Ce3+和Yb3+共掺杂的Y3Al5O12 可见及量子剪裁近红外发光性质

张继森; 张立国; 任建岳; 段配华; 骆永石; 赵海峰; 吕少哲

doi:10.3788/fgxb20143508.0891

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Ce³⁺和Yb³⁺共掺杂的Y₃Al₅O₁₂ 可见及量子剪裁近红外发光性质

材料合成及性能 | 更新时间：2020-08-12

- Ce³⁺和Yb³⁺共掺杂的Y₃Al₅O₁₂ 可见及量子剪裁近红外发光性质
- Properties of Visible and NIR Emissions with Quantum Cutting in Ce³⁺-Yb³⁺-codoped Y₃Al₅O₁₂ Powder Materials
- 发光学报 2014年35卷第8期页码：891-896
- 作者机构：
  
  中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
- 作者简介：
- 基金信息：
  
  国家自然科学基金（11174276，11174278）资助项目()
- DOI：10.3788/fgxb20143508.0891
  中图分类号： O482.31
- 收稿日期：2014-04-26，
  
  修回日期：2014-06-05，
  
  纸质出版日期：2014-08-03
- 稿件说明：
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张继森, 张立国, 任建岳等. Ce3+和Yb3+共掺杂的Y3Al5O12 可见及量子剪裁近红外发光性质[J]. 发光学报, 2014,35(8): 891-896

ZHANG Ji-sen, ZHANG Li-guo, REN Jian-yue etc. Properties of Visible and NIR Emissions with Quantum Cutting in Ce3+-Yb3+-codoped Y3Al5O12 Powder Materials[J]. Chinese Journal of Luminescence, 2014,35(8): 891-896
张继森, 张立国, 任建岳等. Ce3+和Yb3+共掺杂的Y3Al5O12 可见及量子剪裁近红外发光性质[J]. 发光学报, 2014,35(8): 891-896 DOI： 10.3788/fgxb20143508.0891.

ZHANG Ji-sen, ZHANG Li-guo, REN Jian-yue etc. Properties of Visible and NIR Emissions with Quantum Cutting in Ce3+-Yb3+-codoped Y3Al5O12 Powder Materials[J]. Chinese Journal of Luminescence, 2014,35(8): 891-896 DOI： 10.3788/fgxb20143508.0891.

摘要

室温下观察了YAG：Ce和YAG：Ce，Yb材料在可见以及近红外区域的发光特性，并通过对Ce

的5d能级辐射跃迁寿命以及Yb

的

5/2

能级布居时间和辐射跃迁寿命的比较研究，提出了光诱导的电荷转移态以及电荷转移辐射跃迁的能量传递机制，同时借助于能级图描述了从Ce

到Yb

的量子剪裁近红外发光过程。

Abstract

-and Yb

-doped YAG powders were prepared and the energy transfer (ET) mechanism with (Ce

)

-Yb

charge transfer transition in the powders was evaluated by the photoluminescence (PL)

the photoluminescence excitation (PLE) and the lifetime. The possibility of the NIR emission of QC was also discussed because the 1 000 nm emission of Yb

just meets the largest spectral response of c-Si solar cells

which may have potential application in enhancing the conversion efficiency of c-Si solar cells.

关键词

Keywords

references

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