热离子交换型铝锗酸盐波导玻璃中钬离子的1.2&mu;m近红外荧光发射

杨佳心; 赵昕; 张竞辉; 林海

doi:10.3788/fgxb20183911.1519

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热离子交换型铝锗酸盐波导玻璃中钬离子的1.2μm近红外荧光发射

材料合成及性能 | 更新时间：2020-08-12

- 热离子交换型铝锗酸盐波导玻璃中钬离子的1.2μm近红外荧光发射
- 1.2μm Near Infrared Fluorescence Emission of Holmium Ions in Thermal Ion-exchanged Aluminum Germanate Waveguide Glasses
- 发光学报 2018年39卷第11期页码：1519-1526
- 作者机构：
  
  1. 大连工业大学纺织与材料工程学院,辽宁大连,116034
  2. 大连工业大学信息科学与工程学院,辽宁大连,116034
- 作者简介：
- 基金信息：
  
  国家自然科学基金（61275057）();辽宁省自然科学基金（2015020187）资助项目()
- DOI：10.3788/fgxb20183911.1519
  中图分类号： TQ171;O482.31
- 收稿日期：2018-01-30，
  
  修回日期：2018-04-10，
  
  网络出版日期：2018-05-09，
  
  纸质出版日期：2018-11-05
- 稿件说明：
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杨佳心, 赵昕, 张竞辉等. 热离子交换型铝锗酸盐波导玻璃中钬离子的1.2μm近红外荧光发射[J]. 发光学报, 2018,39(11): 1519-1526

YANG Jia-xin, ZHAO Xin, ZHANG Jing-hui etc. 1.2μm Near Infrared Fluorescence Emission of Holmium Ions in Thermal Ion-exchanged Aluminum Germanate Waveguide Glasses[J]. Chinese Journal of Luminescence, 2018,39(11): 1519-1526
杨佳心, 赵昕, 张竞辉等. 热离子交换型铝锗酸盐波导玻璃中钬离子的1.2μm近红外荧光发射[J]. 发光学报, 2018,39(11): 1519-1526 DOI： 10.3788/fgxb20183911.1519.

YANG Jia-xin, ZHAO Xin, ZHANG Jing-hui etc. 1.2μm Near Infrared Fluorescence Emission of Holmium Ions in Thermal Ion-exchanged Aluminum Germanate Waveguide Glasses[J]. Chinese Journal of Luminescence, 2018,39(11): 1519-1526 DOI： 10.3788/fgxb20183911.1519.

摘要

采用高温熔融法制备了适用于钾钠离子交换波导的钬离子掺杂铝锗酸盐玻璃，并对热离子交换玻璃样品的波导折射率分布和红外光谱特性进行了表征。实验结果表明，在390℃的KNO

熔盐中热离子交换4 h时，波导玻璃折射率最大改变量为0.006 9，K

-Na

热离子交换有效扩散深度为7.802 m，有效扩散系数达0.063m

/min。K

-Na

离子交换有效扩散系数比磷酸盐玻璃低，与MP19硅酸盐玻璃相当，但明显高于BK7玻璃和硼硅酸盐玻璃，其热离子交换过程易于控制。在644 nm泵浦光下可观察到Ho

归属于

的1.196m近红外有效发射，最大受激发射截面为2.3010

-21

。当Ho

在

能级的分数因子超过0.6时，增益截面达10

-21

量级以上。有效的近红外荧光发射和稳定的波导性能表明钬掺杂铝锗酸盐玻璃是~1.2 m波导激光器潜在的增益介质。

Abstract

doped aluminum germanate glasses adapting for K

-Na

ion-exchanged waveguide were fabricated by high temperature melting technique. The thermal ion-exchanged waveguide refractive index profile and infrared spectral characteristic of the glasses were measured. These experimental results reveal that the maximum change of refractive index in waveguide glasses is 0.006 9 when Ho

doped aluminum germanate glasses are immersed in KNO

molten salt at 390℃ for 4 h. Effective diffusion depth and coefficient of K

-Na

thermal ion exchange are 7.802 m and 0.063 m

/min

respectively. K

-Na

effective diffusion coefficient in aluminum germanate glass is lower than that in phosphate glass and approximately equals to that in MP19 silicate glass

but significantly higher than those in the BK7 glass and borosilicate glass

which indicates the thermal ion-exchanged process can be controlled easily. Effective 1.2 m near infrared emission belonging to

transition could be observed under 644 nm pump whose the maximum stimulated emission cross-section at 1.196 m is derived to be 2.3010

-21

. For the

transition of Ho

the gain cross-section achieves a magnitude of 10

-21

when fraction factor

exceeds 0.6. Effective near-infrared fluorescence and perfect waveguide performance demonstrate that Ho

doped aluminum germanate glass is a kind of potential gain medium in~1.2 m waveguide laser device.

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Keywords

references

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1.2μm Near Infrared Fluorescence Emission of Holmium Ions in Thermal Ion-exchanged Aluminum Germanate Waveguide Glasses

DOI：10.3788/fgxb20183911.1519

摘要

Abstract

关键词

Keywords

references