吡嗪-2-羧酸在&gamma;-改性磷酸锆中的插层组装及发光性能

燕海姣; 石士考; 蒋兰宏; 王淑萍; 周济

doi:10.3788/fgxb20143507.0807

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吡嗪-2-羧酸在γ-改性磷酸锆中的插层组装及发光性能

材料合成及性能 | 更新时间：2020-08-12

- 吡嗪-2-羧酸在γ-改性磷酸锆中的插层组装及发光性能
- Intercalation Assembly and Luminescent Properties of Pyrazinecarboxylic Acid into γ-Modified Zirconium Phosphate
- 发光学报 2014年35卷第7期页码：807-812
- 作者机构：
  
  1. 河北师范大学化学与材料科学学院,河北石家庄,050016
  2. 清华大学材料科学与工程系北京,100084
- 作者简介：
- 基金信息：
  
  国家自然科学基金（20971035）();河北省自然科学基金（B2010000370）资助项目()
- DOI：10.3788/fgxb20143507.0807
  中图分类号： O482.31
- 收稿日期：2014-04-25，
  
  修回日期：2014-05-29，
  
  纸质出版日期：2014-07-03
- 稿件说明：
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燕海姣, 石士考, 蒋兰宏等. 吡嗪-2-羧酸在γ-改性磷酸锆中的插层组装及发光性能[J]. 发光学报, 2014,35(7): 807-812

YAN Hai-jiao, SHI Shi-kao, JIANG Lan-hong etc. Intercalation Assembly and Luminescent Properties of Pyrazinecarboxylic Acid into γ-Modified Zirconium Phosphate[J]. Chinese Journal of Luminescence, 2014,35(7): 807-812
燕海姣, 石士考, 蒋兰宏等. 吡嗪-2-羧酸在γ-改性磷酸锆中的插层组装及发光性能[J]. 发光学报, 2014,35(7): 807-812 DOI： 10.3788/fgxb20143507.0807.

YAN Hai-jiao, SHI Shi-kao, JIANG Lan-hong etc. Intercalation Assembly and Luminescent Properties of Pyrazinecarboxylic Acid into γ-Modified Zirconium Phosphate[J]. Chinese Journal of Luminescence, 2014,35(7): 807-812 DOI： 10.3788/fgxb20143507.0807.

摘要

采用直接沉淀法制备了层状框架-磷酸锆（-ZrP）及改性磷酸锆（-DDZrP），通过插层化学法将吡嗪-2-羧酸生色团与改性磷酸锆进行杂化组装。X射线衍射结果显示，-DDZrP的层间距（3.70 nm）远远大于-ZrP（1.11 nm），这有利于吡嗪-2-羧酸生色团的插入。组装后层状框架的层间距由3.70 nm减小为3.33~3.29 nm。荧光光谱表明，最大发射峰位置发生了明显蓝移，由溶液中的373 nm蓝移至悬浮液的366 nm。研究发现，吡嗪-2-羧酸在水溶液中的荧光强度很低，但形成插层组装后，悬浮液的荧光强度有了很大程度的提高，当浓度为15 mol/L时，荧光强度增大了6倍。这说明-DDZrP能够改善吡嗪-2-羧酸的荧光性能，有利于其在分子识别和荧光探针等领域的应用。

Abstract

-zirconium phosphate(-ZrP) and a modified zirconium phosphate (-DDZrP)were prepared by direct precipitation method. Then

the chromophore pyrazinecarboxylic acid as guest molecules was intercalated into the modified zirconium phosphate. The changes of their layer spacing and spectroscopic properties were studied in detail. The results of X-ray-diffraction demonstrate that the interlayer spacing is reduced to 3.29 nm from 3.70 nm after intercalation. The fluorescence spectra show that the emission peak is blue shifted from 373 nm in aqueous solution to 366 nm in suspension. Furthermore

the fluorescence property of pyrazinecarboxylic acid assembled into lamellar framework is dramatically improved as compared to the chromophores in aqueous solution. As the chromophore concentration is 15 mol/L

the fluorescence intensity is enhaced 6-fold. It is concluded that -DDZrP provides a special microenvironment which can improve the optical properties of chromophores.

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references

Lezhnina M, Benavnte E, Bentlage M, et al. Luminescent hybrid materials based on a clay mineral [J]. Chem. Mater., 2007, 19(5):1098-1102.

Brunet E, Alonso M, Cerro C, et al. A luminescence and electrochemical study of photoinduced electron transfer within the layers of zirconium phosphate [J]. Adv. Funct. Mater., 2007, 17(10):1603-1610.

Dey A, kirchner M T, Vangala V R, et al. Crystal structure prediction of aminols: Advantages of a supranolecular synthon approach with experimental structures [J]. J. Am. Chem. Soc., 2005, 127(30):10545-10559.

Holder E, Tessler N, Rogach A L. Hybrid nanocomposite materials with organic and inorganic components for opto-electronic devices [J]. J. Mater. Chem., 2008, 18(10):1064-1078.

Shi S K, Liu Q, Zhang X, et al. Fabrication and spectroscopic properties of a metalloporphyrin-intercalated zirconium phosphate assembly [J]. RSC Adv., 2013, 3(22):8254-8260.

Zhou G F, Wang Q, Zeng R Q, et al. Preparation and application of zirconium phosphate and its derivatives [J]. Prog. Chem.(化学进展), 2014, 26(1):87-99 (in Chinese).

Zhang X, Shi S K, Liu Q, et al. Tris-(8-hydroxy-quinoline) aluminium/zirconium phosphate: A novel hybrid assembly with strong luminescence and prolonged lifetime [J]. Chem. Commun., 2011, 47(22):6359-6361.

Odobel F, Massiot D, Harrison B S, et al. Photoinduced energy transfer between ruthenium and osmium tris-bipyridine complexes covalently pillared into -ZrP [J]. Langmuir, 2003, 19(1):30-39.

Li Y F, Jin L Q, Liu Z Q. The research progress on pyrazinamide [J]. Chin. J. Med. Chem.(中国现代应用药学), 2010, 27(4):307-312 (in Chinese).

Zhou L S, Feng Y Q, Qu H M. The progress of pyrazinmide [J]. Chem. Prop. Poly. Mater.(化学推进剂与高分子材料), 2002, 4(4):4-6 (in Chinese).

Wang Q Q, Bai J Q, Dong Y Y. Synthesis and application of pyrazinecarboxylic acid [J]. Chem. Reag. (化学试剂), 2012, 34(6):508-512 (in Chinese).

Tomita I, Takeo C, Hasegawa Y, et al. Synthesis of -zirconium phosphate by the fluoro-complex method and the intercalation behavior of some -diimines [J]. J. Inclusion Phenom. Mol. Recognit. Chem., 1990, 9:315-325.

Yao W, Wang H N, Wang J W, et al. Preparation, characterization and absorption mechanism for phenols CTMBA-ZrP [J]. Acta. Phys. Chim. Sinica (物理化学学报), 2011, 27(7):1763-1771 (in Chinese).

Liu Q, Zhang X, Shi S K, et al. Inercalation assembly and optical properties of metalloporphyrin into an inorganic lamellar framework [J]. Chin. J. Lumin.(发光学报), 2011, 32(6):617-621 (in Chinese).

Shi S K, Liu Y, Han S T, et al. Intercalation and enhanced fluorescence of tetraphenylporphine in modified lamellar zirconium phosphate [J]. Chin. J. Inorg. Chem.(无机化学学报), 2007, 23(4):703-707 (in Chinese).

Kaschak D M, Lean J K, Waraksa C C, et al. Photoinduced energy and electron transfer reactions in lamellar polyanion/polycation thin films: Toward an inorganic leaf [J]. J. Am. Chem. Soc., 1999, 121(14):3435-3445.

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吡嗪-2-羧酸在γ-改性磷酸锆中的插层组装及发光性能

Intercalation Assembly and Luminescent Properties of Pyrazinecarboxylic Acid into γ-Modified Zirconium Phosphate

DOI：10.3788/fgxb20143507.0807

摘要

Abstract

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Keywords

references