Eu<sup>3+</sup>掺杂方钠石荧光材料的合成及发光特性

阿孜古丽·热合曼; 何久洋; 穆亚斯尔·凯合日曼; 马媛媛; 王飞; 艾尔肯·斯地克

doi:10.3788/fgxb20143510.1194

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Eu³⁺掺杂方钠石荧光材料的合成及发光特性

材料合成及性能 | 更新时间：2020-08-12

- Eu³⁺掺杂方钠石荧光材料的合成及发光特性
- Synthesis and Luminescence Properties of Eu³⁺ Doped Sodalite Fluorescent Phosphor
- 发光学报 2014年35卷第10期页码：1194-1200
- 作者机构：
  
  新疆师范大学物理与电子工程学院物理系, 新疆矿物发光材料及其微结构实验室, 新疆乌鲁木齐 830054
- 作者简介：
- 基金信息：
  
  国家自然科学基金（11264040）;理论物理自治区重点学科创新基金（LLWLY201303，LLWLY201205，LLWLY201204）;自治区研究生科研创新基金（XJGRI2014122）;自治区重点学科招标课题（14XSQZ0601）;新疆师范大学研究生创新基金（20131231）资助项目
- DOI：10.3788/fgxb20143510.1194
  中图分类号： O433.4;O482.31
- 收稿日期：2014-07-25，
  
  修回日期：2014-08-11，
  
  纸质出版日期：2014-10-03
- 稿件说明：
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阿孜古丽·热合曼, 何久洋等. Eu³⁺掺杂方钠石荧光材料的合成及发光特性[J]. 发光学报, 2014,35(10): 1194-1200

Aziguli Reheman, HE Jiu-yang, Muyassar Kaiheriman etc. Synthesis and Luminescence Properties of Eu³⁺ Doped Sodalite Fluorescent Phosphor[J]. Chinese Journal of Luminescence, 2014,35(10): 1194-1200
阿孜古丽·热合曼, 何久洋等. Eu³⁺掺杂方钠石荧光材料的合成及发光特性[J]. 发光学报, 2014,35(10): 1194-1200 DOI： 10.3788/fgxb20143510.1194.

Aziguli Reheman, HE Jiu-yang, Muyassar Kaiheriman etc. Synthesis and Luminescence Properties of Eu³⁺ Doped Sodalite Fluorescent Phosphor[J]. Chinese Journal of Luminescence, 2014,35(10): 1194-1200 DOI： 10.3788/fgxb20143510.1194.

摘要

采用水热反应及后期热处理工艺合成了Eu

掺杂方钠石结构的荧光材料Na

（OH）

（H

O/NO

）

：Eu

。SEM图像显示，所合成的样品由一些长棒状和不规则多面体结构组成，平均粒径约为0.6 m和2 m。样品在394 nm（对应于Eu

离子的

跃迁）激发下发出单色性较好的红色荧光，相应的色坐标值为（0.613 6，0.337 7），色纯度为85.5%，量子效率为0.36。随着Eu

掺杂摩尔分数的增大，样品的红色荧光增强。当Eu

摩尔分数超过7%时发生部分相变现象。发光热猝灭研究发现，样品的相对亮度和红色比在37~100 ℃内比较稳定。

Abstract

doped Na

(OH)

O/NO

)

phosphors were synthesized by hydrothermal method and after heat treatment conditions. SEM images show that the samples are composed of some long rod shape and irregular polyhedron structure

and the average particle sizes are about 0.6 and 2 m

respectively. The samples can be excited efficiently by 394 nm (corresponding to the

transition in Eu

) and emit red fluorescence with better monochromaticity. The color coordinate of the red fluorescence is (0.613 6

0.337 7)

and the color purity is 85.5%. The luminescence intensity increases with the increasing of Eu

concentration. Part of the phase change occurs when Eu

mole fraction is more than 7%. Thermal quenching measurements show that the relative brightness and red ratio of the samples are stable to the change of the temperature in the range of 37-100 ℃.

关键词

Keywords

references

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Eu3+掺杂方钠石荧光材料的合成及发光特性

Synthesis and Luminescence Properties of Eu3+ Doped Sodalite Fluorescent Phosphor

DOI：10.3788/fgxb20143510.1194

摘要

Abstract

关键词

Keywords

references

Eu³⁺掺杂方钠石荧光材料的合成及发光特性

Synthesis and Luminescence Properties of Eu³⁺ Doped Sodalite Fluorescent Phosphor