升时间和下降时间分别为0.33 s和0.38 s。
TiO
2
nanotubes arrays were fabricated on ITO substrate
via
a liquid phase deposition method
with the assistance of ZnO nanorods arrays template
and the morphologies and structures of the samples were characterized by using SEM and XRD. Furthermore
the photoelectrochemical photodetector was fabricated with ITO as counter electrode and the photocurrent and spectral responses were measured. In addition to the high sensitivity and self-powered characteristic
the photodetector also revealed a splendid wavelength selectivity in the spectral range between 300 and 400 nm at zero bias voltage. Meanwhile
it is interesting to note that self-powered TiO
2
nanotubes UV-photodetector has the excellent stability and repeatability
and the rise time and decay time are 0.33 s and 0.38 s
respectively.
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祁晓萌, 彭文博, 赵小龙, 等. 基于高阻ZnO薄膜的光电导型紫外探测器[J]. 物理学报, 2015, 64(19):198501. QI X M, PENG W B, ZHAO X L, et al.. Photoconductive UV detector based on high-resistance ZnO thin film[J]. Acta Phys. Sinica, 2015, 64(19):198501. (in Chinese)
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